• Journal of Korean Society for Atmospheric Environment
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• v.28 no.5
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• pp.506-517
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• 2012

Electronic Toll Collection System (ETCS), so called "Hi-Pass" in Korea, has improved traffic flow at toll gate of highways. It is known that the improvement of traffic flow should reduce air pollutants and $CO_2$ from vehicles. In this study, real driving emission of a light duty truck with Portable Emission Measurement System(PEMS) has been measured to evaluate the emission reduction effect due to ETCS. The correlations between driving variables and emissions have been analyzed to verify its effect on traffic flow improvement and emission reduction at toll gate. We considered average vehicle speed, Relative Positive Acceleration (RPA), and the distance of queue as driving variables. Compared to passing Manual Toll Collection System (MTCS) lane without queue, ETCS was able to reduce 38.7% of $NO_x$, 21.6% of soot, and 27.7% of $CO_2$. The results showed that the higher the average vehicle speed, the lower RPA and no queue in ETCS contributed to the emission reductions. Linear equation models with RPA and queue have been established by the multiple linear regression method. The linear models resulted in the higher coefficient of determination than those with only average vehicle speed used for establishing vehicle emission factors.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.1
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• pp.72-82
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• 2008

Benzene is a very harmful and toxic compound known as human carcinogen by all routes of exposure. Owing to the risky feature of benzene, several countries such as Japan, UK and EU have established the ambient air quality standard and protect from that risk of it. Korea also has designated it as one of the criteria air pollutants and established the concentration limit ($5\;{\mu}g/m^3$) in the air and is going to apply the standard from 2010. Benzene is emitted from various sources such as combustion plants, production processes, waste treatment facilities and also automobiles. Mobile source is known as one of the major emission sources of benzene. In this study, we estimated the domestic emissions of benzene from mobile source and compared the results with those of advanced countries. Mobile source was divided into 2 categories, Le., on-road source and non-road source. The total emissions of benzene from mobile source were estimated as 3,106 tons/yr and 1,612 tons/yr was emitted from on-road source and 1,494 tons/yr was from non-road source. Emission ratio of benzene from on-road source showed that 80.0% was from passenger cars, 10.1% was from taxis, 7.2% was from light-duty vehicles, 2.5% was from heavy-duty vehicles and 0.2% was from buses. In the case of non-road source, the distribution showed that 66.3% was from construction machineries, 14.5% was from locomotives, 11.7% was from ships, 7.1% was from agriculture equipments and 0.5% was from aircrafts. The cold-start emissions were estimated as 942 tons/yr and this value was almost 1.5 times greater than that for hot engine emissions (608 tons/yr). In addition, the fuel-based distribution was 65.9%, 31.1% and 2.8% from gasoline, LPG and diesel vehicles, respectively. The emission ratio from mobile source occupied 65% and 30% of total benzene emissions in USA and UK, respectively. In case of Korea, the emission ratio of benzene from mobile source occupied 29% (15% from on-road source, 14% from non-road source) which showed similar value with UK.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.2
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• pp.67-75
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• 2014

Biodiesel as alternative fuels has been widely studied due to biodiesel merits such as lower sulfur, lower aromatic hydrocarbon and higher oxygen content. But biodiesels could be easily oxidized by several conditions. In this study, various antioxidants such as propyl gallate, TBHA, TBHQ, DTBHQ, butyl-amin, aniline and pyrogallol were added in the biodiesel produced by the used cooking oil, then the material property test and the vehicle emissions test were conducted in accordance with test method. From the results of material property test, all antioxidants were suitable for the quality standard of density and kinematic viscosity, but Propyl gallate and Pyrogallol, as a type of Gallate additives, showed that the result of TAN increased rapidly according to the increase of the amount of additives. In the oxidation stability test, TBHQ, Butyl-amine and Aniline showed the excellent oxidation stability. Also, when considering the material property test, TBHQ was verified to the most excellent additives. In case of the vehicle emissions test, the testing was conducted by using the biodiesel added by TBHQ and was conducted by using two light duty diesel vehicles suitable for the EURO 4 and EURO 5 emission regulation. The result of testing showed that when the TBHQ was added, the amounts of CO, NOx and NMHC+NOx were decreased but the amount of $CO_2$ was increased.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.1-9
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• 2015

To satisfy stricter $NO_X$ emission regulations for light- and heavy-duty diesel vehicles, a control algorithm needs to be developed based on a selective catalytic reaction (SCR) dynamics model for chemical reactions. This paper presents the development and validation of a SCR dynamics model through test rig experiments and MATLAB simulations. A nonlinear state space model is proposed based on the mass conservation law of chemical reactions in the SCR dynamics model. Experiments were performed on a test rig to evaluate the effects of the $NO_X$ and $NH_3$ concentrations, gas temperature, and space velocity on the $NO_X$ conversion efficiency for the urea-SCR system. The parameter values of the proposed SCR model were identified using the experimental datasets. Finally, a control-oriented model for an SCR system was developed and validated from the experimental data in a MATLAB simulation. The results of this study should contribute toward developing a closed-loop control strategy for $NO_X$ and $NH_3$ slip reduction in the urea-SCR system for an actual engine test bench.