• Title/Summary/Keyword: Liquid Electrolyte

Search Result 261, Processing Time 0.032 seconds

Simulation for transport phenomena of DMFC (Direct Methanol Fuel Cell) (직접메탄올 연료전지내 전달현상에 대한 전산 모사)

  • Im, Hun-Suk;Kim, Yo-Jin;Hong, Won-Hi
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.11a
    • /
    • pp.490-493
    • /
    • 2006
  • The results of simulation of direct methane fuel cell fed with liquid-state methanol feed are shown. This numerical process is based on mass and current conservation equations. The results showed that over low current density $(<200mA/cm^2)$ IV polarization curve was well-presented compared to experimental result. Methanol fed from anodic side moved into cathodic side through electrolyte membrane and the pressure near cathode electrode increased according to amount of methanol crossover and production of water. Besides change of overpotential on each el electrode were checked by x-axis.

  • PDF

Solid State Dye-Sensitized Solar Cells Employing Polymer Electrolytes : Oligomer Approach

  • Kang, Yong-Soo;Lee, Yong-Gun;Kang, Moon-Sung;Kim, Jong-Hak;Char, Kook-Choen
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.63-64
    • /
    • 2006
  • The solid state dye-sensitized solar cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5 % at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs: "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the efficiency has also been investigated.

  • PDF

Simultaneous mixing and pumping using asymmetric microelectrodes (비대칭 미세전극을 이용한 동시 혼합 및 펌핑)

  • Kim, Byoung-Jae;Yoon, Sang-Youl;Lee, Kyung-Heon;Sung, Hyung-Jin
    • 한국가시화정보학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.77-83
    • /
    • 2007
  • This paper presents numerical and experimental works for simultaneous pumping and mixing small liquid using asymmetric microelectrode arrays, based on AC electroosmotic flows. To this end, four arrangements of electrode pairs were considered with diagonal/herringbone shapes. Numerical simulations were made of three-dimensional geometries by using the linear theory. The results indicated that the helical flow motions induced by the electrode arrays play a significant role in the mixing enhancement. The pumping performance was influenced by the slip velocity at the center region of the channel compared to that near the side walls. To validate the numerical predictions, the microfluidic devices were made through MEMS. The flow rate was obtained by using micro PIV, increasing the applied frequency. The electrolyte was potassium chloride solution. The flow patterns above electrodes were visualized to see lateral flow for mixing. The experimental results showed good agreements with the numerical predictions.

  • PDF

Study on the Structure and Photoelectrochemical Properties of Anodized TiO2 Nanotube Films (양극산화법으로 제작한 TiO2 나노튜브 박막의 구조 및 광전기화학 특성 분석)

  • Lee, A Reum;Park, Sanghyun;Kim, Jae-Yup
    • Journal of Sensor Science and Technology
    • /
    • v.27 no.4
    • /
    • pp.264-268
    • /
    • 2018
  • Vertically-aligned $TiO_2$ nanotube electrodes have attracted considerable attention for applications in solar cells, catalysts, and sensors, because of their ideal structure for electron transport and electrolyte diffusion. Here, we prepare vertically-aligned $TiO_2$ nanotube electrodes using a two-step anodization process. The prepared $TiO_2$ nanotube electrodes exhibit uniform pore structures with an inner diameter of ~80-90 nm and wall thickness of ~20-25 nm. In addition, they exhibit an anatase crystal phase after a high-temperature annealing. The annealed $TiO_2$ nanotube electrodes are applied in dye-sensitized solar cells (DSSCs) as photoanodes. The fabricated DSSC exhibits conversion efficiencies of 3.46 and 2.15% with liquid- and gel-type electrolytes, respectively.

Further Applications of the Solubility Theory to Various Systems (용해도 이론의 여러가지 계에 대한 적용)

  • Sung, Yong-Kiel;Paek, U-Hyon;Jhon, Mu-Shik
    • Journal of the Korean Chemical Society
    • /
    • v.15 no.4
    • /
    • pp.211-217
    • /
    • 1971
  • The theory of solubility proposed by Jhon and Kihara has been tested and applied to various systems. In the present paper, the systems are the solubilities of gases such as $Ar,\;H_2,\;N_2,\;O_2,\;CO_2,\;CH_4,\;and\;C_2H_6$ in liquid benzene and carbon disulfide, those of solids iodine and naphthalene in the nonaqueous solvents, and those of gases $H_2,\;N_2,\;O_2,\;Ar,\;CH_4,\;and\;C_2H_4$ in the electrolyte solutions. The theoretical values of solubilities are in good agreement with the experimental data in the literature.

  • PDF

Quasi-solid state electrolytes with silica nanomaterial for high efficiency dye-sensitized solar cells

  • Jeon, Semina;Lim, Jeongmin;Han, Chi-Hwan;Jun, Yongseok
    • Rapid Communication in Photoscience
    • /
    • v.2 no.3
    • /
    • pp.85-88
    • /
    • 2013
  • Silica nanoparticles were synthesized with various silane coupling agents to make specific pathway of electrons and anti-recombination system when solidifying liquid electrolytes. In this study, we used an appropriate method of synthesis for activated silica nanoparticles and silane coupling agents with 3-(triethoxysilyl)propionitrile, Trimethoxy[3-(methylamino)propyl]silane, Triethoxyoctylsilane, and octadecyltrimethoxy silane. Dye-sensitized solar cells using solidified electrolytes with silica nanoparticles exhibit comparatively excellent efficiency, ranging from 2.3 to 7.0% under similar conditions.

Study of Back-Up Electric Power Source as a Role for Instant Power Industry Safety by Super Capacitor (순간 정전시 산업안전용 보조전원 역할의 Super Capacitor에 관한 연구)

  • 김상길;김종철;허진우;김경민;이용욱;강안수
    • Proceedings of the Safety Management and Science Conference
    • /
    • 1999.11a
    • /
    • pp.345-354
    • /
    • 1999
  • A new type of capacitor named "Super Capacitor" has been developed, in which the properties of electric double layer formed at the interface of activated carbon electrode- liquid organic electrolyte is applied. This capacitor is small In size, light in weight, wide In temperature range(-25~$70^{\circ}C$), large in charge-discharge capability and good in voltage preservation. And this super capacitor is applied as a power back-up for electricity failure in volatile memory devices etc., a power source for a short time and a power source for operating actuators. At present the development of high power back-up types of the capacitor system and improvement of their characteristics are being actively conducted in order to find wider applications.lications.

  • PDF

A Study on the Performance Analysis of Mobile Fuel Cell (모바일용 연료전지의 성능해석에 관한 연구)

  • Kim, Kwang-Soo;Choi, Jong-Pil;Jeong, Chang-Ryeol;Jang, Jae-Hyeok;Jeon, Byeong-Hee;Kim, Byeong-Hee
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.25 no.1
    • /
    • pp.115-121
    • /
    • 2008
  • In this paper, a three-dimensional computational fluid dynamic model of a proton exchange membrane fuel cell(PEMFC) with serpentine flow channel is presented. A steady state, single phase and isothermal numerical model has been established to investigate the influence of the GDL (Gas Diffusion Layer) parameters. The GDL is made of a porous material such as carbon cloth, carbon paper or metal wire mesh. For the simplicity, the GDL is modeled as a block of material having numerous pathways through which gaseous reactants and liquid water can pass. The porosity, permeability and thickness of the GDL, which are employed in the model parameters significantly affect the PEMFC performance at the high current region.

Fabrication and characterization of $SnO_2$ anode thin film for thin film secondary battery (박막형 2차전지용 $SnO_2$음극 박막의 제작 및 특성 평가)

  • 이성준;신영화;윤영수;조원일
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.571-574
    • /
    • 2000
  • In this study, Tin oxide thin film for secondary battery was deposited on Pt/Ti/Si(100). It was fabricated by r.f. reactive sputtering with Tin metal target. At constant power (130W), pressure (Base 5$\times$10$^{-6}$ Torr, working 5$\times$10$^{-3}$ Torr) and at room temperature, it was fabricated by Ar/O2 gas ratio. After deposition, we got AFM & SEM to investigated surface of thin films and had XRD to find crystalline of thin films. Charge/discharge characteristics were carried out in 1M LiPF$_{6}$ , EC:DMC = 1:1 liquid electrolyte using lithium metal at room temperature.

  • PDF

Fabrication and electrochemical characterization of amorphous vanadium oxide thin films for thin film micro-battery by reactive r.f. sputtering (반응성 r.f. 스퍼터링에 의한 마이크로 박막 전지용 산화바나듐 박막의 제작 및 전기화학적 특성 평가)

  • 전은정;신영화;남상철;윤영수;조원일
    • Journal of the Korean Vacuum Society
    • /
    • v.9 no.1
    • /
    • pp.42-47
    • /
    • 2000
  • The amorphous vanadium oxide thin films for thin-film rechargeable lithium batteries were fabricated by r.f. reactive sputtering at room temperature. As the experimental parameter, oxygen partial pressure was varied during sputtering. At high oxygen partial pressures(>30%), the as-deposited films, constant current charge/discharge characteristics were carried out in 1M $LiPF_6$, EC:DMC+1:1 liquid electrolyte using lithium metal as anode. The specific capacity of amorphous $V_2O_5$ after 200cycles of operation at room temperature was higher compared to crystalline $V_2O_5$. The amorphous vanadium oxide thin film and crystalline film showed about 60$\mu$Ah/$\textrm{cm}^2\mu\textrm{m}$ and about 38$\mu$Ah/$\textrm{cm}^2\mu\textrm{m}$, respectively. These results suggest that the battery capacity of the thin film vanadium oxide cathode strongly depends on the crystallinity.

  • PDF