• Journal of Hydrogen and New Energy
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• v.20 no.3
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• pp.238-244
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• 2009

We investigated the electrochemical properties of lithium/molybdenum sulfide(Li/MoS$_2$) using tetra (ethylene glycol) dimethyl ether(TEGDME) electrolyte. The Li/TEGDME/MoS$_2$ cell showed the first discharge capacity of 288mAhg$^{-1}$. From the XRD, SEM results of the MOS$_2$ electrode in various cut-off voltage during charge-discharge process, MoS$_2$ partly changed into Li$_2$S and Mo during discharge and Li$_2$S partly recovered into MOS$_2$ and Li during charge. Full charged MOS$_2$ electrode showed lump shape of big size, which might be related to agglomerate of MoS$_2$ particles. Therefore, the degradation might be related to decrease of active material for electrochemical reaction by agglomeration of MOS$_2$.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.68-69
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• 2011

The process of charge transfer at the interface between two semiconductors or between a metal and a semiconductor plays an important role in many areas of technology. The optimization of such devices requires a good theoretical description of the interfaces involved. This, in turn, has motivated detailed mechanistic studies of interfacial charge-transfer reactions at metal/organic, organic/organic, and organic/inorganic semiconductor heterojunctions. Charge recombination of photo-induced electron with redox species such as oxidized dyes or triiodide or cationic HTM (hole transporting materials) at the heterogeneous interface of $TiO_2$ is one of main loss factors in liquid junction DSSCs or solid-state DSSCs, respectively. Among the attempts to prevent recombination reactions such as insulating thin layer and lithium ions-doped hole transport materials and introduction of co-adsorbents, although co-adsorbents retard the recombination reactions as hydrophobic energy barriers, little attention has been focused on the anchoring processes. Molecular engineering of heterogeneous interfaces by employing several co-adsorbents with different properties altered the surface properties of $TiO_2$ electrodes, resulting to the improved power conversion efficiency and long-term stability of the DSSCs. In this talk, advantages of the coadsorbent-assisted sensitization of N719 in preparation of DSSCs will be discussed.

• Advances in materials Research
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• v.8 no.1
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• pp.37-46
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• 2019

Electrochemical double layer capacitors (EDLCs) which are fabricated using carbon based electrodes have been emerging at an alarming rate to fulfill the energy demand in the present day world. Activated charcoal has been accepted as a very suitable candidate for electrodes but its cost is higher than natural graphite. Present study is about fabrication of EDLCs using composite electrodes with activated charcoal and Sri Lankan natural graphite as well as a gel polymer electrolyte which is identified as a suitable substitute for liquid electrolytes. Electrochemical Impedance Spectroscopy, Cyclic Voltammetry and Galvanostatic Charge Discharge test were done to evaluate the performance of the fabricated EDLCs. Amount of activated charcoal and natural graphite plays a noticeable role on the capacity. 50 graphite : 40 AC : 10 PVdF showed the optimum single electrode specific capacity value of 15 F/g. Capacity is determined by the cycling rate as well as the potential window within which cycling is being done. Continuous cycling resulted an average single electrode specific capacity variation of 48 F/g - 16 F/g. Capacity fading was higher at the beginning. Later, it dropped noticeably. Initial discharge capacity drop under Galvanostatic Charge Discharge test was slightly fast but reached near stable upon continuous charge discharge process. It can be concluded that initially some agitation is required to reach the maturity. However, the results can be considered as encouraging to initiate studies on EDLCs using Sri Lankan natural graphite.

• Journal of the Korea Society of Computer and Information
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• v.29 no.3
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• pp.191-198
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• 2024

Korea is an import and export-oriented economy that relies on shipping transportation, and sea ports play an important role in national economic growth. To secure and maintain the competitiveness of these ports, hardware and software investments are required, but policy support can also be expected to have an effect. This study identified the irrationality of the system by exploratory analysis of the port facility fee discount system for Ulsan Port, an energy hub port, and suggested improvement measures to resolve it.This study analyzed the volume of Ulsan Port and the reduction of port facility usage fees for about 10 years and identified irrational factors that despite a special port for liquid cargo, a considerable reduction for container cargo is concentrated, and even because it was a passing ship, 100% reduction for entrance and clearance fees were provided to them, which could cause serious moral hazard.. As a way to improve the port facility charge discount system at Ulsan Port, this study proposed strengthening support for eco-friendly activities to support containers, adjusting the reduction rate for passing ships, or improving the reduction and exemption application process.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.443-455
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• 2013

Electrochemical studies on charge transfer reactions across the interface between two immiscible electrolyte solutions (ITIES) have greatly attracted researcher's attentions due to their wide applicability in research fields such as ion sensing and biosensing, modeling of biomembranes, pharmacokinetics, phase-transfer catalysis, fuel generation and solar energy conversion. In particular, there have been extensive efforts made on developing sensing platforms for ionic species and biomolecules via gelifying one of the liquid phases to improve mechanical stability in addition to creating microscale interfaces to reduce ohmic loss. In this review, we will mainly discuss on the basic principles, applications and future aspects of various sensing platforms utilizing ion transfer reactions across the ITIES. The ITIES is classified into four types : (i) a conventional liquid/liquid interface, (ii) a micropipette supported liquid/liquid interface, (iii) a single microhole or an array of microholes supported liquid/ liquid interface on a thin polymer film, and (iv) a microhole array liquid/liquid interface on a silicon membrane. Research efforts on developing ion selective sensors for water pollutants as well as biomolecule sensors will be highlighted based on the use of direct and assisted ion transfer reactions across these different ITIES configurations.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.4
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• pp.604-613
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• 2002

Generation characteristics of electrospray droplets for highly viscous liquid have been investigated by measuring size distributions of droplets emitted from the Taylor cone using glycerol solutions with various conductivities. Because of very small volatility of glycerol, droplet sizes can be measured by an aerodynamic size spectrometer (TSI Aerosizer DSP) with negligible evaporation of droplets. For highly conducting and viscous liquid, the sizes of the droplets electrosprayed from the Taylor cone are found to be relatively insensitive to applied voltages and the electrosprays assisted by the corona discharge call produce monodisperse droplets as long as the corona intensity is not too high. Near the minimum flow rate where a liquid cone is stable, the spray tends to consist of a one -peak monodisperse distribution of drop lets. However, at high flow rates, the spray bifurcates into bimodal distributions, which are consistent with the result of the previous study for less viscous liquids than our liquids. For liquid flow rates (Q) below 1 nl/s, the measured droplet diameters by the aerosizer are in the range of 0.30 to 1.2 ${\mu}{\textrm}{m}$ for the glycerol solutions. The diameters of monodisperse droplets scale approximately with $r^*=Q_$\tau$(Q$\tau$){^1/3}$ where $r^*$ is a characteristic length and $\tau$is the electrical relaxation time of the fluid. However, when compared with several represe ntative scaling laws, the droplet diameters are two to six factors greater than those predicted by the scaling laws. This may be closely related to the combined effect of the much higher viscosity and the electrical charge on the jet breakup of glycerol so solution.

• Journal of the Korean Electrochemical Society
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• v.14 no.4
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• pp.201-207
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• 2011

Supercapacitor has been studied actively as one of the most promising electrochemical energy storage system for a wide range of applications. To increase the energy density of supercapacitor, the introduction of ionic liquids is required. In this study, two types of EMI-$BF_4$ based on quaternary imidazolium salt were prepared with quaternary reaction and anion exchange. The structural characterization and thermal stability were analyzed by nuclear magnetic resonance($^1H$-NMR) and thermogravimetric analysis(TGA), respectively. Thermal stability of the EMI-$BF_4$ using TGA confirmed that, after heat treatment, the decomposition temperature of EMI-$BF_4$ was increased. Supercapacitors were fabricated with synthesized and commercial ionic liquids, and charge/discharge characteristics were also investigated. The capacity of supercapacitor, for synthesized and commercial EMI-$BF_4$ were determined to be 0.067 F and 0.073 F respectively, by means of charge/discharge test.

• Analytical Science and Technology
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• v.20 no.1
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• pp.61-69
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• 2007

The geometrical parameters, total and relative energies, vibrational frequencies, the HOMO-LUMO energy gap, and reorganization energies for the neutral molecule, anion, and cation of $C_{16}H_{16}O_3$ have been determined using density functional method (DFT). The highest level of theory employed in this study is $B3LYP/6-311G^{**}$. Harmonic vibrational frequencies were determined at the $B3LYP/6-311G^{**}$ level of theory. All positive vibrational frequencies were obtained to confirm minimum structures. The HOMO-LUMO energy gap and reorganization energies were calculated to predict the charge transport property of liquid-crystal.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.1
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• pp.26-33
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• 2007

The intake swirl motion, as one of dominant effects for an engine combustion. is very effective for turbulence enhancement during the compression process in the cylinder of 2-valve engine. Because the combustion flame speed is determined by the turbulence that is mainly generated from the mean flow of the charge air motion in intake port system. This paper describes the experimental results of swirl flow and combustion characteristics by using the oil spot method and back-scattering Laser Doppler velocimeter (LDV) in 2-valve single cylinder transparent LPG engine using the liquid phase LPG injection. For this. various intake port configurations were developed by using the flow box system and swirl ratios for different intake port configurations were determined by impulse swirl meter in a steady flow rig test. And the effects of intake swirl ratio on combustion characteristics in an LPG engine were analyzed with some analysis parameters that is swirl ratio. mean flow coefficient, swirl mean velocity fuel conversion efficiency. combustion duration and cyclic variations of indicated mean effective pressure(IMEP). As these research results, we found that the intake port configuration with swirl ratio of 2.0 that has a reasonable lean combustion stability is very suitable to an $11{\ell}$ heavy-duty LPG engine with liquid phase fuel injection system. It also has a better mean flow coefficient of 0.34 to develope a stable flame kernel and to produce high performance. This research expects to clarify major factor that effects on the design of intake port efficiently with the optimized swirl ratio for the heavy duty LPG engine.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.475-481
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• 2013

By using ionic liquid 1-hexylpyridinium hexafluorophosphate ($HPPF_6$) based carbon ionic liquid electrode (CILE) as the substrate electrode, a $CoMoO_4$ nanorods and myoglobin (Mb) composite was casted on the surface of CILE with chitosan (CTS) as the film forming material to obtain the modified electrode (CTS/$CoMoO_4$-Mb/CILE). Spectroscopic results indicated that Mb retained its native structures without any conformational changes after mixed with $CoMoO_4$ nanorods and CTS. Electrochemical behaviors of Mb on the electrode were carefully investigated by cyclic voltammetry with a pair of well-defined redox peaks from the heme Fe(III)/Fe(II) redox center of Mb appeared, which indicated that direct electron transfer between Mb and CILE was realized. Electrochemical parameters such as the electron transfer number (n), charge transfer coefficient (${\alpha}$) and electron transfer rate constant ($k_s$) were estimated by cyclic voltammetry with the results as 1.09, 0.53 and 1.16 $s^{-1}$, respectively. The Mb modified electrode showed good electrocatalytic ability toward the reduction of trichloroacetic acid in the concentration range from 0.1 to 32.0 mmol $L^{-1}$ with the detection limit as 0.036 mmol $L^{-1}$ ($3{\sigma}$), and the reduction of $H_2O_2$ in the concentration range from 0.12 to 397.0 ${\mu}mol\;L^{-1}$ with the detection limit as 0.0426 ${\mu}mol\;L^{-1}$ ($3{\sigma}$).