• Title/Summary/Keyword: Light absorption

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OPTICAL PROPERTIES OF SEA WATER IN THE JAPAN SEA (동해 북동해역에서의 해수의 광학적 성질)

  • YANG Yong Rhim
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.10 no.3
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    • pp.173-177
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    • 1977
  • Optical properties were studied in the Japan Sea based on the optical observations in nine oceanographic stations from September 28 to October 2, 1976. Submarine light intensity was measured by using a submarine illuminometer (RIGO, Type: 2501-A) : equipped with a filter(RIGO, Type:V-R-60, wavelength: 600-620nm). In the upper 40 m depth layer light intensity was measured at 1 m depth interval. The absorption coefficient for red color in the area ranged from 0.142 to 0.323 (mean 0.232) : the Secchi-disc depth in the area ranged from 15 to 23 meters (mean 19.8 meters). The relation ship between absorption coefficient (m) am transparency depth (D) was m =4.93/D. The rates of light penetration for red color at three different depths are computed with reference to the surface light intensity At tile depths of 5 m, 10 m and 20 m, the rates of light penetration were $23.11\%(15-34.2\%),\;6.49\%(3.04-12\%)\;and\;0.698\%(0.113-1.27\%)$ respectively.

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Comparative Analysis of the Physical and Biochemical Properties of Light-cure Resin-modified Pulp Capping Materials

  • Tae Gyeom Kim;Jongsoo Kim;Joonhaeng Lee;Jisun Shin;Mi Ran Han;Jongbin Kim;Yujin Kim;Jae Hee Park
    • Journal of the korean academy of Pediatric Dentistry
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    • v.51 no.2
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    • pp.149-164
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    • 2024
  • This study compared the solubility, water absorption, dimensional stability, release of various ions (hydroxyl, calcium, sulfur, strontium, and silicon), and cytotoxicity of light-cured resin-modified pulp-capping materials. Resin-modified calcium hydroxide (Ultra-blendTM plus, UBP), light-cured resin-modified calcium silicate (TheraCal LCTM, TLC), and dual-cure resin-modified calcium silicate (TheraCal PTTM, TPT) were used. Each material was polymerized; solubility, 24-hour water absorption, and 30- day dimensional stability experiments were conducted to test its physical properties. Solubility was assessed according to the ISO 6876 standard, and 24 hours of water absorption, 30 days of dimensional stability were assessed by referring to the previous protocol respectively. Eluates at 3 and 24 hours and on 7, 14, and 28 days were analyzed according to the ISO 10993-12 standard. And the pH, Ion-releasing ability, cell proliferation rate, and cell viability were assessed using the eluates to evaluate biochemical characteristics. pH was measured with a pH meter and Ion-releasing ability was assessed using inductively coupled plasma atomic emission spectrometry (ICP-AES). Cell proliferation rate and cell viability were assessed using human dental pulp cells (hDPCs). The former was assessed by an absorbance assay using the CCK-8 solution, and the latter was assessed by Live and Dead staining. TPT exhibited lower solubility and water absorption than TLC. UBP and TPT demonstrated higher stability than TLC. The release of sulfur, strontium, calcium, and hydroxyl ions was higher for TLC and TPT than for UBP. The 28-day release of hydroxyl and silicon ions was similar for TLC and TPT. TLC alone exhibited a lower cell proliferation rate compared to the control group at a dilution ratio of 1 : 2 in cell proliferation and dead cells from Live and Dead assay evaluation. Thus, when using light-cure resin-modified pulp-capping materials, calcium silicate-based materials can be considered alternatives to calcium hydroxide-based materials. Moreover, when comparing physical and biochemical properties, TPT could be prioritized over TLC as the first choice.

Influence of Reducing Agents and Additives on the Synthesis of ZnSe Nanoparticles (ZnSe 나노분말 합성에 미치는 환원제와 첨가제의 영향)

  • Back, Geum Ji;Lee, Da Gyeong;Lee, Min Seo;Song, Ha Yeon;Hong, Hyun Seon
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.233-240
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    • 2020
  • Nano-sized ZnSe particles are successfully synthesized in an aqueous solution at room temperature using sodium borohydride (NaBH4) and thioglycolic acid (TGA) as the reducing agent and stabilizer, respectively. The effects of the mass ratio of the reducing agent to Se, stabilizer concentration, and stirring time on the synthesis of the ZnSe nanoparticles are evaluated. The light absorption/emission properties of the synthesized nanoparticles are characterized using ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, and particle size analyzer (PSA) techniques. At least one mass ratio (NaBH4/Se) of the reducing agent should be added to produce ZnSe nanoparticles finer than 10 nm and to absorb UV-vis light shorter than the ZnSe bulk absorption wavelength of 460 nm. As the ratio of the reducing agent increases, the absorption wavelengths in the UV-vis curves are blue-shifted. Stirring in the atmosphere acts as a deterrent to the reduction reaction and formation of nanoparticles, but if not stirred in the atmosphere, the result is on par with synthesis in a nitrogen atmosphere. The stabilizer, TGA, has an impact on the Zn precursor synthesis. The fabricated nanoparticles exhibit excellent photo-absorption/discharge characteristics, suggesting that ZnSe nanoparticles can be alloyed without the need for organic solutions or high-temperature environments.

A comparative study on the phytochemical and anti-oxidant activity differences in HongJam prepared with various silkworm varieties

  • Nguyen, Phuong;Kim, Seong-Wan;Jo, You-Young;Beteta, Sofia Pallais;Kang, Sang Kook;Kim, Soo Bae;Kim, NamSook;Kweon, Hae Yong;Kim, Kee-Young;Koh, Young Ho
    • International Journal of Industrial Entomology and Biomaterials
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    • v.41 no.2
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    • pp.19-27
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    • 2020
  • The aim of this study was to elucidate the difference in the amount of phytochemicals and anti-oxidant activities of the freeze-dried 5th instar 3rd day silkworm powder (FDSP) and 7 HongJams (HJs). Three primary colors of light of 8 silkworm powders revealed why each sample had unique color. The visual and absorption spectrum analyses of 80% methanol (MeOH) extracts of 8 silkworm powders revealed that white jade (WJ)-FDSP extracts showing strong forest-green colors had different absorption spectrum from 7 HJs. Among 7 HJs, the absorption spectrum of light green silkworm (LGS)-HJ extract was different from those of other HJ extracts. The amounts of total flavonoids and phenolic compounds of WJ-FDSP were 423.0±9.21% and 252.3±12.86%, respectively, more than those of WJ-HJ. Among 7 HJs, the amounts of total flavonoids and phenolic compounds in LGS-and red silkorm (RS)-HJ extracts were significantly more than those of WJ-HJ extract. Consistent with the amounts of phytochemicals, radical scavenging activity and reducing ability of WJ-FDSP extract were significantly higher that other HJ extracts. Among 7 silkworm powder extracts, LGS-HJ extract showed significantly higher radical scavenging activity and reducing ability than those of WJ-HJ extract. But, RS-HJ extract only showed significantly higher radical scavenging activity than that of WJ-HJ extract. Taken together, the amounts of phytochemicals in 8 silkworm powders contributed on their colors and anti-oxidant activities.

Synthesis and Photovoltaic Performance of Long Wavelength Absorption Dyes for the Dye Sensitized Solar Cell (장 파장 대 태양광을 흡수하는 염료감응형태양전지에 대한 염료와 합성)

  • Kim, Sangah;Yoon, Jooyoung;Kim, Jaehong
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.89.2-89.2
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    • 2010
  • The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of $TiO_2$ are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

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Synthesis and Photovoltaic Performance of NIR Absorption Dyes for the Dye Sensitized Solar Cell (NIR 흡수 염료를 이용한 염료감응형 태양전지)

  • Kim, Sangah;Jung, Miran;Lee, Minkyung;Kim, Jaehong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.118.1-118.1
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    • 2011
  • The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of TiO2 are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

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An Improved Theoretical Model to Explain Electronic and Optical Properties of p-Type GaAs/AlGaAs Superlattices for Multi-Wavelength Normal Incidence Photodetectors

  • Kim, Byoung-Whi;Choi, Eun-Chang;Park, Kwon-Chul;Kang, Seok-Youl
    • ETRI Journal
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    • v.18 no.4
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    • pp.315-338
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    • 1997
  • We extend our previous theoretical analysis of electronic and optical properties of p-type quantum well structures based on the two heavy- and light-hole system to include all the three valence bands. These theories are then used to clarify the origin of the normal incidence absorption and photo current at photon wavelengths of 2 - 3 ${\mu}m$, which was observed in addition to the absorption around 8 ${\mu}m$ by a recent experimental investigation with heavily doped p-type GaAs/AlGaAs multi-quantum well (MQW) structures. In the theoretical analysis, the Hartree and exchange-correlation many-body interactions are taken into account within one-particle local density approximation, and it is shown that normal incidence absorption occurs in two wavelength regions over the transition energy range higher than barrier height for p-type GaAs/AlGaAs superlattices with well doping of $2{\times}10^{19}\;cm^{-3}$; one region has broad absorption peaks with coefficients of about 5000 $cm^{-1}$ around 8 ${\mu}m$, and the other has two rather sharp peaks at 2.7 ${\mu}m$ and 3.4 ${\mu}m$ with 1800 $cm^{-1}$ and 1300 $cm^{-1}$, respectively. The result indicates that the theory explains the experimental observation well, as the theoretical and experimental results are in close agreement in general absorption features.

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Effect of Acoustic Reflector's Surface Density on Sound Absorption Characteristics and Stage Acoustics (음향 반사판의 밀도별 흡음특성 및 무대음향에의 영향)

  • Kim, Young-Sun;Jeong, Jeong-Ho;Jeon, Jin-Yong;Kim, Myeong-Seok
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.5
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    • pp.429-436
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    • 2012
  • In concert halls and auditoriums, acoustic reflector and stage enclosure is one of the main factors on the room and stage acoustic characteristics. As a stage enclosure and acoustic reflector honey comb based light-weight reflector is widely used, because it is easy to install. However, there was not enough research on the surface density effect on room and stage acoustics. In this study, sound absorption coefficient tests on three kinds of wooden acoustic reflectors with different surface density were conducted. Surface density of acoustic reflector was changed from 11 kg/$m^2$ to 41 kg/$m^2$. For the low frequency excitation, sub-woofer was used with omnidirectional loud-speaker simultaneously. From the experiments, it was found that sound absorption coefficient below 250 Hz band was decrease by the increment of surface density. In order to check the influence of the surface density on room and stage acoustic parameters, room acoustic simulation was conducted with sound absorption coefficients, which were tested in reverberation chamber. By the increment of surface density of acoustic reflector, RT(reverberation time) and EDT(early decay time) were increased. Also, ST(stage support) was improved in low frequency bands.

MAGNETOSPHERIC STRUCTURE OF THE INTERMEDIATE POLAR

  • Kim, Yong-Gi
    • Journal of Astronomy and Space Sciences
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    • v.11 no.1
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    • pp.1-12
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    • 1994
  • The structure of the magnetic funnel element in the intermediate polar is considered in terms of an important site for the X-ray absorption and the reemission of the X-ray as the optical light. In this paper the column density and the optical depth vary with the filling factor, which is introduced to characterize the structure of matter in the magnetic funnel element. The results of the energy dependence of the X-ray spectrum and the modulation depth of the X-ray light curve are discussed.

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Optical Anisotropy of Polyimide and Polymethacrylate Containing Photocrosslinkable Chalcone Group in the Side Chain under Irradiation of a Linearly Polarized UV Light

  • Choi, Dong-Hoon;Cha, Young-Kwan
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.469-476
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    • 2002
  • Photocrosslinkable soluble polyimide and polymethacrylate compound were synthesized for studying the optically induced anisotropy of the thin films. Chalcone group was introduced into the side chain unit of two polymers. We observed a photodimerization behavior between the double bonds in the chalcone group and an optical anisotropy of these materials by irradiation of a linearly polarized UV light (LPL). Optical anisotropy of the thin film was also investigated by using polarized UV absorption spectroscopy. The dynamic property of optical anisotropy in photoreactive polyimide was compared to that in polymethacrylate containing chalcone group in the side chain.