• Title/Summary/Keyword: Light absorption

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Photoinhibition Induced Alterations in Energy Transfer Process in Phycobilisomes of PS II in the Cyanobacterium, Spirulina platensis

  • Kumar, Duvvuri Prasanna;Murthy, Sistla D.S.
    • BMB Reports
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    • v.40 no.5
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    • pp.644-648
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    • 2007
  • Exposure of algae or plants to irradiance from above the light saturation point of photosynthesis is known as high light stress. This high light stress induces various responses including photoinhibition of the photosynthetic apparatus. The degree of photoinhibition could be clearly determined by measuring the parameters such as absorption and fluorescence of chromoproteins. In cyanobacteria and red algae, most of the photosystem (PS) II associated light harvesting is performed by a membrane attached complex called the phycobilisome (PBS). The effects of high intensity light (1000-4000 ${\mu}mol$ photons $m^{-2}s^{-1}$) on excitation energy transfer from PBSs to PS II in a cyanobacterium Spirulina platensis were studied by measuring room temperature PC fluorescence emission spectra. High light (3000 ${\mu}mol$ photons $m^{-2}s^{-1}$) stress had a significant effect on PC fluorescence emission spectra. On the other hand, light stress induced an increase in the ratio of PC fluorescence intensity of PBS indicating that light stress inhibits excitation energy transfer from PBS to PS II. The high light treatment to 3000 ${\mu}mol$ photons $m^{-2}s^{-1}$ caused disappearance of 31.5 kDa linker polypeptide which is known to link PC discs together. In addition we observed the similar decrease in the other polypeptide contents. Our data concludes that the Spirulina cells upon light treatment causes alterations in the phycobiliproteins (PBPs) and affects the energy transfer process within the PBSs.

Preparation of Nano Titania Sols and Thin Films added with Transition Metal Elements (전이금속원소들이 첨가된 나노 티타니아 졸 및 코팅막 제조)

  • Lee K.;Lee N. H.;Shin S. H.;Lee H. G.;Kim S. J.
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.634-641
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    • 2004
  • The photocatalytic performance of $TiO_2$ thin films coated on porous alumina balls using various aqueous $TiOCl_2$ solutions as starting precursors, to which 1.0 $mol\%$ transition metal ($Ni^{2+},\;Cr^{3+},\;Fe^{3+},\;Nb^{3+},\;and\;V^{5+}$) chlorides had been already added, has been investigated, together with characterizations for $TiO_2$ sols synthesized simultaneously in the same autoclave through hydrothermal method. The synthesized $TiO_2$ sols were all formed with an anatase phase, and their particle size was between several nm and 30 nm showing ${\zeta}-potential$ of $-25{\sim}-35$ mV, being maintained stable for over 6 months. However, the $TiO_2$ sol added with Cr had a much lower value of -potential and larger particle sizes. The coated $TiO_2$ thin films had almost the same shape and size as those of the sol. The pure $TiO_2$ sol showed the highest optical absorption in the ultraviolet light region, and other $TiO_2$ sols containing $Cr^{3+},\;Fe^{3+}\;and\;Ni^{2+}$ showed higher optical absorption than pure sol in the visible light region. According to the experiments for removal of a gas-phase benzene, the pure $TiO_2$ film showed the highest photo dissociation rate in the ultraviolet light region, but in artificial sunlight the photo dissociation rate of $TiO_2$ coated films containing $Cr^{3+},\;Fe^{3+}\;and\;Ni^{2+}$ was measured higher together with the increase of optical absorption by doping.

Ag2Se-Graphene/TiO2 Nanocomposites, Sonochemical Synthesis and Enhanced Photocatalytic Properties Under Visible Light

  • Meng, Ze-Da;Zhu, Lei;Ghosh, Trisha;Park, Chong-Yeon;Ullah, Kefayat;Nikam, Vikram;Oh, Won-Chun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3761-3766
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    • 2012
  • $Ag_2Se$-Graphene/$TiO_2$ composite was synthesized by a facile sonochemical method. The as-prepared products were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM) and UV-vis diffuse reflectance spectrophotometer. During the reaction, both of the reduction of graphene oxide and loading of $Ag_2Se$ and $TiO_2$ particles were achieved. The as-prepared $Ag_2Se$-Graphene/$TiO_2$ composites possessed great adsorptivity of dyes, extended light absorption range, and efficient charge separation properties simultaneously. Hence, in the photodegradation of rhodamine B (Rh.B), a significant enhancement in the reaction rate was observed with $Ag_2Se$-Graphene/$TiO_2$ composites, compared to the pure $TiO_2$. The high activity can be attributed to the synergetic effects of high charge mobility, and red shift in absorption edge of $Ag_2Se$-Graphene/$TiO_2$ composites.

Applications of metamaterials: Cloaking, Photonics, and Energy Harvesting

  • Kim, Kyoungsik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.77.2-77.2
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    • 2015
  • Recently, metamaterials attracted much attention because of the potential applications for superlens, cloaking and high precision sensors. We developed several dielectric metamaterials for enhancing antireflection or light trapping capability in solar energy harvesting devices. Colloidal lithography and electrochemical anodization process were employed to fabricate self-assembed nano- and microscale dielectric metamaterials in a simple and cost-effective manner. We improved broadband light absorption in c-Si, a-Si, and organic semiconductor layer by employing polystyrene (PS) islands integrated Si conical-frustum arrays, resonant PS nanosphere arrays, and diffusive alumina nanowire arrays, respectively. We also demonstrated thin metal coated alumina nanowire array which is utilized as an efficient light-to-heat conversion layer of solar steam generating devices. The scalable design and adaptable fabrication route to our light management nanostructures will be promising in applications of solar energy harvesting system. On the other hands, broadband invisible cloaks, which continuously work while elastically deforming, are developed using smart metamaterials made of photonic and elastic crystals. A self-adjustable, nearly lossless, and broadband (10-12GHz) smart meatamaterials have great potentials for applications in antenna system and military stealth technology.

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Property of Thermal Conductivity of Light Weight Panel Core Using Light-Weight Aggregate (인공경량골재를 이용한 경량패널 심재의 열전도 특성)

  • 이정국;도정윤;문경주;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.131-136
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    • 2002
  • In recent year, it has been investigated on the reduction of mass of structures for the purpose of the larger space and the economy with the industry developing very fast and qualitatively. So the purpose of this study is to investigate the manufacture of light weight concrete panel using the artificial light-weight aggregate as a part of the substitution of foamed styrene and polyurethane because of narrow allocable temperature zone in use. The compressive strength, flexural strength, unit weight, absorption test and thermal conductivity were practised at 3, 7 and 28 days after manufacturing the light-weight concrete lot the panel core: the filling ratio of continuous void was defied as 40%, 50%, and 60% and water-cement rate was 35, 40 and 45%. As a result of this, it was revealed that the mixture derived from filling ration of void of 50% and water-cement ratio 40% were developing the best properties of the others.

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Performance Evaluation of Polymer Cementitious Interior Finish Using Light-Weight Aggregates Containing Pyroligneous Liquid (목초액 담지체를 골재로 사용한 폴리머 시멘트계 내장마감재의 성능평가)

  • Lee, Chae-Young;Kim, Joo-Young;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.218-219
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    • 2014
  • The purpose of this study is to develop eco-friendly internal material of acrylic emulsion mortars using light-weight aggregate carrier which contains pyroligneous liquid. Four types of light-weight aggregates (vermiculite, perlite, charcoal, zeolite) that are widely used in building materials are selected and the properties such as adhesion, water absorption coefficient, antibiosis, crack and impact resistance are evaluated in accordance with KS F 4715. As a result, the properties of acrylic emulsion mortars using light-weight aggregate carrier are satisfied with KS requirements. The antibiosis is improved with increasing zeolite light-weight carrier content.

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THE NEW FINDING OF A LIGHT DEPENDENT $Ca^{2+}$ CHANNEL AND $Na^+-Ca^{2+}$ EXCHANGER IN THE VERTEBRATE RETINA (II)

  • Kim, Yun-Sook;Jung, Hyuk;Park, Chang-Suck;Woo, Suk-Hyang;Kim, Hyun-Jung;Kim, You-Young
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.133-136
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    • 1996
  • Calcium modulates the activity of guanylate cyclase and plays a key role in dark and light adaptation in the visual system. We have measured the Ca$^{2+}$, K$^+$ and Na$^+$ concentration in dark and light adapted bullfrog's (Rana catesbeiana) vitreous humor by using the atomic absorption spectrophotometer. The calcium concentration of the light adapted bullfrog's vitreous humor was higher than that of the dark adapted bullfrog's vitreous humor. This means that ion activity between the photoreceptor and vitreous humor side is light dependent and we have found that a Ca$^{2+}$ channel and Na$^+$ - Ca$^{2+}$ exchanger exist in the vitreous humor.

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High Throughput Proteomic Approaches for the Dissection of Light Signal Transduction Pathways in Photosynthetic Cyanobacterium Synechocystis sp.PCC 6803

  • Chung Young-Ho;Park Young Mok
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2002.10a
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    • pp.203-205
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    • 2002
  • Light is an environmental signal that regulates photomovement and main energy source of photosynthesis in the cyanobacterium Synechocystis sp. PCC 6803 (Syn6803). Syn6803 is a popular model system for study of plant functional genomics. In this report, we adopted 2D gel based proteomics study to investigate proteins related with the light absorption and photo-protection in Syn6803. More than 700 proteins were detected on the SDS-gels stained with silver nitrate. Several proteins showing different expression level under various light conditions were identified with MALDI-TOF Mass spectrometry. As a comparison, we also conducted ICAT-based proteome study using WT and cphl (cyanobacterial phytochrome 1) mutant. A cphl deletion led to changes in the expression of proteins involved in translation, photosynthesis including photosystem and CO2 fixation, and cellular regulation. We are currently involved in TAP-tagging method to study protein-protein interactions in search for the molecular component involved in the light signal transduction of Syn6803 photomovement.

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유기 발광 다이오드의 광 추출 효율 개선을 위한 다양한 광학기능구조의 적용

  • Kim, Yang-Du;Kim, Gwan;Heo, Dae-Hong;Lee, Heon
    • Ceramist
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    • v.21 no.1
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    • pp.64-79
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    • 2018
  • Recent years, OLEDs have been progressed intensively and been widely applied to Display and Lighting industry,Almost 100% internal quantum efficiency was achieved by developing new materials and structure optimization. However, external quantum efficiency was still low due to total internal reflection of light inside OLED devices and absorption of light at the surface of metal electrode. In order to improve external quantum efficiency of OLED devices, various kinds of optical functional structures were introduced to inside and outside of OLED devices to increase light extraction efficiency. In this paper, various efforts to apply optical functional structures in OLED devices were reviewed and way to improve light extraction efficency of OLED devices were discussed.

OPTICAL PROPERTIES Of SEA WATER IN THE NORTHWEST PACIFIC (북서태평양에서의 해수의 광학적 성질)

  • YANG Yong Rhim
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.10 no.4
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    • pp.237-241
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    • 1977
  • Optical properties were studied in the Northwest Pacific near Kamchatka Peninsula based on ten oceanographic stations from September 20 to 24, 1976. Submarine light intensity was measured by usins a submarine illuminometer (RIGO, Type: 2501-A) ; equipped with a red filter (RIGO, Type: V-R-60, wave length: 600-620 nm). Light intensity in the upper 40 m depth layer was measured at 1 m depth intervals. The absorption coefficient for red color in the area ranged from 0. 178 to 0.376 (mean 0.278) : the Secchidisc depth in the area ranged from 9 to 12 meters (mean 10.6 meters). The relationship between absorption coefficient (m) and transparency depth (D) was m=5.347/D. The rates of light penetration for red color at three different depths are computed with reference to the surface light intensity. The mean rates of light penetration were $16.36\%\;(6.45\~23.5\%),\;3.65\%\;(1.38\~7.31\%)\;and\;0.276\%(0.048\~0.647\%) $ at the depths of s m, 10 m, and 20 m, respectively.

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