• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.2909-2912
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• 2009

The amines studied in this study are less reactive toward ethyl propiolate (3) in MeCN than in H$_2$O although they are 7 to 9 pK$_a$ units more basic in the aprotic solvent. The reactivity of morpholine and deuterated morpholine toward 3 is found to be identical, indicating that proton transfer occurs after rate-determining step (RDS). The fact that kinetic isotope effect is absent excludes a stepwise mechanism in which proton transfer occurs in RDS as well as a concerted mechanism in which nucleophilic attack and proton transfer occur concertedly through a 4-membered cyclic transition state (TS). Thus, the reactions have been concluded to proceed through a stepwise mechanism in which proton transfer occurs after RDS. Brønsted-type plots are linear with small ${\beta}_{nuc}$ values, i.e., ${\beta}_{nuc}$ = 0.29 in H$_2$O and ${\beta}_{nuc}$ = 0.51 in MeCN, indicating that bond formation is not advanced significantly in RDS. The small ${\beta}_{nuc}$ value also supports the conclusion drawn from the study of kinetic isotope effect.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1058-1063
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• 2004

This paper presents a new approach regarding thermal characteristics associated with a design of the high efficiency motor. Electrical conduction materials, such as coil and aluminum embedded in the core generate high heat exerting negative influence on both lifetime and performance of machine. Thus, it is necessary to design high efficiency motor considering heat transfer in order to improve motor performance and to be protected against overheating. In this paper, firstly, numerical analysis of electromagnetic field is carried out by the nonlinear transient finite element method (FEM). Secondly, the linear static FEA of magneto-thermal field is implemented by applying source current computed by the nonlinear transient analysis. FE results are validated in terms of electromagnetics and heat transfer by experiments. And then, the pseudo-transient topology optimization using a multi-objective function is performed. The proposed method is applied to a squirrel cage single-phase induction motor of the scroll compressor.

• 한국항공우주학회지
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• 제33권3호
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• pp.39-46
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• 2005

본 논문에서는 광범위한 함수 근사성질을 갖고 있는 신경회로망을 이용하여, 시스템의 입출력 조화성분의 선형관계를 표현하기 위해 추정된 전달행렬의 적용범위를 확장할 수 있는 적응 고차조화제어(Higher Harmonic Control, HHC) 기법을 제안하고 있다. 신경회로망의 학습신호는 추정된 전달행렬을 기반으로 계산된 최적제어 이득 값 행렬을 이용하여 구성된다. 내부 안정성을 보장하기 위하여 신경회로망의 가중치 학습방법은 Lyapunov 직접 방법을 이용하여 유도하였다. 6개의 입력과 2개의 출력을 갖는 비선형 시스템에 대한 시뮬레이션 결과를 통해 적응 고차조화제어 기법이 불확실한 전달행렬에 적용 가능함을 보였다.

• 조명전기설비학회논문지
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• 제28권1호
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• pp.69-78
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• 2014

In this paper, characteristics of wireless power transfer (WPT) systems using magnetically coupled resonance scheme with relay coils are investigated and modeled. Especially, asymmetric frequency splitting characteristics in over-coupled region of WPT with relays are measured and accurately modeled. Transmitter, receiver, and relay coils are modeled with R, L, C equivalent circuits. Using these circuit models and mutual inductances between coils, a WPT system is described with a linear matrix equation. For under-coupled region, a matrix is simplified considering only mutual inductances between adjacent coils. An analytical transfer characteristic of WPT system vs. distance is extracted using an inverse matrix that is acquired by Gauss elimination method for the simplified matrix. For over-coupled region, a matrix considering mutual inductances between non-adjacent coils is used to predict a frequency splitting characteristics accurately. A 6.3MHz WPT system with relay coils is implemented and measured. An accuracy of the model is investigated by comparing the output of the model with the measured results.

• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.121-126
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• 1984

The charge transfer complex formations between indole derivatives and methylviologen were investigated spectroscopically. In aqueous solutions near room temperature, the order of complex stability was tryptamine < tryptophan < indole < indole acetate, which is the reverse order of the magnitude of molar absorptivities. This was interpreted as involvement of contact charge transfer. The decrease of enthalpy of complex formation (-${\Delta}$H) was highest in tryptamine, and lowest in indole acetate. ${\Delta}$H and entropy of complex formation (${Delta}$S) varied nearly in a linear fashion with isokinetic temperature $242^{\circ}$K. These results were attributed to the hydration-dehydration properties of the side chains in indole derivatives. Except indole acetate, the complex formations were greatly enhanced by the addition of sodium dodecyl sulfate(SDS). However, the direct relationship between the enhanced complex formation and SDS micelle formation was not found. The enhanced charge transfer interaction inSDS solutions was attributed to the increased ${\Delta}$S by interaction between methylviologen and SDS in premicellar level. The order of complex stability in SDS solutions was indole acetate < tryptophan < trypamine < indole, which reflects the hydrophobicity of indole derivatives as well as electrostatic interaction between indole derivatives and methylviologen associated with SDS.

• 설비공학논문집
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• 제13권2호
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• pp.122-133
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• 2001

Pool boiling heat transfer coefficients(HTCs) of HFC32/HFC134a, HFC125/HFC134a, HFC32/HFC125 and HFC32/HFC125/HFC134a were measured on a horizontal smooth tube. The experimental apparatus was specially designed to simulate the real heat transfer tube with the use of the secondary fluid of water. Data were taken in the order of decreasing heat flux starting at 80kW/$m^2\; and\; ending\; at\; 5kW/m^2$ in the pool temperature at $7^{\circ}C$. Test results showed that HTCs of these mixtures were 11~38% lower than those of ideal HTCs calculated by a linear mixing rule with pure fluids、 HTCs. Experimental data were compared with Stephan & Korner, Thome, Schlunder, Thome & Shakir、s correlations only to find that those correlations were not satisfactory for all fluids. Hence, a new correlation based on the present data was proposed which could be applied even to the ternary mixture. The correlation predicts the degradation of HTCs of mixtures well, showing a mean deviation of less than 15% for all the mixture data.

• 대한설비공학회지:설비저널
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• 제13권2호
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• pp.10-15
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• 1984

The aims of this study are to obtain a suitable method and a proper mesh for investigation of the temperature distribution and heat transfer. The relative errors of temperature distribution and heat transfer for each mesh are acquired in accordance with linear finite element (FEM 3), square finite element (FEM 6), cubic finite element (FEM 10), and finite difference method (FDM). It has been found that FEM 10 is the most accurate measure to obtain the temperature distribution and heat transfer. However, no significant results have been obtained successfully, because when higher order finite element methods are used the more computational efforts are necessary due to the distribution of elements. The results of this study are as follows ; 1 . In case of a=b=L, meshes for less than $1\%$ relative errors (temperature distribution) acquired in various methods to exact solution are $2\times2,\;4\times4,\;8\times8\;and\;8\tiems8$ for each FEM 10, FEM 6, FEM 3 and FDM and a=L, b=1/2L are $10\times5$ for each FEM 3 and FDM. And the tendency of results acquired of heat transfer is similar to those above. 2 . In computational efforts (a=b=L), FEM 6 has taken 21 times. and FEM 10 154times FEM 3 and FDM and FEM 3 is the sane as FDM.

• 한국지반공학회논문집
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• 제26권9호
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• pp.5-13
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• 2010

최근 초고층 빌딩과 대형 교량의 사용 증가로 인하여 바렛말뚝에 대한 사용이 증가하고 있지만 바렛말뚝의 주면부 거동특성에 대한 연구는 미비한 실정이다. 이에 본 연구에서는 실물크기 시험말뚝에 대한 현장재하시험을 실시하여 표준관입시험 저항치와 바렛말뚝의 주면히중전이곡선을 산정하는 경험식을 제안하였다. 또한 3차원 유한요소해석을 실시하여 말뚝과 지반과의 경계면 효과를 살펴보았으며 이를 현장자료와 비교하여 평가하였다.

• 대한교통학회지
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• 제30권1호
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• pp.125-133
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• 2012

본 논문에서는 스마트카드 데이터를 이용하여 서울시의 대중교통 환승통행 현황을 분석하고, 이를 통해 환승체계 효율화의 필요성을 살펴보았다. 특별히 환승효율성 제고를 위한 환승센터 건립 시 그 입지선정을 위한 수리모형을 이중구조모형으로 구축/제시하였다. 상위모형은 입지결정 모형으로 지역별 환승센터 개수 및 총건설비용 예산 제약하에서 총통행비용을 최소화하는 선형 0-1 정수모형이고, 하위 모형은 환승센터 입지 여부에 따른 사용자 평형 경로 선택 모형으로 구성된다. 모형의 해법으로 상위 및 하위 모형의 해를 순차적으로 구하는 방법을 제시하였고, 예제네트워크 적용을 통해 해법의 수렴성과 모형의 적용성을 평가하였다. 그 결과 본 논문에서 구축된 모형과 해법을 이용하여 효과적으로 최적의 환승센터 입지를 결정할 수 있음을 확인하였다. 마지막으로, 실제 네트워크에 적용하기 위한 방법론을 검토한 결과 본 논문의 모형과 해법이 현실에서도 충분히 활용될 수 있을 것으로 기대된다.

• Journal of Mechanical Science and Technology
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• 제18권8호
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• pp.1435-1450
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• 2004

Experimental data are presented which describe the effects of a combustor-level high free-stream turbulence on the near-wall flow structure and heat/mass transfer on the endwall of a linear high-turning turbine rotor cascade. The end wall flow structure is visualized by employing the partial- and total-coverage oil-film technique, and heat/mass transfer rate is measured by the naphthalene sublimation method. A turbulence generator is designed to provide a highly-turbulent flow which has free-stream turbulence intensity and integral length scale of 14.7% and 80mm, respectively, at the cascade entrance. The surface flow visualizations show that the high free-stream turbulence has little effect on the attachment line, but alters the separation line noticeably. Under high free-stream turbulence, the incoming near-wall flow upstream of the adjacent separation lines collides more obliquely with the suction surface. A weaker lift-up force arising from this more oblique collision results in the narrower suction-side corner vortex area in the high turbulence case. The high free-stream turbulence enhances the heat/mass transfer in the central area of the turbine passage, but only a slight augmentation is found in the end wall regions adjacent to the leading and trailing edges. Therefore, the high free-stream turbulence makes the end wall heat load more uniform. It is also observed that the heat/mass transfers along the locus of the pressure-side leg of the leading-edge horseshoe vortex and along the suction-side corner are influenced most strongly by the high free-stream turbulence. In this study, the end wall surface is classified into seven different regions based on the local heat/mass transfer distribution, and the effects of the high free-stream turbulence on the local heat/mass transfer in each region are discussed in detail.