• KSBB Journal
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• v.8 no.4
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• pp.370-374
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• 1993

In transportation the amount of metal ion by crown ethers, dibenzo-18-crown-6 were investigated using ultraviolet spectrometer. Transported the amount of one valence metal ion as $K^+ and Li^+}$ was not so much. On the other hand, two valence metal ion increased by dibenzo-18-crown-6, which means that the ionic charge and hydration of two valence metal ion affected the carrying ability of crown ethers. The carrying ability of dibenzo-18-crown-6 was, therefore, adequate for two valence metal ion as $Ca^{2+}$ and $Ba^{2+}$. It was also suggested that transport metal ion by crown ethers, which is related rather the catching ability than the selectivity of metalion.

• Journal of ILASS-Korea
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• v.13 no.1
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• pp.1-8
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• 2008

It was investigated how fuel injection timing - early injection and later injection - in conjunction with throttle open rate effect the fuel-air mixing characteristics, Engine power, combustion stability and emission characteristics on a DI CNG spark Engine and control system that had been modified and designed according to the author's original idea. It was verified that the combustion characteristics were changed according to fuel injection timings and Engine conditions determined by different throttle open rates and rpm. It was found that the combustion characteristics greatly improved at the complete open throttle rate with an early injection timing and at the part throttle rate with a late injection timing. Combustion duration was governed by flame propagation duration in a late injection timing and by an early flame development duration in an early injection timing. As the result, we discovered that combustion duration is shortened, lean limit is improved, air-fuel mixing conditions controlled, and emissions reduced through control of fuel injection timing according to change of the throttle open rate.

• Journal of the Korean Ceramic Society
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• v.32 no.5
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• pp.567-574
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• 1995

The effect of MnO2 addition to 0.1mol% Sb2O3-doped BaTiO3 ceramics on microstructure and PTCR characteristics was studied. The PTCR characteristics was observed when 0.01 and 0.02 wt% MnO2 were added and sintered at 132$0^{\circ}C$ for 1 hour. The characteristics can be explained by the changes in the number and size of the abnormal grain growth due to the liquid phase during sintering. when the amount of MnO2 addition was 0.03 wt%, the sample showed NTCR characteristics with room-temperature resistivity over 109 Ωm regardless of the sintering temperature. This behavior can be described by the microstructure change due to the abnormal grain growth and charge compensation effect by MnO2 added. The room-temperature resistivity was increased as the amount of MnO2 was increased. And the specific resistivity ratio (pmax/pmin) showed maximum at 0.02wt% MnO2.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.254-257
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• 1997

In this paper, we investigated the effects of gap length and tip radius influenced in breakdown of mineral based insulation oil Electrode system was needle-plane geometry It is to model conductive extrusions in oil filled electrical power apparatus. The tip radius of needle electrode was 5, 10, 20 and 25${\mu}{\textrm}{m}$, respectively. We measured breakdown voltage for each of tip radius with increasing electrode gap, 2mm to 12mm. It was calculated electrical breakdown strength at tip using Mason\`s equation from breakdown voltage As gap lenght increased. breakdown strength increased linearly. But, as tip radius of needle increased, breakdown strength decreased exponentially. It can be explained by tole phenomenon that electron is easily injected, as tip radius increases, and effective work function decreases. When appling DC voltage. breakdown 7tr7ilgtll was higher wheal polarity of needle was negative than positive. It is because of the space charge effect ill accordance with the influence of liquid motion.

• Journal of the Korean Society of Safety
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• v.19 no.1
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• pp.56-59
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• 2004

In this paper, we investigated the influence of gap length and tip radius on breakdown of mineral based insulation oil. Applied voltages were DC and AC voltage. Electrode system was needle-plane structure. The tip radius of needle electrode was 5, 10, 20 and 25${\mu}m$, respectively. We measured breakdown voltage for each of tip radius with increasing electrode gap, 2mm to 12mm. Electric breakdown strength at tip was calculated using Mason's equation contained geometric figure. As gap length increased, breakdown strength increased linearly. But, as tip radius of needle increased, breakdown strength decreased exponentially. It can be explained by the phenomenon that electron is easily injected, as tip radius increases, and effective work function decreases. When appling DC voltage, breakdown strength was higher when polarity of needle was negative than positive. It is because of the space charge effect in accordance with the influence of liquid motion.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.256-256
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• 2013

Carbon nanotubes (CNT) / polyvinylidene fluoride (PVDF) piezoelectric composite films for nanogenerator devices were fabricated by spray coating method. When the CNT/PVDF mixture solution passes through the spray nozzle with small diameter by the compressed nitrogen gas, electric charges are generated in the liquid by a triboelectric effect. Then randomly distributed ${\beta}$ phase PVDF film could be re-oriented by the electric field resulting from the accumulated electrical charges, and might be resulted in extremely one-directionally aligned ${\beta}$ phase PVDF film without additional electric field for poling. X-ray diffraction patterns were used to investigate crystal structure of the CNT/PVDF composite films. It was confirmed that they revealed extremely large portion of the ${\beta}$ phase PVDF crystalline in the film. Therefore we could obtain the poled CNT/PVDF piezoelectric composite films by the spray coating method without additional poling process. Charge accumulation and resulting electric field generation mechanism by spray coating method were shown in Fig. 1. The capacitance of the CNT/PVDF films increased by adding CNTs into the PVDF matrix, and finally saturated. However, the I-V curves didn't show any saturation effect in the CNT concentration range of 0~4 wt%. Therefore we can control the performance of the devices fabricated from the CNT/PVDF composite film by adjusting the current level resulted from the CNT concentration with the uniform capacitance value.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.127.2-127.2
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• 2013

오늘날 유기고분자기반 태양전지는 다른 태양전지와 비교될 정도로 낮은 광변환효율로 인해 효율향 상을 위한 많은 연구들이 진행되어 왔다. 그중 패터닝을 통한 광포집률과 charge carrier 수집효율이 증가되었다는 많은 보고들이 있었다. 따라서 우리는 200~1,400 nm polystyrene bead를 합성하여 air-liquid interfacial 방법을 이용해 2차원 육방조밀구조를 갖는 template를 형성하고 Nanosphere lithography (NSL)를 이용하여 대면적으로 균일한 poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS)를 패턴화하였다. 균일한 패턴형성을 측정하기위해 Field Emission Scanning Electron Microscopy (FE-SEM), image를 얻었으며, Atomic Force Microscopy (AFM)를 통해 형성된 패턴의 낙차 높이를 얻었고, Near IR-UV-Vis을 통해 bead size 변화에따라 얻어진 PEDOT:PSS 패턴의 반사율을 측 정하였다.

• Journal of the Korean Magnetic Resonance Society
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• v.16 no.2
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• pp.147-161
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• 2012

Human melanocortin-4 receptor (hMC4R) among MC-Rs, expressed in the brain, is in charge of the control on energy homeostasis and food intake. The structure and function of human MC4R have been studied to understand their essential function and roles. To investigate the structure and function, it is necessary to prepare sufficient amounts of proteins. However, their expression and purification is demanding and time-consuming due to their innate insoluble and toxic properties. The heterozygous mutations of hMC4R, exchange of Asp 90 to Asn located in second transmembrane, cause severe obesity in human. To obtain purified hMC4R wt-TM2 for structural studies, it was first over-expressed and purified by fast protein liquid chromatography (FPLC) and then solution NMR studies were performed to get high-resolution spectra. In here, we established optimized purification scheme to get more purified target peptide.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.5
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• pp.418-425
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• 2006

An AHX (Accumulator Heat exchanger) consists of a commercial accumulator and an inner heat exchanger located inside of the accumulator. The AHX is used in multi air-conditioners to assure that liquid-phase refrigerant enters into the expansion device. This purpose is achieved by heat transfer between the refrigerant leaving the evaporator and the refrigerant leaving the condenser. In this study, the effects of AHX on the performance of a refrigeration system using R-22 were measured and the test results were analyzed. The operating characteristics of the refrigeration system with the AHX are considerably different from those without the AHX. Therefore, it is required to determine optimum refrigerant charge and optimum operating conditions when the AHX is used in the refrigeration system having a constant flow-area expansion device such as capillary tube.

• Journal of Sensor Science and Technology
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• v.30 no.6
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• pp.357-363
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• 2021

We developed a chemiresistive anion sensor using highly conductive carbon nanotube fibers (CNTFs) functionalized with anion receptors. Mechanically robust CNTFs were prepared via wet-spinning utilizing the nematic liquid crystal properties of CNTs in chlorosulfonic acid (CSA). For anion detection, polymeric receptors composed of dual-hydrogen bond donors, including thiourea 1, squaramide 2, and croconamide 3, were prepared and bonded non-covalently on the surface of the CNTFs. The binding affinities of the anion receptors were studied using UV-vis titrations. The results revealed that squaramide 2 exhibited the highest binding affinity toward AcO^-, followed by thiourea 1 and croconamide 3. This trend was consistent with the chemiresistive sensing responses toward AcO^- using functional CNTFs. Selective anion sensing properties were observed that CNTFs functionalized with squaramide 2 exhibited a response of 1.08% toward 33.33 mM AcO^-, while negligible responses (<0.1%) were observed for other anions such as Cl^-, Br^-, and NO₃^-. The improved response was attributed to the internal charge transfer of dual-hydrogen bond donors owing to the deprotonation of the receptor upon the addition of AcO^-.