• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.1
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• pp.127-131
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• 2022

The structural safety of prototype transport and storage containers for very low-level radioactive liquid waste was experimentally estimated for its localization development. Transport containers for radioactive liquid waste have been researched and developed, however, there are no standardized commercial containers for very low-level radioactive waste in Korea. In this study, the structural safety of the designated IP-2 type container capable of transporting and temporarily storing large amounts of very low-level liquid waste, which is generated during the operation and decommissioning of nuclear power plants, was demonstrated. The stacking and drop tests, which were conducted to determine the structural integrity of the container, verified that there was no external leakage of the contents in spite of its structural deformation due to the drop impact. This study shows the effort required for the localization of the technology used in manufacturing transport and storage containers for very low-level radioactive liquid waste, and the additional structural reinforcement of the container in which the commercial intermediate bulk container (IBC) external frame was coupled.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.2 no.3
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• pp.219-230
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• 2004

Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), and into radiochemical and radioactive laundry waste. Although the evaporation process has a high decontami- nation ability, it has several problems such as corrosion, foam, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED), instead of the current evaporation process, has been introduced into the Yonggwang NPP #5 and 6. These two methods have been compared to understand the differences in this study. Aspects compared here were the released radioactivity amount of the liquid radioactive wastes, the dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. The IED system is designed to discharge higher radioactivity about 20% than the evaporating system, and the actual radioactivity released from the evaporating and IED system were 0.473mCi and 1.098mCi, respectively. The radioactivity released from the IED was 2.32 times higher than that of the evaporating system. The dose of off-site residents was $2.97{\times}10^{-6}$mSv for the evaporating system, and $6.47{\times}10^{-6}$mSv for IED. The decontamination factor(DF) of the evaporator is, in most cases, far lower than the lower limits of detection(LLD) with the Ge-Li detector. Due to the low concentration of the liquid wastes collected from the liquid waste system, the decontamination factor of IED is very low. Since there is not enough data on the amount of solid radioactive wastes generated by the evaporation system, the comparison on these two systems has been conducted on the basis of the design, and the comparison result was that the evaporating system generated more wastes about 40% than IED.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.02a
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• pp.12-27
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• 2004

Pretreatment process consisted of submerged hollow-fiber microfiltration(HMF) membrane and spiral-wound nanofiltration(SNF) membrane has been developed by NETEC, KHNP for the purpose of improving the impurities of liquid radioactive waste before entering Selective Ion Exchange System(SIES). The lab-scale combined system was installed at Kori NPP #2 nuclear power plant and demonstration tests using actual liquid radioactive waste were carried out to verify the performance of the combined system. The submerged HMF membrane was adopted for removal of suspended solid in liquid radioactive waste and the SNF membrane was used for removal of particulate radioisotope such as, Ag-l10m and oily waste because ion exchange resin can not remove particulate radioisotopes. The liquid waste in Waste Holdup Tank (WHT) was processed with HMF and SNF membrane, and SIES. The initial SS concentration and total activity of actual waste were 38,000ppb and $1.534{\times}10_{-3}{\mu}Ci/cc$, respectively. The SS concentration and total activity of permeate were 30ppb and lower than LLD(Lower Limit of Detection), respectively.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.43-47
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• 2003

The performance of the Radwaste System is measured in terms of generation of waste volumes, the release of radioactive materials to the environment and the occupational radiation exposure to workers. Based on our design and operating experience from PWR plants, various design goals for liquid radwaste system were developed to improve system performance. It has been making continuous effort to develop the advanced liquid radwaste processing technology for new PWR plants since 1998. The primary goal of this effort was to obtain better performance and to design a more economical liquid radwaste system. This paper describes lesson learned experience from design of the liquid radwaste system in Korea Nuclear Power Plants.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.377-385
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• 2004

The quantity of radioactive waste generated from HANARO operation for the years of 1996 to 2003 has been analysed. It was found that the solid waste of $72, 999{\ell}$ and liquid waste of $263, 576{\ell}$ have been generated for the past 8 years. The amounts of Ar-41, I-131 and H-3 exhausted to the environment were 1, 225.6 Ci, 1.612E-2 Ci and 210 Ci, respectively.

• Journal of Radiation Industry
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• v.18 no.2
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• pp.147-153
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• 2024

Radioactive liquid waste generated during operation and overhaul is collected and reused through the radioactive liquid waste treatment system and continuous monitoring system in the nuclear power plant or discharged to the outside if it satisfies the limit within the control and monitoring. However, there are concerns about boric acid management, which controls the power output of nuclear power plants in radioactive liquid waste. Due to the behavior of boric acid, it is difficult to remove it in the existing liquid radwaste system, and the concentration of boric acid water discharged tends to be higher than the natural state of 5 ppm, so additional facilities should be considered. Therefore, this study aims to evaluate the radiological effects of radioactive waste treatment facilities that are under development and use them as a basis for managing worker exposure and evaluating the safety of facilities in the future.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.11b
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• pp.290-299
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• 2005

Two decommissioning projects are carried out at the KAERI (Korean Atomic Energy Research Institute), one for the Korea research reactors, KRR-1 and KRR-2, and another for the uranium conversion plant (UCP). The concept of the management of the wastes from the decommissioning sites was reviewed with a relation of the decommissioning strategies, technologies for the treatment and the decontamination, and the characteristics of waste. All the liquid waste generated from KRR-1 and KRR-2 decommissioning site is evaporated by a solar evaporation facility and all the liquid waste from the UCP is treated together with lagoon sludge waste. The solid wastes from the decommissioning sites are categorized into three groups; not contaminated, restricted releasable and radioactive waste. The not-contaminated waste will be reused and/or disposed at an industrial disposal site, and the releasable waste is stored for the future disposal at the KAERI. The radioactive waste is packed in containers, and will be stored at the decommissioning sites till they are sent to a national repository site. The reduction of the radioactive solid waste is one of the strategies for the decommissioning projects and could be achieved by the repeated decontamination. By the achievement of the minimization strategy, the amount of radioactive waste was reduced and the disposal cost will be reduced, but the cost for manpower, for direct materials and for administration was increased.

• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3957-3961
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• 2022

Deposition behaviors of Sr and Cs in various liquid cathodes, such as Zn, Bi, Cd, and Pb, were examined to evaluate their recovery from LiCl-KCl eutectic salt. Cations in the salt were deposited on the liquid cathode, exhibiting potential of -1.8 to -2.1 V (vs. Ag/AgCl). Zn cathode had successful deposition of Sr and exhibited the highest recovery efficiency, up to 55%. Meanwhile, the other liquid cathodes showed low current efficiencies, below 18%, indicating LiCl-KCl salt decomposition. Sr was recovered from the Zn cathode as irregular rectangular SrZn₁₃ particles. A negligible amount of Cs was deposited on the entire liquid cathode, indicating that Cs was hardly deposited on liquid cathodes. Based on these results, we propose that liquid Zn cathode can be used for cleaning Sr in LiCl-KCl salt.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2017.05a
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• pp.275-276
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• 2017

• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.516-522
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• 2023

The co-precipitation process plays a key role in the decontamination of radionuclides from low and intermediate levels of liquid waste. For that reason, the removal of Cs ions from waste solution by the co-precipitation method was carried out. A simulated liquid waste (¹³³Cs) was prepared from a 0.1 M CsCl solution, while wastewater generated by washing steel ash served as a representative of radioactive cesium solution (¹³⁷Cs). By co-precipitation, potassium ferrocyanide was applied for the adsorption of Cs ions, while nickel nitrate and iron sulfate were selected for supporting the precipitation. The amount of residual Cs ions in the CsCl solution after precipitation and filtration was determined by ICP-OES, while the radioactivity of ¹³⁷Cs was measured using a gamma-ray spectrometer. After cesium removal, the amount of cesium appearing in both XRD and SEM-EDS was analyzed. The removal efficiency of ¹³³Cs was 60.21% and 51.86% for nickel nitrate and iron sulfate, respectively. For the ash-washing solution, the removal efficiency of ¹³⁷Cs was revealed to be more than 99.91% by both chemical agents. This implied that the co-precipitation process is an excellent strategy for the effective removal of radioactive cesium in waste solution treatment.