• Title/Summary/Keyword: Liquid Resin

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비변색타입의 무용제형 상온 액상수지 (Non-Solvent Liquid Resin of Non-Discoloration Type at Room Temperature)

  • 문진복;목동엽;김규현
    • Korean Chemical Engineering Research
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    • 제47권6호
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    • pp.669-675
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    • 2009
  • 연질 PVC 대체를 위한 비변색 타입의 무용제형 상온 액상수지를 폴리올을 경화제로 사용하는 폴리우레탄수지 구조제어 설계를 통한 프리폴리머 합성방법을 응용하여 제조할 수 있었다. Macro-glycol, 분자량 및 반응조건의 영향 등을 고찰하여 최적의 작업성과 물성을 가지는 무용제형 상온액상수지를 제조하였으며, 우수한 기계적인 특성과 함께 유색작업을 위한 안료의 분산성 등에서도 우수하였고, Tg가 $-40^{\circ}C$의 값을 나타내었다. 또한 자외선 노출이나 질소산화물에 의한 황변특성도 개선할 수 있었다.

불포화 폴리에스테르 모르터의 인성강화에 관한 실험 연구 (An Experimental Study on Toughening of Unsaturated Polyester Mortar)

  • 김화중;박준철;윤명덕;윤요현;최영준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
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    • pp.1115-1120
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    • 2000
  • The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of liquid rubber. In general, unsaturated polyester liquid has strong brittleness in spite of if high strength Therefore; it is difficult use polyurethane liquid rubber for the place where impact resistance is demanded. In this study, it was evaluated strength, impact resistance and fracture toughness by adding to polyurethane liquid rubber(0~25%). As a result, it was found that a tendency to be increase bearing impact and fracture toughness as polyurethane liquid rubber increased but strength was decreased.

선박용 폐 FRP 수지의 재활용 공정 개발 (Development of A Recycling Process for Waste FRP from Boats)

  • 강세란;김영우;황덕기;김시영;이민규;주창식
    • 한국환경과학회지
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    • 제12권6호
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    • pp.635-641
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    • 2003
  • A recycling process for the waste FRP from boats was developed. The recycling process is composed of decomposition of waste FRP with propylene glycol and synthesis of recycled unsaturated polyester resin from the decomposed liquid material. Prior to the decomposition, waste FRP was cut into 2cm x 5cm segments and mechanical impact was applied by press roller to give gaps between cumulated laminates. Propylene glycol effectively decomposed the waste FRP segments and glass fibers were easily separated from decomposed liquid material. Recycled unsaturated polyester resin could be made from the decomposed liquid material by reaction with maleic anhydride and phthalic anhydride.

Liquid-phase Dehydration of 1-Phenylethanol to Styrene over an Acidic Resin Catalyst

  • Khan, Nazmul Abedin;Hwang, Jin-Soo;Jhung, Sung-Hwa
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1327-1330
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    • 2011
  • Dehydration of 1-phenylethanol to produce styrene has been studied in liquid phase with three solid acid catalysts such as H-ZSM-5, H-Y and Amberlyst-15. Amberlyst-15 shows the highest conversion and styrene yield, suggesting the applicability of a resin catalyst in the dehydration. The good performance of the Amberlyst-15 may be due to high acid concentration and ready diffusion of reactants and products. A possible reaction scheme (such as the formation of styrene from diphenylethylether) has also been suggested.

UV 나노임프린트리소그래피의 정렬 공정 중 몰드의 변형해석 (Deformation of a mold for large area UV-nanoimprint lithography in alignment and curing processes)

  • 박인수;원종진;임홍재;정재일
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1939-1943
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    • 2008
  • Deformation of a mold is measured and analyzed in alignment and curing processes of UV-Imprint Lithography. We are focused on mold deformation caused by a UV resin, which is laminated between a mold and a target glass-panel. The UV resin is viscous in case of liquid state, and the resin will be solidified when being exposed by the ultra-violet light. The viscosity of the resin causes shear force on the mold during the alignment process. Moreover, the shrinkage during phase change from liquid to solid may cause residual stress on the mold. The experiments for measuring temperature and strain are made during alignment and curing process. Strain-gages and thermocouples are used for measuring the strain and variation of temperature on several points of the mold, respectively. The deformation of mold is also simulated and analyzed. The simulation results are compared with the experiments. Finally, sources of alignment errors in large area UV-nanoimprint lithography are discussed.

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S-RIM을 이용한 Glass Fiber Chopped Strand Mat 강화 p-DCPD 복합재료 제작 및 수치해석을 통한 공정 시간 예측 (Manufacturing and Numerical Analysis of Glass Fiber Chopped Strand Mat Reinforced p-DCPD Composites Processed by S-RIM)

  • 유형민;엄문광;최성웅
    • 한국수소및신에너지학회논문집
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    • 제30권6호
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    • pp.629-634
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    • 2019
  • Dicyclopentadiene is a low viscosity resin which forms a poly-dicyclopentadiene rapidly through ring opening metathesis polymerization (ROMP). This poly-dicyclopentadiene has outstanding properties of low-temperature, water and impact resistances. Due to these advantages, military and offshore structures try to apply the DCPD composites by using liquid composite molding process. In this study, 14%, 38% volume fraction fiber glass strand mat reinforced p-DCPD composites processed by structural reaction injection molding (S-RIM) which has resin-catalsyt mixing head and glass fiber preform in the mold. Additionally, S-RIM numerical analysis was conducted to predict the process time depending on fiber volume fraction and mold temperature. The process time is shorter when it has the lower fiber volume fraction or the higher mold temperature. At higher mold temperature, it is necessary to set the maximum mold temperature considering the resin curing time.

에폭시수지 공정에서 발생되는 고염 폐수로부터 황산알루미늄과 PAC 응집제를 이용한 응집/고액분리 조건 최적화 (Optimizing of Coagulation and Solid-Liquid Separation Conditions Using Aluminum Sulfate and Poly-Aluminum Chloride Coagulants from Brine Wastewater Discharged by the Epoxy-resin Process)

  • 이창한;김유진;문성현;권성헌;안갑환
    • 한국환경과학회지
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    • 제31권1호
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    • pp.1-8
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    • 2022
  • In this study, solid-liquid separation conditions for coagulation and sedimentation experiments using inorganic coagulant (aluminum sulfate and Poly-Aluminum Chloride (PAC)) were optimized with brine wastewater discharged by the epoxy-resin process. When the turbidity and suspended solid (SS) concentration in raw wastewater were 74 NTU and 4.1 mg/L, respectively, their values decreased the lowest in a coagulant dosage of 135.0 - 270.0 mg Al3+/L. The epoxy resin was re-dispersed in the upper part of wastewater treated above 405.0 mg Al3+/L. The removal efficiencies of turbidity and SS via dosing with aluminum sulfate and PAC were evaluated at initial turbidity and SS of 74 - 630 NTU and 4.1 - 38.5 mg/L, respectively. They increased most in the range from 135.0 - 270.0 mg Al3+/L. The solid-liquid separation condition was quantitatively compared to the correlation of SS removal efficiency between the coagulant dosage and SS concentration based on the concentration of aluminum ions. The empirical formula, R = beaD, shows the relationship between SS removal efficiency (R) and coagulant dosage (D) at 38.5 mg/L; it produced high correlation coefficients (r2) of 0.9871 for aluminum sulfate and 0.9751 for PAC.

쾌속조형과 스크린 인쇄기술을 이용한 빌드업인쇄회로기판의 제조공정기술개발 (Development of Build-up Printed Circuit Board Manufacturing Process Using Rapid Prototyping Technology and Screen Printing Technology)

  • 조병희;정해도;정해원
    • 한국정밀공학회지
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    • 제17권2호
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    • pp.130-136
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    • 2000
  • Generally, the build-up printed circuit board manufactured by the sequential process with etching, plating, drilling etc. requires many types of equipments and lead time. Etching process is suitable for mass production, however, it is not adequate for manufacturing prototype in the developing stage. In this study, we introduce a screen printing technology to prototyping a build-up printed circuit board. As for the material, photo/thermal curable resin and conductive paste are used for the formation of dielectric and conductor. The build-up structure is made by subsequent processes such as the formation of liquid resin thin layer, the solidification by UV/IR light, and via filling with conductive paste. By use of photo curable resin, productivity is greatly enhanced compared with thermal curable resin. Finally, the basic concept and the possibility of build-up printed circuit board prototyping are proposed in comparison with to the conventional process.

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투명 아크릴 레진을 이용한 초소형 PMMA 렌즈 배열의 제작 (Fabrication of refractive PMMA microlens array using transparent acrylic resin)

  • 안시홍;김용권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 G
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    • pp.3316-3318
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    • 1999
  • PMMA(poly-methyl methacrylate) microlens array is fabricated using transparent acrylic resin. PMMA is commonly used material for plastic lens due to its excellent visibility larger than 90% and other optical characteristics so much close to those of glass. Orthodontic resin (DENTSPLY International Inc.), commonly used in dentistry, is an transparent acrylic resin kit including MMA liquid and polymerization powder. Their mixture results in PMMA through polymerization. Using the resin PMMA layer is formed on the substrate through spin-coating. Designed pattern of lens structure is transferred to PMMA layer by RIE (Reactive Ion Etching) with oxygen plasma. Final lens shape is formed by thermal treatment that causes PMMA to reflow, The thickness of PMMA spun on the substrate is $17{\mu}m$ that is also final sag of microlens, Designed diameters of the microlenses are $200{\mu}m$, $300{\mu}m$,and $500{\mu}m$, respectively.

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사각단면 액체저장탱크에서의 슬로싱 거동 연구 (Study on Sloshing Behaviors in Liquid Storage Tank with Rectangular Cross Section)

  • 윤성호;이은동;박기진
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.1087-1090
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    • 2003
  • In this study, experimental procedures were suggested to investigate the sloshing behavior of a liquid storage tank subjected to inevitably external vibrating conditions. For this purpose. liquid storage tank with rectangular cross section was made of an acrylic resin for the visualization of liquid fluctuation. A specially designed vibrator was used to provide a specified vibrating condition to the liquid storage tank. Extrapolation technique was applied to determine sloshing natural frequency by using various sloshing frequencies at each vibrating displacement and liquid contents at a fixed vibrating frequency. Sloshing mode was also determined from continuous images or liquid fluctuation captured from a video camera. In addition, change in the height of the liquid free surface was measured by using a floating target and a laser displacement sensor. It is found that the suggested method can be applicable to identify the sloshing behavior of liquid storage tank with rectangular cross section.

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