• Bulletin of the Korean Chemical Society
• /
• v.17 no.1
• /
• pp.2-4
• /
• 1996

• Bulletin of the Korean Chemical Society
• /
• v.31 no.8
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• pp.2195-2200
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• 2010

The reaction of $PdCl_2$ dispersed in tetra-n-butylammonium bromide with tributyl amine at $120^{\circ}C$ under argon leads to stable isolable nanometric particles. X-ray diffraction analysis of the material indicated that it is constituted of Pd(0). Transmission electron microscopy analysis of the particles dispersed in acetone shows the mean particle size distribution ($4{\pm}1\;nm$). The isolated palladium nanoparticles can be dispersed in an ionic liquid or in methanol or used in solventless condition for selective hydrogenation of 2-hexyne under mild reaction conditions(0.2 MPa and $20^{\circ}C$). The commercial variety of the Lindlar catalyst was also studied for comparative investigations.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.9
• /
• pp.2853-2854
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• 2012

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1247-1249
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• 2013