• Title/Summary/Keyword: Light absorption

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Polarization Properties of J-aggregates by Mutual Mixing Effect in the LB Films of Merocyanine Dyes (메로시아닌 색소 LB막의 상호혼합효과에 의한 J-aggregates 편광특성)

  • Yang, Chang-Heon;Kim, Gyong-Chol;Kwon, Young-Soo;Shin, Hoon-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.12
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    • pp.2245-2249
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    • 2010
  • The physical properties of the LB films with merocyanine dyes have been published and attract attention due to the possibility of molecular structure control. The evaluation of the thin films was focused for the purpose of molecular structure control. The molecular structure in the case of the thin films with dyes can be examine by optical absorption spectra measurements. In the result measured by optical absorption spectra, the $[DX]_{1-x}[DO]_x$ LB films shows a large in-plane anisotropy and the transition dipole moment of red-shifted band is preferentially oriented perpendicular to the dipping direction of the film, while that of the blue-shifted band prefers the dipping direction. The spectrum for $0_{\circ}$, $90_{\circ}$-polarized light coincides with the spectrum for non-polarized light and also with the spectrum was observed in the LB film deposited using a fresh solution. These results show that the aging process does not cause a structural change in chromophore but a change in the degree of molecular orientation. In the results, study of the merocyanine dyes LB films using optical absorption spectra would an interesting problem of absorbance peak shifts and mixed components.

Coherent Absorption Spectroscopy with Supercontinuum for Semiconductor Quantum Well Structure

  • Byeon, Ciare C.;Oh, Myoung-Kyu;Kang, Hoon-Soo;Ko, Do-Kyeong;Lee, Jong-Min;Kim, Jong-Su;Choi, Hyoung-Gyu;Jeong, Mun-Seok;Kee, Chul-Sik
    • Journal of the Optical Society of Korea
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    • v.11 no.3
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    • pp.138-141
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    • 2007
  • We suggest that supercontinuum can be used for absorption spectroscopy to observe the exciton levels of a semiconductor nano-structure. Exciton absorption spectrum of a GaAs/AlGaAs quantum well was observed using supercontinuum generated by a microstructrured fiber pumped by a femtosecond (fs) pulsed laser. Significantly narrower peaks were observed in the absorption spectrum from 11 K up to room temperature than photoluminescence (PL) spectrum peaks. Because supercontinuum is coherent light and can readily provide high enough intensity, this method can provide a coherent ultra-broad band light source to identify exciton levels in semiconductors, and be applicable to coherent nonlinear spectroscopy such as electromagnetically induced transparency (EIT), lasing without inversion (LWI) and coherent photon control in semiconductor quantum structures.

Optical Anisotropic Properties of Merocyanine Dye J-aggregates LB films by Molecular Interfacial Control (분자계면제어에 의한 메로시아닌 색소 J-회합체 LB막의 광학적 이방성 특성)

  • Shin, Hoon-Kyu;Park, Hyun-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.352-353
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    • 2007
  • The spectrum for $0_{\circ}$, $90_{\circ}$-polarized light coincides with the spectrum for non-polarized light and also with the spectrum was observed in the LB film deposited using a fresh solution. And, the formation and dissociation of J-aggregates, anisotropic behavior was no longer observed in the heat treated merocyanine dyes LB films. But, in the optical absorption spectra of same LB films by UV irradiation at room temperature, their were observed only dissociation of J-aggregates, that is decrease of absorbance peak without change spectral shape. On the other hand, in the case of optical absorption spectra of the LB films by the heat treatment at $70^{\circ}C$ in the air, both of the shifted absorption bands decay and a monomer absorption peak of about 530 nm appears instead.

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Effects of Light Intensity on Photosynthetic Activity of Shade Tolerant and Intolerant Tree Species (광도(光度)가 내음성(耐陰性)이 서로 다른 3수종(樹種)의 광합성(光合成) 생리(生理)에 미치는 영향(影響))

  • Kim, Pan-Gi;Yi, Yong-Sub;Chung, Dong-Jun;Woo, Su-Young;Sung, Joo Han;Lee, Eun Ju
    • Journal of Korean Society of Forest Science
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    • v.90 no.4
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    • pp.476-487
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    • 2001
  • In this study, three tree species (Populus euramericana, Kalopanax pictus and Quercus serrata) exhibiting different levels of shade tolerance were employed to investigate photosynthetic responses to the lower light condition on forest floors. Chlorophyll contents, spectral properties and photosynthetic characteristics were examined by using the tree species grown under high light intensity (PPFD $920{\mu}mol\;m^{-2}s^{-1}$) or low light intensity (PPFD $80{\mu}mol\;m^{-2}s^{-1}$). Plants grown under the low light intensity tended to have reduced leaf area, chlorophyll content per unit leaf area, light absorption and respiration in the shade intolerant tree species of P. euramericana. However, the shade tolerant species K. pictus and Q. serrata showed increased leaf area, chlorophyll content and net apparent quantum yield. Therefore, light absorption and light utilization efficiency were improved under the low light intensity. Also shade tolerant species maintained activities of photosystems and $CO_2$ fixation systems with little changes in low light intensity condition.

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Energy Absorption Characteristics of Al/CFRP Compound Tubes Under Axial Compression (축 하중을 받는 AI/CFRP 혼성튜브의 에너지흡수 특성)

  • 이길성;차천석;문지현;양인영
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.10a
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    • pp.108-113
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    • 2004
  • The compressive axial collapse tests were performed to investigate energy absorption characteristics of Al/CFRP compound tubes which are aluminum tubes wrapped with CFRP (Carbon Fiber Reinforced Plastics) outside the aluminum circular and square tubes. Based on collapse characteristics of aluminum tubes and CFRP tubes respectively, the axial collapse tests were performed for Al/CFRP compound tubes which have different fiber orientation angles. Test results showed that Al/CFRP compound tubes supplemented the unstable brittle failure of CFRP tubes due to ductile nature of inner aluminum tubes. In the light-weight aspect, specific energy absorption were the highest for Al/CFRP, CFRP in the middle, and aluminum the lowest. Also, specific energy absorption of circular tubes was higher than square tubes'. It turned out that fiber orientation angle of Al/CFRP compound tubes influence specific energy absorption together with the collapse modes of the tubes.

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Current Status in Light Trapping Technique for Thin Film Silicon Solar Cells (박막태양전지의 광포획 기술 현황)

  • Park, Hyeongsik;Shin, Myunghoon;Ahn, Shihyun;Kim, Sunbo;Bong, Sungjae;Tuan, Anh Le;Hussain, S.Q.;Yi, Junsin
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.95-102
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    • 2014
  • Light trapping techniques can change the propagation direction of incident light and keep the light longer in the absorption layers of solar cells to enhance the power conversion efficiency. In thin film silicon (Si) solar cells, the thickness of absorption layer is generally not enough to absorb entire available photons because of short carrier life time, and light induced degradation effect, which can be compensated by the light trapping techniques. These techniques have been adopted as textured transparent conduction oxide (TCO) layers randomly or periodically textured, intermediate reflection layers of tandem and triple junction, and glass substrates etched by various patterning methods. We reviewed the light trapping techniques for thin film Si solar cells and mainly focused on the commercially available techniques applicable to textured TCO on patterned glass substrates. We described the characterization methods representing the light trapping effects, texturing of TCO and showed the results of multi-scale textured TCO on etched glass substrates. These methods can be used tandem and triple thin film Si solar cells to enhance photo-current and power conversion efficiency of long term stability.

Absorption properties and size distribution of aerosol particles during the fall season at an urban site of Gwangju, Korea

  • Park, Seungshik;Yu, Geun-Hye
    • Environmental Engineering Research
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    • v.24 no.1
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    • pp.159-172
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    • 2019
  • To investigate the influence of pollution events on the chemical composition and formation processes of aerosol particles, 24-h integrated size-segregated particulate matter (PM) was collected during the fall season at an urban site of Gwangju, Korea and was used to determine the concentrations of mass, water-soluble organic carbon (WSOC) and ionic species. Furthermore, black carbon (BC) concentrations were observed with an aethalometer. The entire sampling period was classified into four periods, i.e., typical, pollution event I, pollution event II, and an Asian dust event. Stable meteorological conditions (e.g., low wind speed, high surface pressure, and high relative humidity) observed during the two pollution events led to accumulation of aerosol particles and increased formation of secondary organic and inorganic aerosol species, thus causing $PM_{2.5}$ increase. Furthermore, these stable conditions resulted in the predominant condensation or droplet mode size distributions of PM, WSOC, $NO_3{^-}$, and $SO{_4}^{2-}$. However, difference in the accumulation mode size distributions of secondary water-soluble species between pollution events I and II could be attributed to the difference in transport pathways of air masses from high-pollution regions and the formation processes for the secondary chemical species. The average absorption ${\AA}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950}$) for 370-950 nm wavelengths > 1.0 indicates that the BC particles from traffic emissions were likely mixed with light absorbing brown carbon (BrC) from biomass burning (BB) emissions. It was found that light absorption by BrC in the near UV range was affected by both secondary organic aerosol and BB emissions. Overall, the pollution events observed during fall at the study site can be due to the synergy of unfavorable meteorological conditions, enhanced secondary formation, local emissions, and long-range transportation of air masses from upwind polluted areas.

Energy absorption of the ring stiffened tubes and the application in blast wall design

  • Liao, JinJing;Ma, Guowei
    • Structural Engineering and Mechanics
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    • v.66 no.6
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    • pp.713-727
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    • 2018
  • Thin-walled mental tubes under lateral crushing are desirable and reliable energy absorbers against impact or blast loads. However, the early formations of plastic hinges in the thin cylindrical wall limit the energy absorption performance. This study investigates the energy absorption performance of a simple, light and efficient energy absorber called the ring stiffened tube. Due to the increase of section modulus of tube wall and the restraining effect of the T-stiffener flange, key energy absorption parameters (peak crushing force, energy absorption and specific energy absorption) have been significantly improved against the empty tube. Its potential application in the offshore blast wall design has also been investigated. It is proposed to replace the blast wall endplates at the supports with the energy absorption devices that are made up of the ring stiffened tubes and springs. An analytical model based on beam vibration theory and virtual work theory, in which the boundary conditions at each support are simplified as a translational spring and a rotational spring, has been developed to evaluate the blast mitigation effect of the proposed design scheme. Finite element method has been applied to validate the analytical model. Comparisons of key design criterions such as panel deflection and energy absorption against the traditional design demonstrate the effectiveness of the proposed design in blast alleviation.

Prediction of Color Reproduction using the Scattering and Absorption Coefficients derived from the Kubelka-Munk model in Package Printing (패키지 인쇄에 있어서 Kubelka-Munk Model 유래의 산란 및 흡수 계수를 이용한 색상 재현성 예측)

  • Hyun, Young-joo;Park, Jae-sang;Tae, Hyun-chul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.3
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    • pp.203-210
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    • 2021
  • With the development of package printing technology, the package has expanded from the basic function of protecting products to the marketing function through package design. Color, the visual element that composes the package design, is delivered to the consumer most quickly and effectively. As color marketing of these package designs expands, accurate color reproduction that the product wants to express is becoming more important. The color of an object is transmitted by absorption and scattering of light. Spectral reflectance refers to the intensity of light reflected by an object at different wavelengths by the spectral effect. As a result, the color of the object is expressed in various colors. Packaged printing inks have their own absorption and scattering coefficients, and the Kubelka-Munk model for color reproduction and prediction defines the relationship between these correlation coefficients through reflectance. In the Kubelka-Munk model for color reproduction and prediction, the relationship between the absorption and scattering coefficients (K/S) of printed material is predicted as the sum of the K/S values according to the mixing ratio of all color ink used. In this study, the reflectance of the measured print is reversely calculated at the mixing ratio of print ink using the Kubelka-Munk model. Through this, the relationship value of the ink-specific absorption/scattering coefficient constituting the final printed material is predicted. Delta E is derived through the predicted reflectance, and the similarity between the measured value and the predicted value is confirmed.

Enhancement of Dye-Sensitized Solar Cell Efficiency by Spherical Voids in Nanocrystalline ZnO Electrodes

  • Hieu, Hoang Nhat;Dao, Van-Duong;Vuong, Nguyen Minh;Kim, Dojin;Choi, Ho-Suk
    • Korean Journal of Materials Research
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    • v.24 no.9
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    • pp.458-464
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    • 2014
  • Light scattering enhancement is widely used to enhance the optical absorption efficiency of dye-sensitized solar cells. In this work, we systematically analyzed the effects of spherical voids distributed as light-scattering centers in photoanode films made of an assembly of zinc oxide nanoparticles. Spherical voids in electrode films were formed using a sacrificial template of polystyrene (PS) spheres. The diameter and volume concentration of these spheres was varied to optimize the efficiency of dye-sensitized solar cells. The effects of film thickness on this efficiency was also examined. Electrochemical impedance spectroscopy was performed to study electron transport in the electrodes. The highest power conversion efficiency of 4.07 % was observed with $12{\mu}m$ film thickness. This relatively low optimum thickness of the electrode film is due to the enhanced light absorption caused by the light scattering centers of voids distributed in the film.