• Title/Summary/Keyword: Lime treatment

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Treatment of Livestock Wastewater with Coagulant-loess (황토를 이용한 축산폐수의 처리에 관한 연구)

  • Park, Jin-Hee;Kim, Bo-Guk;Won, Chan-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1799-1808
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    • 2000
  • To investigate the applicability of loess as a coagulant. the optimum conditions of coagulation and efficiency comparison of several coagulants (PAC, PACS, LAS) in chemical treatment of livestock wastewater were performed. As a result, the optimum mixing ratio of loess and lime(CaO) was 3:7. The optimum dosage of the mixed coagulant was 30 g/L. The optimum speed for rapid mixing of the mixed coagulant was 200 rpm at 1 min. and the optimum speed for slow mixing was 50 rpm at 10 min. The mixed coagulant showed the removal efficiency of turbidity, SS, BOD, $COD_{cr}$. T-P and TKN to 95.8%, 92.5%, 71.6%, 71.1%, 98.2% and 32.5%, respectively, which was better than other several coagulants. The mixed coagulant was possible to use as substitutional coagulants of traditional coagulant, and the producted sludge can use as a soil amendments.

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Elution characteristics of lime-based granular alkaline material and applicability of phosphorus crystallization processes (석회계 입상알칼리재의 용출특성과 이를 이용한 인 결정화공정의 적용성)

  • Chang, Hyang-Youn;Park, Na-Ri;Jang, Yeo-Ju;Ahn, Kwang-Ho;Lim, Hyun-Man;Kim, Weon-Jae
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.6
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    • pp.577-586
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    • 2017
  • One of the major sources causing eutrophication and algal blooms of lakes or streams is phosphorus which comes from point and nonpoint pollution sources. HAP (hydroxyapatite) crystallization using granular alkaline materials can achieve the decrease of phosphorus load from wastewater treatment plants and nonpoint pollution control facilities. In order to induce HAP crystal formation, continuous supply of calcium and hydroxyl ions is required. In this research, considering HAP crystallization, several types of lime-based granular alkaline materials were prepared, and the elution characteristics of calcium and hydroxyl ions of each were analyzed. Also, column tests were performed to verify phosphorus removal efficiencies of granular alkaline materials. Material_1 (gypsum+cement mixed material) achieved the highest pH values in the column tests consistently, also, Material_2 (gypsum+slag mixed material) and Material_3 (calcined limestone material) achieved over pH 9.0 for 240 hours (10 days) and proved the efficiencies of long-term ion supplier for HAP crystallization. In the column tests using Material_3, considerable pH increase and phosphorus removal were carried out according to each linear velocity and filtration depth. T-P removal efficiencies were 87.0, 84.0, 68.0% and those of PO4-P 100.0, 97.0, 80.0% for linear velocity of 1.0, 2.5, 5.0 m/hr respectively. Based on the column test results, the applicability of phosphorus removal processes for small-scale wastewater treatment plants and nonpoint pollution control facilities was found out.

Chemical Forms and Release Potential of Heavy Metals from the Lime Treated Sediments (석회 처리에 의한 오염 퇴적물 내 중금속의 형태 변화 및 용출 가능성)

  • Park, Gil-Ok;Jun, Sang-Ho
    • Korean Journal of Ecology and Environment
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    • v.41 no.2
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    • pp.166-173
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    • 2008
  • Chemical forms and release potential of heavy metals were studied in the lime treated sediment of lake Chungcho. Chemical forms of heavy metals were analyzed using a sequential extraction method, and release potential of heavy metals was evaluated by the ratio of the content of labile forms to total metal one. Dominant form of Cd, Cu, Pb, and Zn in the untreated sediments was organic/sulfidic form that is stable in the reducing environment such as the bottom of Lake Chungcho. With liming of the sediment, the chemical forms of studied metals were greatly changed from organic/sulfidic form to adsorbed and reducible form, especially Cd and Cu to adsorbed and reducible form, but Pb and Zn to reducible form. It is believed that increase of unstable form of heavy metals in the sediments by liming was caused by the increase of pH of the pore water at the expense of organic/sulfidic form. Thus, we concluded that the liming approach currently used in the treatment of dredged sediments might cause the increase of labile form which is easily dissolved, and may increase the release of metals from the sediment into overlying water.

Applications of Organic Fungicides Reduce Photosynthesis and Fruit Quality of Apple Trees

  • Bhusal, Narayan;Kwon, Jun Hyung;Han, Su-Gon;Yoon, Tae-Myung
    • Horticultural Science & Technology
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    • v.34 no.5
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    • pp.708-718
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    • 2016
  • Two different pest control programs were applied on 8-year-old 'Ryoka'/M.26 apple trees (Malus domestica Borkh.). Lime sulfur or Bordeaux mixture with emulsified oil were applied 12 times from late March to mid-September as organic treatment, and synthetic chemicals were 7 times applied as control treatment. Over the entire apple-growing season, photosynthesis rates of apple trees were significantly lower in the organic treatment than in the control, and this photosynthetic differences were larger in July and August. Photosynthesis-related parameters such as stomatal conductance and transpiration behaved similarly to photosynthesis. The leaf area in the organic treatment was significantly smaller ($24.7cm^2$) than that in the control treatment ($30.7cm^2$). Organic leaves contained significantly less Chl. a ($15.5mg{\cdot}g^{-1}$) than did control leaves ($17.6mg{\cdot}g^{-1}$). Fruit yield per tree was significantly lower in the organic treatment (18.8 kg) than in the control (24.5 kg), because organic fruits experienced a higher rate of disease infection such as white rot (Botryosphaeria dothidae) and bitter rot (Glomerella cingulata) than did control fruits. Organic fruits had high flesh firmness but less color development (lower Hunter's a values). In this experiment, the pest control program with frequent applications of organic fungicides showed negative effects on photosynthesis and disease infection on leaves and fruits, and thus reduce the fruit quality and yield in 'Ryoka'/M.26 apple trees.

Application of Practical Immobilizing Agents for Declining Heavy Metal (loid)s Accumulation by Agricultural Crop (Allium wakegi Araki)

  • Seo, Byoung-Hwan;Kim, Hyun-Uk;Lwin, Chaw Su;Kim, Hyuck Soo;Kim, Kwon-Rae
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.4
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    • pp.226-234
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    • 2017
  • In order to reduce the accumulation of toxic metals (As, Cd and Pb) in the chives, various immobilizing agents such as a soil pH change-inducing immobilizing agent (lime), sorption agent (compost, spent mushroom compost), soil pH change and sorption agent (biochar) and, dissolved organic carbon (DOC) coagulator (gypsum) and uncontaminated soil were applied to the contaminated soils in isolation and in combination. Then chives were grown and determined for As, Cd and Pb concentrations accumulated in the edible part at harvest. The Cd and Pb concentrations of the chive plant grown in the contaminated soil (no treatment) exceeded the legislated Korean guideline values (Cd: $0.05mg\;kg^{-1}$, Pb $0.1mg\;kg^{-1}$) and As concentration ($21mg\;kg^{-1}$) was 1,000 times higher than chives plant grown in uncontaminated environment in Korea. Application of lime and gypsum significantly reduced As, Cd and Pb concentrations in all chives examined, due to the increased soil pH and decreased soil DOC. Also, application of combination treatments involving DOC coagulator such as gypsum together with lime decreased As, Cd and Pb concentrations from 21, 1.3 and $9.7mg\;kg^{-1}$ to 2.1, 0.1 and $1.1mg\;kg^{-1}$, respectively. Consequently, it was concluded that pH change-inducing immobilizing agent (lime) which was already well known and DOC coagulator such as gypsum could be used as a promising immobilizing agent for safer chives plant production.

Effect of Different Fertilizers on Growth and Fiber Yield in Ramie Plant (모시풀의 생육과 섬유수량에 미치는 비료의 영향)

  • 김상곤;정동희;권병선;임준택
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.3
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    • pp.235-239
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    • 1993
  • To determine the optimal application level of fertilizers, nitrogen, phosphate, potassium and lime in ramie(Beohmeria nivia Hooker et Arnot), the experiments were conducted for four years from seedling stage propagated by suckers to fully-grown stage under various comibinations of $N, P_2O_5, O$ and lime. Increasing in application rate of N and $K_2$O enhanced stem growth of ramie greatly, and it appeared that lime application also had large effect on increase of stem growth. Yield increased greatly by increasing of application rate with two or three times in N and two times in $K_2$O as much as the standard application rate of fertilizers N-$P_2O_5$-$K_2$O =9-3-9kg/l0a. Especially, treatment with 18kg N, 3kg $P_2O_5, $, 18kg $K_2$O and 200kg lime per l0a showed higher percentage of productive culm and increased yield of crude fiber about 33%. The variation among treatments was relatively small in stem length but larger in fresh weight of shoot and stem. The variation was large at early stage of experiment, that is, from one to two years after planting, but decreased progressively from three years after planting. There was no large difference in number of stems among application rates of fertilizers from three years after planting which was fully-grown stage. However, increasing in application rate of Nand $K_2$O twice as much as the standard rate had large effect on increasing the percentage of productive culm, and hence increased yield greatly.

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Effect of ITO thin films characterization by barrier layers$(SiO_2\;and\;Al_2O_3)$ on soda lime glass substrate (Soda lime glass기판위의 barrier층$(SiO_2,\;Al_2O_3)$이 ITO박막특성에 미치는 영향)

  • Lee, Jung-Min;Choi, Byung-Hyun;Ji, Mi-Jung;An, Yong-Tae;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.292-292
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    • 2007
  • To apply PDP panel, Soda lime glass(SLG) is cheeper than Non-alkali glass and PD-200 glass but has problems such as low strain temperature and ion diffusion by alkali metal oxide. In this paper suggest the methode that prohibits ion diffusion by deposing barrier layer on SLG. Indium thin oxide(ITO) thin films and barrier layers were prepared on SLG substrate by Rf-magnetron sputtering. These films show a high electrical resistivity and rough uniformity as compared with PD-200 glass due to the alkali ion from the SLG on diffuse to the ITO film by the heat treatment. However these properties can be improved by introducing a barrier layer of $SiO_2\;or\;Al_2O_3$ between ITO film and SLG substrate. The characteristics of films were examined by the 4-point probe, SEM, UV-VIS spectrometer, and X-ray diffraction. GDS analysis confirmed that barrier layer inhibited Na and Ka ion diffusion from SLG. Especially ITO films deposited on the $Al_2O_3$ barrier layer had higher properties than those deposited on the $SiO_2$ barrier layer.

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Effects of Oyster Shell Lime on Barley Growth and Soil Microbe in an Upland Soil (패화석이 보리생육과 토양 미생물상에 미치는 영향)

  • Lee, Young-Han;Sonn, Yeon-Kyu;Lee, Seong-Tae;Heo, Jae-Young;Kim, Min-Keun;Kim, Eun-Seok;Song, Won-Doo;Kim, Dae-Ho;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.610-613
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    • 2012
  • Oyster shell has a high content of $CaCO_3$ to be used as a acidic soil amendment. To enhance productivity of barley and soil microbe in an upland soil, oyster shell and calcium-magnesium carbonate were selected as a soil amendments in this study. A field experiment was treated no treatment (hereafter, control), oyster shell lime $3.09Mg\;ha^{-1}$ and $2.38Mg\;ha^{-1}$, and calcium-magnesium carbonate $2.38Mg\;ha^{-1}$ as amount of lime requirement in silt loam soil. The yield of barley from the oyster shell lime treatment was the highest. The protein content of barley was the highest of 11.1% in the calcium-magnesium carbonate, followed by 10.7% for the control, 10.6% for the oyster shell lime $3.09Mg\;ha^{-1}$, and 10.4% for the oyster shell lime $2.38Mg\;ha^{-1}$. Soil pH value was higher than that of control in harvesting stage. In addition, the population of soil bacteria was highest in oyster shell lime $2.38Mg\;ha^{-1}$, actinomycetes was highest in calcium-magnesium $2.38Mg\;ha^{-1}$. We concluded that the oyster shell lime can be effective to restore soil nutrient and microbe balance in an upland soil.

Lowered Substrate pH Reduced the Bicarbonate Injury during Vegetative Growth of 'Ssanta' Strawberry (혼합상토의 pH 저하가 영양생장 중인 '싼타' 딸기의 중탄산 피해 경감에 미치는 영향)

  • Lee, Hee Su;Cheung, Jong Do;Choi, Jong Myung
    • Journal of Bio-Environment Control
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    • v.26 no.2
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    • pp.115-122
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    • 2017
  • Objective of this research was to investigate the influence of lowered substrate pH on the reduction of bicarbonate injury in the vegetative growth of 'Ssanta' strawberry. The acid substrate was formulated by mixing sphagnum peat moss with pine bark (5:5, v/v) and the pH, EC, and CEC of the substrate were 4.07, $0.46dS{\cdot}m^{-1}$, and $91.3cmol^+{\cdot}kg^{-1}$, respectively. To adjust the pH of acid substrate, various amount of dolomitic lime [$CaMg(CO_3)_2$] were incorporated with the rate of 0 (untreated), 1, 2, 3, and $4g{\cdot}L^{-1}$. Then, mother plants were transplanted and grown with fertilizer solution containing $240mg{\cdot}L^{-1}$ of the $HCO_3{^-}$ and equal concentrations of essential nutrients to Hoagland solution. In growth of 'Ssanta' strawberry, fresh weight of mother plants were the highest in the treatment of $2g{\cdot}L^{-1}$ dolomitic lime such as 102.1 g followed by 94.7 g in $1g{\cdot}L^{-1}$, 91.2 g in $3g{\cdot}L^{-1}$, 75.7 g in $0g{\cdot}L^{-1}$ and 72.3 g in $4g{\cdot}L^{-1}$ treatments. The dry weight showed a similar tendency to fresh weight. At 140 days after transplanting, 5.8, 9.8, 11.8, 8.8, and 5.0 daughter plants were derived from each of the mother plants in the treatments of 0, 1, 2, 3, and $4g{\cdot}L^{-1}$ dolomitic lime, respectively. The highest occurrence of daughter plants were observed in the treatments $2g{\cdot}L^{-1}$ dolomitic lime. The substrate pH and bicarbonate concentration of 'Ssanta' strawberry seedlings in the 1 and $2g{\cdot}L^{-1}$ dolomitic lime treatments were maintained at a proper range such as 5.6 to 6.2. The micro-nutrient contents of above ground tissue in mother plants were the highest in $2g{\cdot}L^{-1}$ and the lowest in $4g{\cdot}L^{-1}$ dolomitic lime treatment. The above results indicate that incorporation rate of dolomitic lime in acid substrate with the pH of around 4 is $2g{\cdot}L^{-1}$ to raise the 'Ssanta' strawberry in propagation.

A Comparison on the Effect of Stabilization Methods for Rice Paddies contaminated by Heavy Metal (중금속 오염 농경지 토양의 안정화 처리공법 효과 비교)

  • Yu, Chan;Yun, Sung-Wook;Park, Jin-Chul;Lee, Jung-Hoon;Choi, Seung-Jin;Choi, Duck-Yong;Yi, Ji-Min
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.819-835
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    • 2009
  • In order to investigate the field application of selected stabilization methods(cover soil method, surface and total interval treatment of embankment method) on rice paddies contaminated by heavy metals, column test was carried out with heavy metal-contaminated soils collected from rice paddies around abandoned mine site. Columns were made by acrylic and filled with untreated soil, treated soil mixed with amendments(lime stone and steel refining slag) and uncontaminated cover soil according to the design report. Distilled water was discharged into the columns with the velocity of 1 pore volume/day. During test, pH, EC, and heavy metal concentration were measured in the regular term. The column test result showed that the selected stabilization methods were effective remediation method to stabilize heavy metals in paddy soils, but it was also expected that application of surface treatment methods was required the careful observation on pH variation due to the lowest increment.

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