• Title/Summary/Keyword: Limited of stability

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Progress in Composite Polymer Membrane for Application as Separator in Lithium Ion Battery (리튬 이온 전지의 분리막으로 사용하기 위한 복합 고분자 막의 동향)

  • Oh, Seok Hyeon;Patel, Rajkumar
    • Membrane Journal
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    • v.30 no.4
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    • pp.228-241
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    • 2020
  • Separators, which produces physical layer between a cathode and anode, are getting enormous attention as the quality of the separator determines the performance of lithium ion batteries (LIBs). Porous membranes based on polyethylene (PE) and polypropylene (PP) are generally utilized as the separator of LIBs because of their high electrochemical stability and suitable mechanical strength. However, low thermal resistance and wettability of PE and PP membranes limited the potential of LIBs. Operating at the temperature exceeding the melting point of membranes, the separators change their structures which lead to short circuit of LIBs. Low wettability of the separators corresponds to low ionic conductivity which increases the cell resistance. To overcome these weaknesses of PE and PP separators, different types of separator were prepared by co-electrospinning, applying coating layer, forming core shell around membrane, and papermaking method. The synthesized separator greatly enhanced the heat resistance and wettability of separator and mechanical properties like flexibility and tensile strength. In this review different type of polymer membrane used as separator in lithium ion battery are discussed.

Photoelectrochemical Properties of Gallium Nitride (GaN) Photoelectrode Using Cobalt-phosphate (Co-pi) as Oxygen Evolution Catalyst (산소발생용 Cobalt-phosphate (Co-pi) 촉매를 이용한 Gallium Nitride (GaN) 광전극의 광전기화학적 특성)

  • Seong, Chaewon;Bae, Hyojung;Burungale, Vishal Vilas;Ha, Jun-Seok
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.2
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    • pp.33-38
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    • 2020
  • In the photoelectrochemical (PEC) water splitting, GaN is one of the most promising photoanode materials due to high stability in electrolytes and adjustable energy band position. However, the application of GaN is limited because of low efficiency. To improve solar to hydrogen conversion efficiency, we introduce a Cobalt Phosphate (Co-pi) catalyst by photo-electrodeposition. The Co-pi deposition GaN were characterized by SEM, EDS, and XPS, respectively, which illustrated that Co-pi was successfully decorated on the surface of GaN. PEC measurement showed that photocurrent density of GaN was 0.5 mA/㎠ and that of Co-pi deposited GaN was 0.75 mA/㎠. Impedance and Mott-Schottky measurements were performed, and as a result of the measurement, polarization resistance (Rp) and increased donor concentration (ND) values decreased from 50.35 Ω to 34.16 Ω were confirmed. As a result of analyzing the surface components before and after the water decomposition, it was confirmed that the Co-pi catalyst is stable because Co-pi remains even after the water decomposition. Through this, it was confirmed that Co-pi is effective as a catalyst for improving GaN efficiency, and when applied as a catalyst to other photoelectrodes, it is considered that the efficiency of the PEC system can be improved.

The Effect of Composite Ratio and Wall Thickness on the Shear Behavior of Composite Basement Wall (합성율과 벽체두께가 합성지하벽의 전단거동에 미치는 영향)

  • Seo, Soo-Yeon;Kim, Seong-Soo;Yoon, Yong-Dae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.1
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    • pp.93-101
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    • 2010
  • When doing underground excavation works for the purpose of constructing large underground structures for a building in the limited space in downtown area, the stability of the adjacent ground must be top priority, and to accomplish this, it is essential to review the retaining wall construction carefully. H-Pile, which has been mainly used as a stress-carrying material in temporary earth-retaining structures, is most likely to be abandoned after completion of the works for the basement exterior wall in relation to contiguous bored piles, so it will result in a waste of material. To improve this situation, Basement Composite Wall where H-Pile and basement wall are compounded, has been developed. This wall is being used most frequently in many local construction sites. In this study, five specimens are made in order to evaluate the shear resistance of the basement composite wall and tested. Test parameter is the composition ratio and wall thickness according to shear connectors. Test result shows that the shear strength is improved when the composite ratio is increased but the magnitude is not much. A formula, which considers the contribution of concrete, web of H-pile as well as flange' effect in calculation of shear strength of composite basement wall, is suggested and used to calculation of the strength of specimens. It is found that there is a good co-relation between test result and the calculated one by the formula.

High-efficiency deep geological repository system for spent nuclear fuel in Korea with optimized decay heat in a disposal canister and increased thermal limit of bentonite

  • Jongyoul Lee;Kwangil Kim;Inyoung Kim;Heejae Ju;Jongtae Jeong;Changsoo Lee;Jung-Woo Kim;Dongkeun Cho
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1540-1554
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    • 2023
  • To use nuclear energy sustainably, spent nuclear fuel, classified as high-level radioactive waste and inevitably discharged after electricity generation by nuclear power plants, must be managed safely and isolated from the human environment. In Korea, the land area is limited and the amount of high-level radioactive waste, including spent nuclear fuels to be disposed, is relatively large. Thus, it is particularly necessary to maximize disposal efficiency. In this study, a high-efficiency deep geological repository concept was developed to enhance disposal efficiency. To this end, design strategies and requirements for a high-efficiency deep geological repository system were established, and engineered barrier modules with a disposal canister for pressurized water reactor (PWR)-type and pressurized heavy water reactor type Canada deuterium uranium (CANDU) plants were developed. Thermal and structural stability assessments were conducted for the repository system; it was confirmed that the system was suitable for the established strategies and requirements. In addition, the results of the nuclear safety assessment showed that the radiological safety of the new system met the Korean safety standards for disposal of high-level radioactive waste in terms of radiological dose. To evaluate disposal efficiency in terms of the disposal area, the layout of the developed disposal areas was assessed in terms of thermal limits. The estimated disposal areas were 2.51 km2 and 1.82 km2 (existing repository system: 4.57 km2) and the excavated host rock volumes were 2.7 Mm3 and 2.0 Mm3 (existing repository system: 4.5 Mm3) for thermal limits of 100 ℃ and 130 ℃, respectively. These results indicated that the area and the excavated volume of the new repository system were reduced by 40-60% compared to the existing repository system. In addition, methods to further improve the efficiency were derived for the disposal area for deep geological disposal of spent nuclear fuel. The results of this study are expected to be useful in establishing a national high-level radioactive waste management policy, and for the design of a commercial deep geological repository system for spent nuclear fuels.

Development of Multi-rotational Prosthetic Foot for Lower Limb Amputee (하지 절단자를 위한 다축 회전이 가능한 인공발의 개발)

  • Shin, Hyunjun;Park, Jin-Kuk;Cho, Hyeon-Seok;Ryu, Jei-Cheong;Kim, Shin-Ki
    • Journal of rehabilitation welfare engineering & assistive technology
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    • v.10 no.4
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    • pp.305-313
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    • 2016
  • Movements of the lower limb are important for normal walking and smooth oscillation of the center of gravity. The ankle rotations such as dorsi-flexion, plantar-flexion, inversion and eversion allows the foot to accommodate to ground during level ground walking. Current below knee (B/K) prostheses are used for replacing amputated ankle, and make it possible for amputees to walk again. However, most of amputees with B/K prostheses often experience a loss of terrain adaptability as well as stability because of limited ankle rotation. This study is focused on the development of multi-rotational prosthetic foot for lower limb amputee. Our prosthesis is possible for amputees to easily walk in level ground by rotating ankle joint in sagittal plane and adapt to the abnormal terrain with ankle rotation in coronal plane. The resistance of ankle joint in the direction of dorsi/plantar-flexion can be manually regulated by hydraulic damper with controllable nozzle. Furthermore, double layered rubber induce the prosthesis adapt to irregular ground by tilting itself in direction of eversion and inversion. The experimental results highlights the potential that our prosthesis induce a normal gait for below knee amputee.

A Study on the Development Strategy of Offshore Oil Resource in China (중국의 해외 석유자원 개발 전략에 관한 연구)

  • Lee, Choong-Bae;Noh, Jin-Ho
    • International Commerce and Information Review
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    • v.13 no.3
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    • pp.119-142
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    • 2011
  • Competitions for secure oil are intense around the world due to the limited oil reserves. The situations are becoming more serious as China has participated in the competition. This paper aims to investigate China's offshore oil development strategies to balance the supply and demand of oil and then suggest its policy implications. A surging increase of oil demand due to the rapid economic growth as well as the stagnation in domestic oil output has turned China into a net oil importer since 1993. Therefore, China has placed a significant priority on securing long-term stability of its offshore oil to cope with the rapid growing demand. It has taken a variety of strategies to secure stable oil resource such as development of offshore oil resource, increasing the number of oil importing countries. China with the highest foreign exchange reserve of approximately $3 trillion as of 2010, has considered to employ foreign exchange reserves while making a huge amount of investment to secure oil resource. China has pursued several policies such as loan to oil production country for securing oil, foreign direct investment on offshore oil development, M&A of oil exploration and production companies and geographical diversification of oil importing countries. China has promoted offensive strategies for securing oil resource rather than cooperation with other countries. Thus, China should find a trade-off point for recovering relationship with international society while developing and investing renewable energy for long-term future. It will also address some implications for Korea, which has to prepare new strategies of overseas oil development.

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An Empirical Study on the Effect of public Construction Industry by Expansion of New Budget System (계속비 사업 확대로 인한 공공건설사업 파급효과 분석)

  • Kim, Sang-Bum;Lee, Jeong-Dae;Cho, Ji-Hoon
    • Korean Journal of Construction Engineering and Management
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    • v.9 no.3
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    • pp.153-163
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    • 2008
  • Domestic construction industry accounts about 15% of Gross Domestic Product(GDP) and Korean government spends approximately 50 trillion won per year for public infrastructure projects. Effective management of public construction projects would result in cost saving and enhance financial stability of the government. In doing so, the government promoted a new budgeting system, Continual Budget Method(CBM) as a part of public project performance enhancement program published in 1999. This research mainly attempted to investigate and analyze the impact of new budgeting in term of cost and schedule performance. Based on the analysis result of n2 projects. The new budgeting system could save project cost by 9.83y. Due to the saving of indirect costs from reduction. Although limited government budget cannot allow all the projects to be excuted with the new budgeting system, the new budgeting system should be more-widely utilized in the public sector because of its proven benefits from this research.

The First Year of the Moon Jae-In Government: An Assessment (문재인 정부 1년의 평가와 전망)

  • Kang, Won-Taek
    • Korean Journal of Legislative Studies
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    • v.24 no.1
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    • pp.5-29
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    • 2018
  • This paper aims at making an assessment about the first year of the Moon Jae-in government. President Moon was elected amid political insecurity over the impeachment of then-president Park Geun-hye. However, the Moon administration settled in fairly smoothly despite no transition period of presidential power. Political and economic stability was soon restored, and the tensions between the US and North Korea over the North's nuclear weapons program were, to some extent, managed along with the agreement of the North-South summit and the US-North Korea summit. Pyeongchang hosted the 2018 winter olympics and paralympics successfully. Moon continued very positive approval ratings of higher than 70%. However, he has something to be desired. His leadership seems to rely heavily on a limited number of close staff in the Blue House, alienating the governing the Minjoo Party of Korea. He should build better relationship with opposition parties particularly given a divided government. Rectification of the lingering negative practices should also produce institutional solutions. Above all, Moon should carefully watch out to prevent scandals over corruption and power abuse around him and his family, which would lead to a precipitous decline of the approval ratings and the abrupt weakening of the leadership.

A Study on Quality Improvement and Verification of Recycled Coarse Aggregate for Concrete Using an Impact Crusher with Radial Rotation (방사형 회전이 추가된 임팩트 크러셔를 이용한 콘크리트용 순환굵은골재 품질향상 및 검증 연구)

  • Jeon, Duk-Woo;Kim, Yong-Seong;Jeon, Chan-Soo;Choi, Won-Young;Cho, Won-Ig
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.133-142
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    • 2022
  • The purpose of this study is to develop an impact crusher with a radial rotating plate installed at the bottom, which is a shock absorber that can produce high-quality recycled coarse aggregate for concrete and to verify the effect of improving the quality performance of recycled coarse aggregate and its applicability through concrete tests. As a result, it showed improved quality in all items such as absolute dry density, absorption rate, abrasion resistance, Particle shape judgment rate, amount lost in the 0.08 mm sieve passing test, alkali aggregate reaction, clay mass, stability, and impurity content, and it was found to meet the criteria of recycled aggregate quality standards. In addition, the air volume and slump of concrete to which recycled coarse aggregate is applied meet all domestic standards. According to the test results of the compressive strength characteristics by age of concrete according to the mixing ratio of the recycled coarse aggregate, it was confirmed that the mixing ratio of the recycled coarse aggregate was applicable up to 60 %.

Study on evaluation of bond strength of cone-shaped button cablebolt (콘형 케이블볼트의 인발강도 평가 연구)

  • Choi, Jung-In;Kim, Won-Keun;Lee, Dong-Seok;Lee, Seok-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.12 no.1
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    • pp.61-73
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    • 2010
  • The cablebolt which secures a workability and stability has been used in foreign countries as one of supporting materials with rebar rockbolt especially in construction of large underground structures. However, only the rebar rockbolt has been applied up to now to all the constructions of underground structures in Korea due to an absence of recognition of cablebolt and large underground structure projects. Consequently, the research for a performance evaluation and verification of cablebolt is very limited and only the proto-type field tests have been conducted. In this study, the cone-shaped button cablebolt is developed by modifying an existing button cablebolt. To evaluate a performance and applicability of cone-shaped button cablebolt, the laboratory pull tests are conducted and bond capacity is analyzed under a various conditions. The rebar rockbolt, plane cablebolt, and bulb cablebolt which has a similar mechanical behavior with cone-shaped button cablebolt, are also tested and their bond capacities are evaluated and compared with cone-shaped button cablebolt under the same condition. The results show that the bond capacity is in the order of (cone-shaped button cablebolt$\approx$bulb cablebolt) > rockbolt > plane cablebolt. It is found that the bond capacity of cone-shaped button cablebolt developed in this study is at least equivalent with an existing high performance cablebolt developed in foreign countries, therefore the cone-shaped button cablebolt could be used as one of supporting materials for underground structures in construction field.