• Title/Summary/Keyword: Liquid Crystal Orientation

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Enhancement of Molecular Orientation of Liquid Crystal on Photoreactive Polymers by using Non-Photoreactive Naphthalenic Polyimide

  • Hah, Hyun-Dae;Sung, Shi-Joon;Cho, Ki-Yun;Kim, Won-Sun;Jeong, Yong-Cheol;Park, Jung-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1169-1172
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    • 2004
  • Polyimides are blended with photoreactive polymers in order to improve the thermal stability of molecular orientation of photoreactive groups induced by polarized UV irradiation. The polyimide/photopolymer blends can be applied for the photo-induced liquid crystal alignment layers. However, the polyimides are also decomposed by UV irradiation and this may have the negative effect on the orientation of liquid crystals. In order to elucidate the influence of polyimide on the molecular orientation of liquid crystal, non-photoreactive naphthalenic polyimide (1,4,5,8-naphthalene tetracarboxylic dianhydride} was selected for the blend alignment layers. We prepared the blends of photo-reactive coumarin polymers and naphthalenic polyimide, and investigated the orientation of liquid crystals. Thermal stability of the orientation of liquid crystals was enhanced due to the thermally stable polyimide. However, there was no other side-effect of polyimide on the orientation of liquid crystals and this might be attributed to the non-photo-reactivity of naphtahlenic polyimide.

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Strong Orientation Anchoring and Shear Flow of a Nematic Liquid Crystal

  • Won Hee HAN
    • International journal of advanced smart convergence
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    • v.13 no.2
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    • pp.103-109
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    • 2024
  • A nonlinear numerical analysis of orientation and velocity fields of the full Ericksen-Leslie theory for a nematic liquid crystal under shear flow is given. We obtained for the first time the three-dimensional orientation and two component velocity profiles evolutions for both in- and out-of-shear plane orientation anchorings. Complex evolution routes to steady state were found even for shear aligning nematic. As the Ericksen number increases monotonic evolution of velocity and orientation shifts towards multi-region nucleating director rotation growth with complex secondary flow generations. We found that contrary to the in-shear-plane anchorings like homeotropic or parallel anchorings, binormal anchoring gives rise to substantial non-planar three-dimensional orientation with nonzero secondary flow.

Molecular Orientation and Optical Properties of Liquid Crystal Mixture Films of Photo-Reactive Mesogens and Non-Reactive Nematic Liquid Crystals (광경화성 액정과 비반응성 네마틱 액정 혼합 필름의 분자 배향 및 광학 특성)

  • Lee, Mong-Ryong;Shin, Mi-Young;Kim, Sung-Hyun;Song, Ki-Gook
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.493-498
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    • 2011
  • Reactive mesogens were used to prepare photo-cured liquid crystal films in which orientations of liquid crystal molecules were preserved by crosslinked networks of cured reactive mesogens. The molecular orientations of liquid crystal mixtures of photo-reative mesogens and non-reactive nematic liquid crystals were studied and compared before and after curing reactions. The effects of temperature and the amount of the non-reactive nematic liquid crystal in the mixture on birefringence of the liquid crystal films were investigated. It was found that optical compensation films with different birefringence could be prepared by controlling the amount of the nematic liquid crystals in the reactive mesogen mixtures.

A Study on Rubbing-induced Molecular Alignment on an Orientation Layer of Polyimide for Liquid Crystal Display (LCD의 폴리이미드 배향막에서 Rubbing에 의한 분자배향에 관한 연구)

  • 최승우;정재원;김승빈;황상만;천희곤;조동율
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.4
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    • pp.306-313
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    • 1998
  • To elucidate the liquid crystal(LC) molecules alignment mechanism, it is important to determine the molecular orientation of the rubbed polymer surface molecules that directly contact with LC molecules. In this work, the molecular orientation on a rubbed surface of polyimide (SE-3310, Nissan) film has been studied by polarized FTIR absorption spectroscopy. It has been found that molecular chain on the rubbed surface of polymide film are oriented along the rubbing direction and are tilted up on an average by 5.0$^{\circ}$. In the SHG(Second Harmonic Generation) measurement, the pretilt angle of molecular chain on the poylmide fim was 4.6$^{\circ}$ fro, the surface plane. And the pedit angle of liquid crystal (ZLI-2293, Merck) molecules measured by crystal rotation method was 5.4$^{\circ}$in the same rubbing condition.

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Liquid Crystal Alignment on the Multiple Photo-treated Layers by the Interfered Laser Light

  • Lee, Eun-Kyu;Kim, Jong-Hyun
    • Journal of Information Display
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    • v.8 no.1
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    • pp.6-9
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    • 2007
  • Orientational alignment patterns have been proven to be that they are very useful for realizing diverse properties of liquid crystals. Here we produced the patterns combining interfered laser beams. A photo-isomerizable polymer including azo unit, which induces nematic liquid crystal alignment to the polarized laser light, was used as the alignment to layer. Double irradiations into two orthogonal directions brought the orientation patterns similar to the checkerboard. It indicates the possibility of bistability on those patterns.

Thermotropic Liquid Crystal Polymer and PBT Blend

  • Lim, Sung-Tack;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.14-19
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    • 1998
  • Increasing demand for high modulus high strength polymeric materials have drawn considerable interest in industry. Thermotropic liquid crystal polymers (TLCP), differing from lyotropic liquid crystal polymers, have excellent melt processability and mechanical property resulting from the high degree of molecular orientation under a shear flow field in the molten state with relatively low viscosity$\^$1,2/.(omitted)

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Materials Stabilized Liquid Crystal Molecules on Chemically Modulated Polystyrene Surface Using Various Ion Beam Exposure Time

  • Han, Jeong-Min;Hwang, Hyun-Suk
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.6
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    • pp.285-287
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    • 2010
  • This paper introduces homogeneous liquid crystal (LC) orientations on chemically modulated polystyrene (PS) surfaces using various ion beam (IB) exposure times. Transparent PS was replaced with conventional polyimide material. As a non-contact process, the IB bombardment process induced LC orientation parallel to the IB process. Through x-ray photoelectron spectroscopy, it was shown that the chemical compositional changes of the IB-irradiated PS surfaces were determined as a function of IB exposure time. Using this analysis, the optimal IB bombardment condition was determined at an IB exposure time of up to 15 seconds. Moreover, thermal stability on IB-irradiated PS surfaces were carried out which showed that a relatively high IB exposure time induced a thermally stable LC alignment property.

Fast Switching Polymer-Stabilized Bend Nematic Devices

  • Kim, Sang-Hwa;Chien, Liang-Chy
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.194-195
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    • 2002
  • We report a fast-switching polymer-stabilized bend nematic (PSBN) device. The morphology study reveal a templated polymer networks captures the orientation of the field deformed nematic host.

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Study on orientation distribution of discotic liquid crystal in compensating film for viewing angle improvement of liquid crystal displays

  • Ryu, J.W.;Shin, Y.S.;Kim, Y.K.;Kim, S.Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.879-882
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    • 2008
  • The discotic liquid crystal in compensating film used for the viewing angle improvement of the twist nematic liquid crystal display panel is analyzed. For the optical characterization of the compensating film, we measured the polarization state of the light passing through the film as the tilt angle and the azimuth angle of the film were varied, and then we compared the measured polarization state with the calculated one. Finally we suggested the best fit configuration of the discotic liquid crystal.

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Effects of Dispersed Carbon nanotubes on Electro-Optic Characteristics and Orientation of Liquid Crystal in the In-Plane Switching Cell

  • Baik, I.S.;Jeon, S.Y.;Choi, J.Y.;Lee, S.H.;Lee, J.Y.;An, K.H.;Lee, Y.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.415-418
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    • 2005
  • To understand effects of carbon nanotubes (CNTs) dispersed in nematic liquid crystal (NLC) on electro-optic characteristic and orientation of the LC, we CNT-doped homogeneously-aligned NLC cells driven by in-plane field have been fabricated. The CNTs were aligned with a LC director from the initial state to below critical ac field, whereas the CNTs disturbed the LC director field above critical ac field. We observed motional textures in the form of vertical stripes in the local area between electrodes, which were associated with a deformation of the LC director orientation. This indicates that CNTs start vibrating three dimensionally with translational motion. Further, the hysterisis studies of voltage-dependent transmittance under dc electric field show that the amount of residual dc, which is related to image sticking problem in liquid crystal displays, is greatly reduced due to ion trapping by CNTS while keeping operating voltage and response time about the same compared to the un-doped LC cell.

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