• Journal of the Korean Institute of Gas
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• v.4 no.4 s.12
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• pp.20-24
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• 2000

The electrostatic safety consciousness of safety manager were investigated through questionnaires sent to liquid petroleum gas stations in Korea. In addition, hazards of fire and explosion due to electrostatic on synthetic-polymer-wears and cotton-wears were estimated experimentally. The results of questionnaires indicate most workers wear their working clothes indiscreetly owing to lack of knowledge of preventing electrostatic hazards. The amounts of electrostatic charge generated in synthetic-polymer-wears were 1.79, 1.44 and 1.02 $\mu$C in winter, spring and autumn and summer, respectively. All these values exceed the limit of working wears of 0.60$\mu$C requested by Korea Standard(KS K-7807) for preventing electrostatic hazards, which means hazards may occur. While, the charge in cotton-wears were in the range of 0.42 to 0.52$\mu$C, which suggests that the cotton-wears investigated in this study have no problem of hazards. Therefore workers, visual and experiential education are necessary for elevating the standard of on electrostatics. It is also necessary to establish standards of wearing for preventing electrostatic hazards.

• Journal of Electrochemical Science and Technology
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• v.14 no.4
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• pp.361-368
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• 2023

In lithium-sulfur (Li-S) batteries, encapsulation of sulfur in activated carbon (AC) materials is a promising strategy for preventing the dissolution of lithium polysulfide into electrolytes and enhancing cycle life, because instead of solid-liquid-solid reactions, quasi-solid-state (QSS) reactions occur in the AC micropores. While a high weight fraction of sulfur in S/AC composites is essential for achieving a high energy density of Li-S cells, the deterioration mechanisms under such conditions are still unclear. In this study, we report the deterioration mechanisms during charge-discharge cycling when the discharge products overflow from the AC. Analysis using scanning electron microscopy and energy-dispersive X-ray spectrometry confirms that the sulfur in the S/AC composites migrates outside the AC as cycling progresses, and it is barely present in the AC after 20 cycles, which corresponds to the capacity decay of the cell. Impedance analysis clearly shows that the electrical resistance of the S/AC composite and the charge-transfer resistance of QSS reactions significantly increase as a result of sulfur migration. On the other hand, the charge-discharge cycling performance under limited-capacity conditions, where the discharge products are encapsulated inside the AC, is extremely stable. These results reveal the degradation mechanism of a Li-S cell with micro-porous carbon and provide crucial insights into the design of a S/AC composite cathode and its operating conditions needed to achieve stable cycling performance.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.23-32
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• 2002

Combustion and flame propagation characteristics of the liquid phase LPG injection (LPLI) engine were investigated in a single cylinder optical engine. Lean bum operation is needed to reduce thermal stress of exhaust manifold and engine knock in a heavy duty LPG engine. An LPLI system has advantages on lean operation. Optimized engine design parameters such as swirl, injection timing and piston geometry can improve lean bum performance with LPLI system. In this study, the effects of piston geometry along with injection timing and swirl ratio on flame propagation characteristics were investigated. A series of bottom-view flame images were taken from direct visualization using an W intensified high-speed CCD camera. Concepts of flame area speed, In addition to flame propagation patterns and thermodynamic heat release analysis, was introduced to analyze the flame propagation characteristics. The results show the correlation between the flame propagation characteristics, which is related to engine performance of lean region, and engine design parameters such as swirl ratio, piston geometry and injection timing. Stronger swirl resulted in foster flame propagation under open valve injection. The flame speed was significantly affected by injection timing under open valve injection conditions; supposedly due to the charge stratification. Piston geometry affected flame propagation through squish effects.

• Journal of the Microelectronics and Packaging Society
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• v.12 no.3 s.36
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• pp.235-241
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• 2005

Incorporation of solid electrodes frequently involves plasma-based processing. The effect of plasma can influence the physical characteristics, depending on the magnitude in plasma. The undesired feature of plasma-induced damage should be prevented in characterizing the ultra-thin materials, such as ultra-thin films and organic monolayers. The current work at first proves the applicability of a liquid phase electrode in the electrical/dielectric properties through comparative work using Al and Hg on ultrathin $Al_2O_3$ films deposited through atomic layer deposition at low temperature: Two types of metals such as Aluminum (Al) and mercury (Hg) were used as electrodes in $Al_2O_3$ thin films in order to investigate the effect of electrode preparation on the current-voltage characteristics and impedance features as a function of thickness in $Al_2O_3$ film thickness. The success of Hg in $Al_2O_3$ thin films is applied to the AC and DC characterization of the organic monolayers obtained using the Langmuir-Blodgett method. From the DC current-voltage characteristics, the diode-like response is found to originate from the bulk response of the organic materials, evidenced by the fact and the capacitance is inversely related to the absolute thickness of organic layers.

• Journal of Mechanical Science and Technology
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• v.19 no.9
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• pp.1790-1800
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• 2005

The examination on the operating mechanism of a pulsating heat pipe (PHP) using visualization revealed that the working fluid in the PHP oscillated to the axial direction by the contraction and expansion of vapor plugs. This contraction and expansion is due to the formation and extinction of bubbles in the evaporating and condensing section, respectively. In this paper, a theoretical model of PHP was presented. The theoretical model was based on the separated flow model with two liquid slugs and three vapor plugs. The results show that the diameter, surface tension and charge ratio of working fluid have significant effects on the performance of the PHP. The following conclusions were obtained. The periodic oscillations of liquid slugs and vapor plugs were obtained under specified parameters. When the hydraulic diameter of the PHP was increased to d=3mm, the frequency of oscillation decreased. By increasing the charging ratio from 40 to 60 by volume ratio, the pressure difference between the evaporating section and condensing section increased, the amplitude of oscillation reduced, and the oscillation frequency decreased. The working fluid with higher surface tension resulted in an increase in the amplitude and frequency of oscillation. Also the average temperature of vapor plugs decreased.

• Journal of ILASS-Korea
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• v.19 no.1
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• pp.9-14
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• 2014

Performance of DI diesel engine with high-pressure fuel injection equipment is directly related to its emission characteristics and fuel consumption. So, the electro-hydraulic injector for the common-rail injection system should be designed to meet the precise high fuel delivery control capability. Currently, most high pressure injector in use has a needle driven by the solenoid coil energy or the piezo actuator controlled by charge-discharge of output pulse current. In this study, macroscopic spray approaching method was applied under constant volume chamber to research the performance of three different injectors : solenoid, indirect-acting piezo and direct-acting piezo type for CR direct-injection. LED back illumination for Mie scattering was applied on the liquid spray visible of direct-acting piezo injector, including hydraulic-servo type solenoid and piezo-driven injectors. As main results, we found that a direct-acting piezo injector had better a spray tip penetration than hydraulic-servo injectors in spray visualization.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.55.1-55.1
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• 2011

Dye-sensitized solar cell(DSSC) have been considered one of the promising alternatives to conventional solar cells, because of their low cost, easy fabrication and relatively high energy conversion efficiency. However, although the cell offers reasonable efficiency at least 11%, the use of a liquid electrolyte placed technological challenges for achieving the desired durability and operational stability of the cell. In order to prevent or reduce electrolyte leakage considerable efforts have been made, such as p-type semiconductor or organic hole-transport material that better mechanical properties and simple fabrication processes. In this work, we synthesized solid-state electrolyte containing LiI and KI metal salt with starting materials of poly ethylene oxide to substitute liquid electrolyte enhance the ionic conductivity and solar conversion efficiency. Li+ leads to faster diffusion and higher efficiency and K+ leading to higher ionic conductivity. The efficiency of poly ethylene oxide/LiI system electrolyte is 1.47% and poly ethylene oxide/potassium electrolyte is 1.21%. An efficiency of 3.24% is achieved using solid-state electrolyte containing LiI and KI concentrations. The increased solar conversion efficiency is attributed to decreased crystallinity in the polymer that leads to enhanced charge transfer.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.85-88
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• 2010

It is essential to understand the spray characteristics of injectors for the development of liquid rocket engine systems. In this study, the image processing methods for the measurement of the spray characteristics such as spray angle, breakup length and drop size of Gas-Centered Swirl Coaxial(GCSC) injectors have been investigated. The charge-coupled device (CCD) camera with a stroboscope was used to capture the spray images. It is to be hoped that this methods could contribute to acquisition of reliable and worthwhile data for the design of injectors. Moreover, this image processing method will be verified by comparison with other experimental results.

• Journal of Magnetics
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• v.10 no.3
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• pp.128-132
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• 2005

We report optical ab-plane properties of the layered sodium cobaltate, $Na_xCoO_2$ for x = 0.35 and 0.75. Two samples show metallic behaviors according to dc resistivity transport. Overall temperature dependent optical conductivities of both samples are very similar to those of the high temperature superconducting underdoped cuprates. We found that the optical scattering rate of x = 0.75 sample, which is in a Curie-Weiss metallic phase, varies linearly (non-Fermi liquid) with frequency and temperature while that of x = 0.35 sample, which is in a paramagnetic metallic phase, varies quadratically (Fermi liquid) with frequency and temperature. Both x = 0.35 and 0.75 samples have an onset of scattering around $600\;cm^{-1}$ which can be attributed to the interaction of charge carriers with a bosonic collective mode in a system.

• Applied Chemistry for Engineering
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• v.25 no.3
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• pp.292-299
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• 2014

In this study, nitrogen doped carbon felt (CFt) is prepared using thermal oxidation and liquid phase ammonia treatment to improve the efficiency for vanadium redox flow batteries (VRFB). The electrochemical properties of prepared CFt electrodes are investigated using cyclic voltammetry (CV) and charge/discharge test. The XPS result shows that the increase of liquid phase ammonia treatment temperature leads to the increased nitrogen functional group on the CFt surface. Redox reaction characteristics using CV reveal that the liquid phase ammonia treated CFt electrodes are more reversible than the thermally oxidized CFt. When CFt is treated by the liquid phase ammonia at $300^{\circ}C$, VRFB cell energy efficiency, voltage efficiency, and current efficiency are increased about 6.93%, 1.0%, and 4.5%, respectively, compared to those of the thermally oxidized CFt. These results are because nitrogen functional groups on CFt help to improve the electrochemical properties of redox reaction between electrode and electrolyte interface.