• Title/Summary/Keyword: Linear blending

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Miscibility of Branched Polycarbonate Blends with Poly(ethylene-co-1,4-dimethyl cyclohexane terephthalate) Copolyesters

  • Song, Jeong-Oh;Jeon, Mi-Young;Kim, Chang-Keun
    • Macromolecular Research
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    • v.15 no.7
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    • pp.640-645
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    • 2007
  • The phase behavior of branched polycarbonate (BPC) blends with poly(ethylene terephthalate-co-1,4-dimethyl cyclohexane terephthalate) copolyesters (PECT), as well as their rheological properties, were assessed. Even though BPC blends with PECT prepared by solvent casting proved to be immiscible, BPC and PECT copolyesters containing 1,4-dimethyl cyclohexane (CHDM) from 32 to 80 mole% formed homogeneous mixtures upon heating. The homogenization temperatures of the blends decreased with increasing CHDM content in PECT. The interaction energies of the BPC-PECT pairs calculated from the phase boundary in accordance with the lattice-fluid theory were positive and also decreased with increasing CHDM content in PECT. It was shown that the phase homogenization of these blends occurs upon heating when the combinatorial entropy term, which is favorable for miscibility, overcomes unfavorable energetic terms at elevated temperatures. A novel product, which is not limited by the drawbacks of linear polycarbonate (PC) and evidences processability superior to that of the PC/PECT blends, can be developed via the blending of BPC and PECT.

Establishment of a Wind Map of the Korean Peninsula I. Evaluation of Offshore Wind Resources Using Remote-Sensing Data (한반도 바람지도 구축에 관한 연구 I. 원격탐사자료를 이용한 해상풍력자원 평가)

  • Kim Hyun-Goo;Lee H.W;Jung W.S
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.63-72
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    • 2005
  • In order to understand regional wind characteristics and to estimate offshore wind resources, a wind map of the Korean Peninsula was established using remote-sensing data from the satellite, U.S. NASA Quik SCAT which has been deployed for the Sea Winds Project since 1999. According to the linear regression result between the wind map data and in-situ marine-buoy data, the correlation factor was greatly improved up to 0.87 by blending the remote-sensing data of Quik SCAT with U.S. NCEP/NCAR CDAS reanalysis data to eliminate precipitation interference and to increase temporal resolution. It is found from the established wind map that the wind speed in winter is prominent temporally and the South Sea shows spatially high energy density over the wind class 6. The reason is deduced that the north-west winds through the Yellow Sea and the north-east winds through the East Sea derived by the low pressure developed in Japan are accelerated passing through the Korea Channel and formed high wind energy region in the South Sea; the same trends are confirmed from the statistical analysis of the meteorological observation data of KMA.

Characterization and experimental investigation for gamma-ray shielding competence of basalt-doped polyethylene nanocomposites

  • I.A. El-Mesady;F.I. El-Agawany;H. El-Samman;Y.S. Rammah;A. Hussein;R.A. Elsad
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.477-484
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    • 2024
  • Experimental investigations on gamma - rays attenuation parameters and dielectric spectroscopic properties were done on a polymeric mixture with chemical composition (100-x) polyethylene + x basalt, where x = 0, 1, 3, 5, 10, and 20 wt%. Using the melting blending technique,six nanocomposite polymeric samples were prepared. The linear attenuation coefficient µ of each prepared set of samples was measured using a gamma-ray spectrometer including High Purity Germanium detector (HPGe) at energies 662.5, 1173.24, and 1332.51 keV. Based on the measured values of (µ) and sample density, the other effective shielding parameters were calculated. The values of µ showed an increase with increasing the dopant ratios from 0.0 up to 20.0 wt%. In addition, the µ values decreased with the photon's energy. The µ values were found 0.0847 up to 0.1175 cm-1, 0.0571 up to 0.0855 cm-1, and 0.0543 up to 0.075 cm-1 at 662.5, 1173.24, and 1332.51 keV. for B0 up to B20, respectively. The ATR spectroscopy was done on the prepared samples, and a good evidence of adding the filler to the pure polyethylene (HDPE) was obtained. Besides, an enhancement in dielectric constant by insertion of basalt NPs also recorded and can be attributed to the large dielectric constant of basalt compared to pure HDPE.

Practical designs for mixture component-process experiments (실용적인 혼합물 성분 공정변수 실험설계)

  • Lim, Yong-B.
    • Journal of Korean Society for Quality Management
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    • v.39 no.3
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    • pp.400-411
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    • 2011
  • Process variables are factors in an experiment that are not mixture components but could affect the blending properties of the mixture ingredients. For example, the effectiveness of an etching solution which is measured as an etch rate is not only a function of the proportions of the three acids that are combined to form the mixture, but also depends on the temperature of the solution and the agitation rate. Efficient designs for the mixture components-process variables experiments depend on the mixture components-process variables model which is called a combined model. We often use the product model between the canonical polynomial model for the mixture and process variables model as a combined model. In this paper we propose three starting models for the mixture components-process variables experiments. One of the starting model we are considering is the model which includes product terms up to cubic order interactions between mixture effects and the linear & pure quadratic effect of the process variables from the product model. In this paper, we propose a method for finding robust designs and practical designs with respect to D-, G-, and I-optimality for the various starting combined models and then, we find practically efficient and robust designs for estimating the regression coefficients for those models. We find the prediction capability of those recommended designs in the case of three components and three process variables to be good by checking FDS(Fraction of Design Space) plots.

T-S Fuzzy Modeling for Container Cranes Using a RCGA Technique (RCGA 기법을 이용한 컨테이너 크레인의 T-S 퍼지 모델링)

  • Lee, Yun-Hyung;Yoo, Heui-Han;Jung, Byung-Gun;So, Myung-Ok;Jin, Gang-Gyoo;Oh, Sea-June
    • Journal of Navigation and Port Research
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    • v.31 no.8
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    • pp.697-703
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    • 2007
  • In this paper, we focuses on the development of Takagi-Sugeno (T-S) fuzzy modeling in a nonlinear container crane system. A T-S fuzzy model is characterized by fuzzy "if-then" rules which represent the locally input-output relationship whose consequence part is described by a state space equation as subsystem. The T-S fuzzy model in container cranes first obtains a few number of linear models according to operation conditions and blends these conditions using fuzzy membership functions. Parameters of the membership functions are adjusted by a RCGA to have same dynamic characteristics with nonlinear system of a container crane. Simulations are given to illustrate the performance of T-S fuzzy model.

Video Augmentation of Virtual Object by Uncalibrated 3D Reconstruction from Video Frames (비디오 영상에서의 비보정 3차원 좌표 복원을 통한 가상 객체의 비디오 합성)

  • Park Jong-Seung;Sung Mee-Young
    • Journal of Korea Multimedia Society
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    • v.9 no.4
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    • pp.421-433
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    • 2006
  • This paper proposes a method to insert virtual objects into a real video stream based on feature tracking and camera pose estimation from a set of single-camera video frames. To insert or modify 3D shapes to target video frames, the transformation from the 3D objects to the projection of the objects onto the video frames should be revealed. It is shown that, without a camera calibration process, the 3D reconstruction is possible using multiple images from a single camera under the fixed internal camera parameters. The proposed approach is based on the simplification of the camera matrix of intrinsic parameters and the use of projective geometry. The method is particularly useful for augmented reality applications to insert or modify models to a real video stream. The proposed method is based on a linear parameter estimation approach for the auto-calibration step and it enhances the stability and reduces the execution time. Several experimental results are presented on real-world video streams, demonstrating the usefulness of our method for the augmented reality applications.

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A Study on Processing and Physical Properties of Isoprene Rubber Involving Norbornene Dialkyl Ester (Norbornene Dialkyl Ester가 첨가된 Isoprene Rubber의 가공성 및 물성에 관한 연구)

  • Jeong, Hye-in;Jo, Nam-chol;Woo, Je-Wan
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.259-264
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    • 2016
  • In this study, we applied six different norbornene dialkyl esters as a plasticizer to an isoprene rubber (IR) and evaluated replaceability of DEHP which is an endocrine disruptor. IR test sheets were prepared by blending IR, norbornene dialkyl ester, vulcanizing agent, etc. and processing properties of the IR were evaluated by measuring Toque, scorch time, cure time and mooney viscosity. Mechanical properties of IR test sheet including hardness, tensile strength, 100% modulus and elongation were also measured and the physical properties of norbornene dialkyl ester applied as a plasticizer were compared to those using DEHN. Both the maximum and minimum toque for the norbornene dialkyl ester as a plasticizer were similar to those of using DEHP. In addition, the scorch and cure time of the former were slightly longer than those of the latter. The mooney viscosity for the case of DEHN was slightly lower than that of the latter. DEHN was also superior to DEHP in terms of processing. The hardness and thermal properties of all IR test sheets were measured to be similar to each other. The linear alkyl chain of norbornene compounds also exhibited good tensile characteristics.

Effects of Cereal Powders on Rheological Properties in Kochujang (곡류분말 처리가 고추장의 물성학적 특성에 미치는 영향)

  • An Yeong-Soon;Hong Yeong-Pyo;Kim Hyong-Yol;Lee Keun-Bo;Lee Mi-Sook
    • Food Science and Preservation
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    • v.12 no.2
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    • pp.151-155
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    • 2005
  • General problems on the quality in circulation process of Kochujang are fluidity, separated water at upper layer, and color change to dark-brown. Rice powders, glutinous rice powder and gelatinized rice powder, gelatinized glutinous rice powder were applied for solving such problems to Kochujang. Relationship between blending ratio of com syrup and fluidity had a linear correlation. Water separation in Kochujang was prevented by addition of gelatinized cereal powders, and gelatinized glufinous rice powder was most effective. Optimal amount of gelatinized glutinous rice powder was $0.5\~1.0\%$ (w/w).

Changes in soil physical properties of coir dust-mixed substrate as influenced by various filling amounts (용기내 충전량 변화에 따른 코이어 더스트 혼합상토의 물리성 변화)

  • Choi, Jong Myung;Lee, Hee Su
    • Korean Journal of Agricultural Science
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    • v.40 no.3
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    • pp.203-208
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    • 2013
  • Differences in the filling amount of substrates in container can influence severely on the soil physical properties and crop growth. This research was conducted to secure the fundamental informations related to the changes in soil physical properties as influenced by the filling amount of coir dust-based substrates in container. For the experiment, three substrates were formulated by blending coir dust (CD) with expanded rice hull (CD+ERH, 8:2, v/v), carbonized rice hull (CD+CRH, 6:4, v/v) or ground and aged pine bark (CD+GAPB, 8:2, v/v). Based on the optimum bulk density, the amount of substrates filled in 347.5mL aluminum cylinder were adjusted to 90, 100, 110, 120, and 130%. Then the changes in total porosity (TP), container capacity (CC), and air-filled porosity (AFP) by various filling amounts were measured. The TP decreased linearly in CD+ERH and CD+GAPB and quadratically in CD+CRH as the filling amounts of the media increased from 90% to 130%. The CC in CD+ERH and CD+GAPB media increased as the filling amount increased from 90% to 120%, then decreased in 130%, showing quadratic change. The CC in CD+CRH was the highest in 90% filling amount and decreased gradually as the filling amount of root medea increased. The AFPs in CD+ERH and CD+GAPB media were 38 and 37%, respectively in 90% filling amount and they decreased drastically until 110% filling, then gradually in 120 and 130% filling amount showing the quadratic changes. The AFP of CD+CRH at 90% filling amount was 22% and it decreased as the filling amount increased until 130%, showing linear change. These results indicate that the increase in filling amount of substrates influenced more severely the AFP than CC, and careful consideration on container filling is required to provide a better root condition thus maximize crop growth.

Comparing the Effect of Three Processing Methods for Modification of Filament Yarns with Inorganic Nanocomposite Filler and their Bioactivity against Staphylococcus aureus

  • Dastjerdi, Roya;Mojtahedi, M.R.M.;Shoshtari, A.M.
    • Macromolecular Research
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    • v.17 no.6
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    • pp.378-387
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    • 2009
  • This research compared three methods for producing and processing nanocomposite polypropylene filament yarns with permanent antimicrobial efficiency. The three methods used to mix antimicrobial agents based on silver nano particles with PP were as follows: 1) mixing of PP powder and inorganic nanocomposite filler with the appropriate concentration using a twin-screw extruder and preparing granules, 2) method 1 with a singlerather than twin-screw extruder, and 3) producing the masterbatch by a twin-screw extruder and blending it with PP in the melt spinning process. All pure polypropylene samples and other combined samples had an acceptable spinnability at the spinning temperature of $240^{\circ}C$ and take-up speed of 2,000 m/min. After producing as-spun filament yarns by a pilot plant, melt spinning machine, the samples were drawn, textured and finally weft knitted. The physical and structural properties (e.g., linear density, tenacity, breaking elongation, initial modulus, rupture work, shrinkage and crystallinity) of the as-spun and drawn yarns with constant and variable draw ratios (the variable draw ratio was used to gain a constant breaking elongation of 50%) were investigated and compared, while DSC, SEM and FTIR techniques were used to characterize the samples. Finally, the antibacterial efficiency of the knitted samples was evaluated. The experimental results revealed that the crystallinity reduction of the as-spun yarn obtained from method 1 (5%) was more than that of method 2 (3%), while the crystallinity of the modified as-spun yarns obtained with method 3 remained unchanged compared to pure yarn. However, the drawing procedure compensated for this difference. By applying methods 2 and 3, the drawing generally improved the tenacity and modulus of the modified fibers, whereas method 1 degraded the constant draw ratio. Although the biostatic efficiency of the nanocomposite yarns was excellent with all three methods, the modified fabrics obtained from methods 1 and 2 showed a higher bioactivity.