• Analytical Science and Technology
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• v.8 no.4
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• pp.597-601
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• 1995

The transfer of chloride ion across an anion exchange membrane (AEM) was investigated by cyclic voltammetry (CV) and electrochemical impedance spectra. In CV experiment, when the size of the hole in membrane was much smaller than the distance between membrane holes, the Cl anion transfer showed steady state voltammetric behavior. Each hole in membrane can be regarded as a microelectrode and the membrane was equivalent to a microelectrode array in this condition. When the hole in membrane was large or the distance between membrane holes was small, the CV curve of the Cl anion transfer across membrane showed peak shape, which attributed to linear diffusion. In ac impedance measurement, the impedance spectrum of the membrane system was composed of two semicircles at low de bias, corresponding to the bulk characteristics of the membrane and the kinetic process of ion transfer, respectively. The bulk membrane resistance increases with increasing dc bias and only one semicircle was observed at higher dc bias. The parameters related to kinetic and membrane properties were discussed.

• International Journal of Air-Conditioning and Refrigeration
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• v.6
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• pp.56-66
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• 1998

The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

• YAKHAK HOEJI
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• v.33 no.3
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• pp.141-148
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• 1989

The weak UV absorbing antihistaminics such as chlorpheniramine, triprolidine, tripelennamine and diphenhydramine were analyzed by charge-transfer spectrophotometric method. The results obtained are summarized as folows. It was possible to determine a weak UV absorbing antihistaminics using the intense charge-transfer UV bands in chloroform. Charge transfer complexes were formed in a 1:1 ratio between antihistaminics and iodine in chloroform. Linear relationship was found between absorbance and concentration in the range of $1.0\;{\times}\;10^{-5}M-5.0\;{\times}\;10^{-5}M$ for chlorpheniramine( ${\varepsilon}\;=\;2.082\;{\times}\;10^4$) and tripelennamine ( ${\varepsilon}\;=\;1.578\;{\times}\;10^4$), $1.0\;{\times}\;10^{-5}M-8.0\;{\times}\;10^{-5}M$ for triprolidine ( ${\varepsilon}\;=\;1.120\;{\times}\;10^4$) and $1.0\;{\times}\;10^{-5}M-1.0\;{\times}\;10^{-4}M$ for diphenhydramine ( ${\varepsilon}\;=\;9.900\;{\times}\;10^3$). Charge transfer complexes of chlorpheniramine, triprolidine and tripelennamine have absorption maxima at 293 nm and complex form of diphenhydramine has absorption maximum at 270 nm. By UV, IR spectra, it could be inferred that CT-complexes were formed by interaction between the basic nitrogen of antihistaminics as electron donor (non bonding electron) and iodine as electron acceptor (${\sigma}$ bonding electron).

• Journal of the Korean Ceramic Society
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• v.34 no.7
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• pp.767-773
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• 1997

Thermal shock behavior of alumina ceramics were studied by quenching the heated alumina specimen into the water of various temperatures over 0~10$0^{\circ}C$. The critical thermal shock temperature difference ( Tc) of the specimen decreased almost linearly from 275$^{\circ}C$ to 20$0^{\circ}C$ with increase in the cooling water temperature over 0~6$0^{\circ}C$. It is probably due to the increase of the maximum cooling rate which is dependent of the convection heat transfer coefficient. The convection heat transfer coefficient is a function of the temperature of the cooling water. However, the critical thermal shock temperature difference( Tc) of the specimen increased at 25$0^{\circ}C$ over 80~10$0^{\circ}C$ due to the film boiling of the cooling water. The maximum cooling rate, which brings about the maximum thermal stress of the specimen in the cooling process, was observed to increase linearly with the increase in the quenching temperature difference of the specimen due to the linear relationship of the convection heat transfer coefficient with the water temperature over 0~6$0^{\circ}C$. The critical maximum cooling rate for thermal shock fracture was observed almost constant to be about 260$\pm$1$0^{\circ}C$/s for all water temperatures over 0~6$0^{\circ}C$. Therefore, thermal shock behavior of alumina ceramics is greatly influenced by the convection heat transfer coefficient of the cooling water.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.7
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• pp.879-886
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• 2004

A numerical optimization has been carried out to determine the shape of the three-dimensional channel with oblique ribs attached on both walls to enhance turbulent heat transfer. The response surface based optimization is used as an optimization technique with Reynolds-averaged Navier-Stokes analysis of fluid flow and heat transfer. Shear stress transport (SST) turbulence model is used as a turbulence closure. Numerical results fur heat transfer rate show good agreements with experimental data. four dimensionless variables such as, rib pitch-to-rib height ratio, rib height-to-channel height ratio, streamwise rib distance on opposite wall to rib pitch ratio, and the attack angle of the rib are chosen as design variables. The objective function is defined as a linear combination of heat-transfer and friction-loss related coefficients with a weighting factor. D-optimal method is used to determine the training points as a means of design of experiment. Sensitivity of the objective parameters to each design variable has been analyzed. And, optimal values of the design variables have been obtained in a range of the weighting factor.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.7
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• pp.185-194
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• 2004

In order to analyze the motion errors of the aerostatic stage, it is necessary to consider the influence of the moment variation occurred inside the pads. In this paper, a motion error analysis method utilizing the transfer functions on the reaction force and moment is proposed, and general characteristics of the transfer functions are discussed. Calculated motion errors by the proposed method show good agreement with the ones calculated by Multi fad Method, which is considered the entire table as an analysis object. Also, by the introduction of the transfer function of motion errors, which represent the relationship between the spatial frequency components of the rail form error and motion errors, motional characteristics of the porous aerostatic stage can be generalized. In detail, the influence of the spatial frequencies is analyzed qualitatively, and the patterns of the insensitive frequencies which almost do not affect the linear motion error or angular motion error according to the rail length ratio and the number of the pad are verified. The relationship between the moment variation occurred inside the pads and the motion errors is also verified together.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.9
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• pp.484-492
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• 2013

Nucleate pool boiling heat transfer coefficients (HTCs) are measured with HFC32/HFC152a mixture at several compositions. All data are taken at the liquid pool temperature of $7^{\circ}C$, on a horizontal plain square surface of $9.53{\times}9.53$ mm, with heat fluxes of 10 $kW/m^2$ to 100 $kW/m^2$ with an interval of 10 $kW/m^2$, in the increasing order of heat flux. Test results show that the HTCs of these mixtures are up to 45% lower than those of the ideal HTCs calculated by a linear mixing rule with pure fluids' HTCs, due to the mass transfer resistance associated with non-azeotropic refrigerant mixtures. Pool boiling data show the deduction in HTCs with an increase in GTD of the mixture. The present mixture data agree well with five well known correlations, within 20% deviation.

• Wind and Structures
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• v.29 no.1
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• pp.65-75
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• 2019

A heated square cylinder (with height $A^*$) is kept parallel to the cold wall at a fixed gap height $0.5A^*$ from the wall. Another adiabatic rectangular cylinder (of same height $A^*$ and width $0.5A^*$) is placed upstream in an inline tandem arrangement. The spacing between the two cylinders is fixed at $3.0A^*$. The inlet flow is taken as Couette-Poiseuille flow based non-linear velocity profile. The conventional fluid (also known as base fluid) is chosen as water (W) whereas the nanoparticle material is selected as $Al_2O_3$. Numerical simulations are performed by using SIMPLE algorithm based Finite Volume approach with staggered grid arrangement. The dependencies of hydrodynamic and heat transfer characteristics of the cylinder on non-dimensional parameters governing the nanofluids and the fluid flow are explored here. A critical discussion is made on the mechanism of improvement/reduction (due to the presence of the upstream cylinder) of heat transfer and drag coefficient, in comparison to those of an isolated cylinder. It is observed that the heat transfer increases with the increase in the non-linearity in the incident velocity profile at the inlet. For the present range studied, particle concentration has a negligible effect on heat transfer.

• The Journal of Asian Finance, Economics and Business
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• v.9 no.5
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• pp.261-272
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• 2022

Agriculture and the rural sector play a crucial part in Vietnam's socio-economic growth. The study's goal is to see how technology transfer from young intellectual research activities affects the economic evolution of Vietnam's agriculture and rural sector in the 4.0 technology era. The research has used a quantitative method through analysis of linear structural model SEM, with a survey scale including 480 samples that are managers in departments and branches in agriculture and rural sector in the provinces in Vietnam. Research results show that technology transfer from research activities of the young intellectual has a direct and positive impact on economic development in agriculture and rural sector. This level of impact will increase with the participation of the intermediary factors such as awareness of managers, trust, and mechanisms in the mobilization and use of resources. These results contribute to both theoretical and practical aspects when proving the impact of technology transfer from the research activity of the young intellectual to the economic development in the field of agriculture and rural sector in the 4.0 era and the mediating role of awareness of managers, trust and mechanisms in the mobilization and use of resources.

• Journal of Navigation and Port Research
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• v.44 no.3
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• pp.145-150
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• 2020

The ship motion of large LNG ships affects ships' safety. The purpose of this study was to estimate the transfer function of roll motion among the hull motion of 153,000 m3 class LNG vessels. The ship motion transfer function was modeled using a Linear Time-Invarient system with single input, single output, and transfer function. The transfer function of the ship motion was estimated by the system identification method using single ocean wave as input of the model, and using the roll motion of the LNG ship obtained through ANSYS as the output of the model. The usefulness of the experimental results was evaluated using the precision and estimation rate of the model for cases wherein the different transfer function dimensions. Results of the experiment showed a precision at 99% and 98%, with estimation rate at 78% and 50%. From these results, we found the proposed method of estimating the transfer function of ship motion in this study reasonable. In the future, data of ship motion in actual sea conditions will be acquired and it will be applied to make the construction of models with multiple inputs and multiple outputs for practical use.