• Title/Summary/Keyword: Limestone formation

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The Yemi Breccia : Origin and Stratigraphic Implications (예미각력암 : 성인과 층서적 의미)

  • Woo Kyung Sik
    • The Korean Journal of Petroleum Geology
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    • v.5 no.1_2 s.6
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    • pp.16-26
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    • 1997
  • The Yemi Breccia has been reported as a separate formation near Yemi area, Kangwondo. This formation overlies the Maggot Formation of the Joseon Supergroup unconformably, and is overlain by the Goseong Shale conformably. Based on the field observation and textural examination of the Yemi Breccia, the breccia beds are interpreted as soluton-collapse breccia beds, which were formed by the dissolution of the pre-existing evaporites. The evaporites were precipitated during the deposition of the upper part of the Maggot Formation. Therefore, the Yemi Breccia should not be regarded as a separate formation, instead, it should be considered to be a upper part of the Maggot Formation. This implies that the overlying Goseong Shale and Goseong Limestone can be correlated with the Jigunsan and Duwibong Formtions, respectively.

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Geology and Ore deposits of Songgwang Mine (송광광산(松廣鑛山)의 지질광상(地質鑛床))

  • Hong, Man Seup
    • Economic and Environmental Geology
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    • v.2 no.3
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    • pp.58-67
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    • 1969
  • Songgwang lead zinc mine is located in about 12km to the north-east of Jeonju City. Geology of the mine and its visinity is consisted of Jeonju series belonged to so-called Okcheon system, Seodaesan tuff formation, Silla series, and the quartz porphyry intruded into these formations. Jeonju series comprising 3 formations; that is, of Sadaeri, Sindong, and Girinbong. Jeonju series is generally distributed in southern part of the area, striking NNW, and diping NE $30^{\circ}$, or NW $30^{\circ}$. It is deformed to form synclinorium and anticlinorium plunging to the north with low angle. In the northern part of the area, Jeonju series was cut by Sinpeongri-fault of NEE direction near Sinpeongri. In the north side of the fault, it is overturned and shows NEE or NWW strikes and NW $60^{\circ}$ dips. At the west of Songgwangri, it is cut by 3 thrusts; the two are almost parallel each other, and the third oneis manifested by the fact that the lower black shale zone thrusted over the upper limestone. Songgwangri thrust, so named, is a post-mineral fault and its plane represents a premineral slip plane. Enrichment of are took place along the bedding plane or fissure parallel to it, as seen in adit No. 1 or No. 2 along the floor of the thrust, and along the sheared zone or the brecciated zone oblique to the plane near the thrust in crystalline limestone of Sindong formation as observed in the underground levels of inclined slope. Ore minerals are chiefly zincblende, galena, pyrrhotite, arsenopyrite, acompanied pyrite and chalcopyrite, and contain Au and Ag. In earlier stage of mineralization, the limestone was recrystalized, and sulphide minerals were enriched in the· permiable zone said above by pyrometasomatism, and in later stage the limestone was affected chloritization and sericitization. However hydrothermal replacement was weak, so that enrichment did not took place. It seems that minerallizing materials came up through the premineral slip plane and injected, and replaced the limestone in permiable zone said above with sulphide are minerals. Then Songgwangri thrust took place and, the lower black shale zone thrusted upon crystalline limestone.

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Effect of Limestone Powder on Hydration of C3A-CaSO4·2H2O System (C3A-CaSO4·2H2O 계의 수화반응에 미치는 석회석 미분말의 영향)

  • Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.584-588
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    • 2011
  • In this work, effects of limestone powder on hydration of $C_3A-CaSO_4{\cdot}2H_2O$ system was discussed based on the XRD Quantitative analysis, and the possibility of Delayed Ettringite Formation was also discussed. The early hydration of $C_3A$ was delayed by addition of $CaCO_3$ powder. The delay effect was enhanced by increasing of $CaCO_3$ content and finer powder of $CaCO_3$ addition. After consumption of $CaSO_4{\cdot}2H_2O$, the reaction of $CaCO_3$ is started. Delayed Ettringite Formation would take place because monosulfoaluminate is not stable in presence of $CaCO_3$. In order to prevent the delayed ettringite formation in $C_3A-CaSO_4{\cdot}2H_2O-CaCO_3$ system, the reduction of monosulfoaluminate formation is important. Therefore, by increasing the amount of $CaCO_3$ addition and finer $CaCO_3$ powder addition, the delayed ettringite formation can be prevented.

Verification of Genetic Process for the High-purity Limestone in Daegi Formation by Oxygen-carbon Stable Isotope Characteristics (산소-탄소 안정동위원소특성을 이용한 대기층 고품위 석회석의 생성기작 해석)

  • Kim, Chang Seong;Choi, Seon-Gyu;Kim, Gyu-Bo;Kang, Jeonggeuk;Kim, Sang-Tae;Lee, Jonghyun;Jang, Jaeho
    • Economic and Environmental Geology
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    • v.52 no.1
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    • pp.107-118
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    • 2019
  • Two assertions about the process the formation of the high-purity limestone in the Taebaeksan Basin, categorized into syngenetic and epigenetic origin, are verified on the basis of its oxygen-carbon stable isotopic characteristics. The carbonate rocks sampled from the selective six high-purity limestone mines and several outcrops in the Daegi formation are featured by various colors such as the gray, light gray and dark gray. They show a wide range of oxygen stable isotope ratios (4.5 ~ 21.6 ‰), but a narrow range of carbon stable isotope ratios (-1.1 ~ 0.8 ‰, except for vein calcite), which means that they had not experienced strong hydrothermal alteration. In addition, there is no difference in the range of the oxygen stable isotope ratios by mine and color, and it is similar to the range from surrounding outcrop samples. These results indicate that the effect of the hydrothermal alteration were negligible in the generation of high-purity limestone in deposit scale. Whereas, the carbonate rocks can be divided texturally into two groups on the basis of an oxygen isotope ratio; the massive-textured or well-layered samples (>15 ‰), and the layer-disturbed (or layer-destructed) and showing over two colors in one sample (<15 ‰). In the multi-colored samples, the bright parts are characterized by the very low oxygen stable isotope ratios, compared to the dark parts, implying the increase in brightness of the carbonate rocks could be induced by the interaction between hydrothermal fluid and rock. However, these can be applied in a small scale such as one sample and are not suitable for interpretation of the generation of high-purity limestone as a deposit scale. In particular, the high oxygen isotope ratios from the recrystallized white limestone suggest that hydrothermal fluids are also rarely involved during recrystallization process. In addition, the occurrences of the high-purity limestone orebody strongly support the high-purity limestone in the area are syngenetic rather than epigenetic; the high-purity limestone layers in the area show continuous and almost horizontal shapes, and is intercalated between dolomite layers. Consequently, the overall reinterpretation based on the sequential stratigraphy over the Taebaeksan basin would play an important role to find additional reserves of the high-purity limestone.

Manufacture of Precipitated Calcium Carbonate from Pungchon Limestone (풍촌지역 석회석을 이용한 침강성탄산칼슘의 제조)

  • Lee, Jae-Jang;Park, Jong-Lyuck
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.251-256
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    • 2001
  • This research is focused on an improvement of additional value of high grade limestone. To obtain the basic data of precipitated calcium carbonate(PCC), studies of physical properties of limestone, calcination and hydration characteristics, the characteristics to manufacture quick lime, hydrated lime, ground calcium carbonate and precipitated calcium carbonate were performed. In the carbonation process, formation of rombohedral must be kept under $10^{\circ}C$ for reaction. Although the temperature of reaction of lime milk was limited under $30^{\circ}C$ for a colloidal PCC manufacture, over $50^{\circ}C$ for spindle type PCC. The recommended reaction conditions for colloidal PCC are $20^{\circ}C$ of reaction temperature, 4% of $Ca(OH)_2$ concentration, 1000rpm of stirring rate and 200ml/min of $CO_2$ gas flow rate.

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On the Genesis of Skarn-type Scheelite Deposits at the Dongmyoung mine (동명광산(東明鑛山)의 스카른형(型) 회중석(灰重石) 광상(鑛床)의 성인(成因))

  • Oh, Mihn-Soo;Park, Ki-Hwa
    • Economic and Environmental Geology
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    • v.16 no.1
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    • pp.37-49
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    • 1983
  • The skarn type tungsten deposits are developed in the contact aureole of Jurassic biotite-hornblende granodiorite and limestone beds. The latter can be divided into the Great Limestone Series of Joseon System and Gabsan Formation which is correlative to the Hongjeom Series of Pyeongahn System. The skarns are impregnated in the limestone, sandstone, schist and granodiorite, and showing zonal distribution. The five skarn zones are from fresh limestone inwards to wollastonite-skarn, clinopyroxene-skarn, clinopyroxene-garnet skarn, garnet skarn and vesuvianite skarn zone. The ore mineral, scheelite, disseminates in the clinopyroxene-garnet and vesuvianite skarn zone, and the size of the scheelite crystals in vesuvianite skarn zone is larger than in clinopyroxene- garnet skarn zone. According to the mineral paragenesis and the composition of skarn minerals, oxygen fugacity ($fo_2$) is low. Fluid inclusions in quartz comprise much $LCO_2$ and fluid inclusion studies revealed that the homogenization temperatures range $240-290^{\circ}C$.

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A Discussion on the Stratigraphy of the so-called Great Limestone Series (소위(所謂) 대석회암통(大石灰岩統)의 층서(層序)에 관(關)한 고찰(考察))

  • Son, Chi Moo
    • Economic and Environmental Geology
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    • v.6 no.4
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    • pp.219-230
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    • 1973
  • This paper reviews Professor O.J. Kim's work on "The stratigraphy and geologic structure of the Great Limestone Series in South Korea". Although he stated in his paper such as "very few geologists in Korea argue without confident evidences against the age and stratigraphy of the Great Limestone Series which have been rather well established previously in most parts of the regions", he disregarded the Jeongseon type of the Joseon (Chosen) System and modified the Yeongweol and the Pyeongchang types. According to his description, the Jeongseon type is not a different type and it is only due to structural repetition of the Hwajeol and Dumudong Formations of the Duwibong type and its Maggol Limestone. Also, he devided the Sambangsan Formation of the Yeongweol type into the east and west parts along the so-called Jeolgaesan fault, and they are correlated to the Hongjeom Series and Sesong Slate (Seison Slate) of Kobayashi, respectively. Furthermore he established newly Yeongweol type which includes the original Kobayashi's Yeongweol type and the Upper Limestone of the Pyeongchang type. Also, he pointed out that his newly established Yeongweol type is quite correlatable to the Duwibong type. The writer's opinion can be concluded that the Jeongseon type is not simply of structural repetition and structurely the Sambangsan Formation can not be devided into two parts. Also structurely there is no evidence of its correlation to the Sesong Slate as well as his conodont study in his Yeongweol type shows no indication of the correlation. The writer thinks that as to the stratigraphy of the Yeongweol and Jeongseon types of the Joseon System, it should be agreed with the Kobayashi's opinion or should be followed the idea of the very few geologists, he mentioned.

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Consideration of Cement Mineral Production Amount and Microstructure Chemical Distribution of Cement Clinker Using Coal Ash and Coarse Limestone (석탄재와 조립 석회석을 적용한 시멘트 클링커의 시멘트 광물생성량과 미세구조의 화학성분 분포 고찰)

  • Dong-Woo Yoo;Sung-Ku Kwon;Min-Seok Oh;Seok-Je Lee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.364-372
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    • 2023
  • By applying coarse-grained limestone and unprocessed coal ash as sintering raw materials for cement clinker, the microstructure and distribution of chemical components of cement clinker were compared and examined. Samples using coarse limestone as a raw material for cement clinker showed a decrease in sinterability compared to samples using reagent-grade raw materials. Samples using coal ash showed a tendency for some increase in sinterability. In samples using coarse limestone and coal ash, the formation of Belite was high at 1350 ℃. The conversion rate from Belite to Alite was high in the range of 1350~1450 ℃. Samples using coal ash showed stable formation of interstitial phase in the range of 1350 to 1450 ℃. The microstructure and chemical composition distribution of cement clinker sintered at 1350~1450 ℃ showed that all samples showed a form and composition distribution in which the calcium silicate phase and interstitial phase were clearly distinguished.

Effect of Limestone Powder on Hydration of $C_{3}A-CaSO_{4}$ $\cdot$ $2H_{2}O$ system ($C_3A-CaSO_4\cdot2H_2O$ 계의 수화반응에 미치는 석회석미분말의 영향)

  • Lee Jong-Kyu;Chu Yong-Sik
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.349-352
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    • 2005
  • In this work, effects of limestone powder on hydration of $C_3A-CaSO_4\cdot2H_2O$ system was discussed based on the XRD Quantitative analysis, and the possibility of Delayed Ettringite Formation was also discussed. The early hydration of $C_{3}A$ was delayed by addition of $CaCO_{3}$ powder. The delay effect was enhanced by increasing of $CaCO_{3}$ content and finer powder of $CaCO_{3}$ addition. After consumption of $CaSO_4\cdot2H_2O$, the reaction of $CaCO_{3}$ is started. Delayed Ettringite Formation would take place because monosulfoaluminate is not stable in presence of $CaCO_{3}$. In order to prevent the delayed ettringite formation in $C_3A-CaSO_4\cdot2H_2O-CaCo_3$ system, the reduction of monosulfoaluminate formation is important. Therefore, by increasing the amount of $CaCO_{3}$ addition and finer $CaCO_{3}$ powder addition, the delayed ettringite formation can be prevented.

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