• Journal of Hydrogen and New Energy
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• v.31 no.1
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• pp.41-48
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• 2020

The present study discussed the thermodynamic analysis of the hydrogen liquefaction process to build a hydrogen liquefaction pilot plant with a small capacity (0.5 ton/day). A 2-stage Brayton cycle utilizing LNG/LN2 cold energy was suggested to be built in Korea for the hydrogen liquefaction pilot plant with a small capacity. Thermodynamic analysis on the effect of various variables on the efficiency of hydrogen liquefaction process was performed. As a result, the CASE in which the ortho-para conversion catalyst was infiltrated inside the heat exchanger showed the best process efficiency. Finally, thermodynamic analysis was performed on the effect of turbo expander compression ratio on the hydrogen liquefaction process and it was confirmed that an optimal turbo expander compression ratio exists.

• International Journal of Naval Architecture and Ocean Engineering
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• v.6 no.3
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• pp.598-625
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• 2014

To support the procedure for determining an optimal liquefaction cycle for FLNG FEED, an ontological modeling method which can automatically generate various alternative liquefaction cycles were carried out in this paper. General rules in combining equipment are extracted from existing onshore liquefaction cycles like C3MR and DMR cycle. A generic relational model which represents whole relations of the plant elements has all these rules, and it is expressed by using the system entity structure (SES), an ontological framework that hierarchically represents the elements of a system and their relationships. By using a process called pruning which reduces the SES to a candidate, various alternative relational models of the liquefaction cycles can be automatically generated. These alternatives were provided by XML-based formats, and they can be used for choosing an optimal liquefaction cycle on the basis of the assessments such as process simulation and reliability analysis.

• Journal of the Korean Institute of Gas
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• v.17 no.1
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• pp.67-72
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• 2013

The LNG liquefaction plant which have a higher value-added business in the LNG value chain takes about 35% of total cost. Liquefaction process is core technology of liquefaction plant. Almost all of cost which was consumed from the liquefaction plant, using for operation energy of liquefaction process. The cost can be reduced by increasing efficiency of liquefaction cycle. C3MR(propane pre-cooled, mixed refrigerant cycle) which liquefies NG using propane and MR cycle has the high efficiency, so C3MR is mostly used liquefaction process in LNG industry. In this study, process simulation and analysis were performed for C3MR process. C3MR process variables were found through this simulation and analysis, and then the process optimization was performed. It is considered that the results of process analysis, process variables and process optimization study can be utilized to develope new liquefaction process.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.1312-1316
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• 2009

Growing interest in $CO_2$ capturing from industrial processes and storage in underground formations is emerging from commitments in reducing $CO_2$ emissions manifested in the Kyoto Protocol. In this paper, $CO_2$ liquefaction system is treated in focus of liquefaction efficiency & production rate. Presently $CO_2$ is transported in ships or trucks at a pressure of 14-20 bar. Considering this, the liquefaction pressures of 20, 15, 6.5 bar are selected. Compressor work and cooling capacity are calculated and compared. In order to investigate the effect of intercooling, the compressed gas after compressor work is cooled by ambient air or seawater. In case of applying the intercooling to the system, consuming energy can be saved larger than 20%. In the lower liquefaction pressure, the more $CO_2$ can be obtained due to higher density. In the liquefaction pressure of 6.5 bar, its $CO_2$ production is about 35% higher than that of the system with the liquefaction pressure, 20 bar.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2001.09a
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• pp.28-35
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• 2001

Liquefaction potential on the specific site of nuclear power plant is analyzed and reviewed. The layered site fur this study consists of silt and sand. Based on the limited available soil data, maximum shear strength at critical locations using Seed & Idriss method and computer program SHAKE is calculated, and liquefaction potential is reviewed. Seismic input motion used fur the assessment of liquefaction is the artificial time history compatible with the US NRC regulatory Guider .60. Assessment results of the liquefaction are validated by analyzing to the other typical soil fecundations which can show the effects of foundation depth and soil data.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.6
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• pp.732-741
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• 2020

Environmental regulations have recently been strengthened. Consequently, floating LNG(Liquefied Natural Gas) power plants are being developed, which are new power generation plants that generate electricity by utilizing LNG. A floating LNG power plant generates BOG(Boil-Off Gas) during its operation, and the system design of such a plant should be capable of removing or re-liquefying BOG. However, the design of an offshore plant differs according to the marine requirements. Hence, a process simulation model of the BOG re-liquefaction system is needed, which can be continuously modified to avoid designing the floating LNG power plant through trial and error. In this paper, to develop a model appropriate for the floating LNG power plant, a commercial process simulation program was employed. Depending on the presence of refrigerants, various BOG re-liquefaction systems were modeled for comparing and analyzing the re-liquefaction rates and liquid points of BOG. Consequently, the BOG re-liquefaction system model incorporating nitrogen refrigerants is proposed as the re-liquefaction system model for the floating LNG power plant.

• Journal of Hydrogen and New Energy
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• v.31 no.6
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• pp.571-577
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• 2020

Thermal analysis was performed for a cold box of a hydrogen liquefaction pilot plant with 0.5 ton/day capacity. The pilot plant has adopted a hydrogen liquefaction process using two-stage helium Brayton cycle with precooling of liquid nitrogen. The cold box for hydrogen liquefaction has generally vacuum insulation but inevitable heat invasion by conduction and radiation exists. The heat loads were calculated for cold box internals according to multilayer insulation emissivity. Total heat load of 181.7 W is estimated for emissivity of 0.03 considered in field condition.

• Journal of the Korean Institute of Gas
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• v.15 no.3
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• pp.1-5
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• 2011

For the hydrogen liquefaction, the large amount of energy is consumed, because precooling, liquefaction and ortho/para conversion heats should be eliminated. In this paper the basic design and thermal analysis are carried out to reduce the energy consumption by using LNG cold energy for precooling process in hydrogen liquefaction processes. The LNG cold energy utilization for hydrogen precooling enables not only to get energy saving for liquefaction, but to recover the wasted cold energy to sea water at the LNG terminal. The results show that the energy saving rate for liquefaction using LNG cold energy is almost 75% of current industrial hydrogen liquefaction plant. The demand flow-rate of LNG is only 15T/D for 1T/D hydrogen liquefaction.

• Journal of Hydrogen and New Energy
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• v.30 no.6
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• pp.490-498
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• 2019

The intermittent electric power supply of renewable energy can have extremely negative effect on power grid, so long-term and large-scale storage for energy released from renewable energy source is required for ensuring a stable supply of electric power. Power to gas which can convert and store the surplus electric power as hydrogen through water electrolysis is being actively studied in response to increasing supply of renewable energy. In this paper, we proposed the novel concept of hydrogen liquefaction process combined with pre-cooling process using the liquid air. It is that hydrogen converted from surplus electric power of renewable energy was liquefied through the hydrogen liquefaction process and vaporization heat of liquid hydrogen was conversely recovered to liquid air from ambient air. Moreover, Comparisons of specific energy consumption (kWh/kg) saved for using the liquid air pre-cooling was quantitatively conducted through the performance analysis. Consequently, about 12% of specific energy consumption of hydrogen liquefaction process was reduced with introducing liquid air for pre-cooling and optimal design point of helium Brayton cycle was identified by sensitivity analysis on change of compression/expansion ratio.

• Progress in Superconductivity and Cryogenics
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• v.15 no.2
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• pp.1-8
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• 2013

This paper reviews the development status of magnetic refrigeration system for hydrogen liquefaction. There is no doubt that hydrogen is one of most important energy sources in the near future. In particular, liquid hydrogen can be utilized for infrastructure construction consisting of storage and transportation. Liquid hydrogen is in cryogenic temperatures and therefore high efficient liquefaction method must be studied. Magnetic refrigeration which uses the magneto-caloric effect has potential to realize not only the higher liquefaction efficiency > 50 %, but also to be environmentally friendly and cost effective. Our hydrogen magnetic refrigeration system consists of Carnot cycle for liquefaction stage and AMR (active magnetic regenerator) cycle for precooling stages. For the Carnot cycle, we develop the high efficient system > 80 % liquefaction efficiency by using the heat pipe. For the AMR cycle, we studied two kinds of displacer systems, which transferred the working fluid. We confirmed the AMR effect with the cooling temperature span of 12 K for 1.8 T of the magnetic field and 6 second of the cycle. By using the simulation, we estimate the total efficiency of the hydrogen liquefaction plant for 10 kg/day. A FOM of 0.47 is obtained in the magnetic refrigeration system operation temperature between 20 K and 77 K including LN2 work input.