• 제목/요약/키워드: Light absorption

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Isolation and Characterization of a Mutant Defective in Light-activated Heterotrophic Groth from Synechocystis sp. PCC 6803 (Synechocystis sp. PCC 6803으로부터 광활성 종속영양 생장결핍 돌연변이체의 분리 및 특성)

  • Park, Mi-Seon;Lee, Young-Sook;Kim, Young-Chang
    • Korean Journal of Microbiology
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    • v.32 no.3
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    • pp.202-207
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    • 1994
  • A mutant strain PRM1 defective in light-activated heterotrophic growth was isolated from Synechocystis sp. PCC 6803. PRM1 could be grown at growth rate equivalent to Synechocystis 6803 under mixotrophic growth conditions. However, PRM1 could not be grown under light-activated heterotrophic conditions, in which a daily pulse of light for 5 min was given. These results suggest that PRM1 is not defective in heterotrophic metabolism, but in the transduction pathway of light signal essential to the growth. Plasmid patterns, absorption spectra of whole cells, and the exterior and interior structures of PRM1 were similar to those of Synechocystis 6803, except that PRM1 could not produce amorphous slime holding cells together.

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Visible Light-Driven $CuInS_2-TiO_2$ Nanotube Composite Photoelectrodes with Heterojunction Structureusing Pulsed-Electrochemical Deposition Process (Pulse 전위를 적용한 전기화학적 증착 공정으로 제조된 가시광 활성 이종접합 $CuInS_2-TiO_2$ Nanotube 화합물 광전극)

  • Yun, Jung-Ho;Amal, Rose;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.49-56
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    • 2013
  • Excellent electron transport properties with enhanced light scattering ability for light harvesting have made well-ordered one dimensional $TiO_2$ nanotube(TNT) arrays an alternative candidate over $TiO_2$ nanoparticles in the area of solar energy conversion applications. The principal drawback of TNT arrays being activated only by UV light has been addressed by coupling the TNT with secondary materials which are visible light-triggered. As well as extending the absorption region of sunlight, the introduction of these foreign components is also found to influence the charge separation and electron lifetime of TNT. In this study, a novel method to fabricate the TNT-based composite photoelectrodes employing visible responsive $CuInS_2$ (CIS) nanoparticles is presented. The developed method is a square wave pulse-assisted electrochemical deposition approach to wrap the inner and outer walls of a TNT array with CIS nanoparticles. Instead of coating as a dense compact layer of CIS by a conventional non-pulsed-electrochemical deposition method, the nanoparticles pack relatively loosely to form a rough surface which increases the surface area of the composite and results in a higher degree of light scattering within the tubular channels and hence a greater chance of absorption. The excellence coverage of CIS on the tubular $TiO_2$ allows the construction of an effective heterojunction that exhibits enhanced photoelectrochemical performance.

Optical Property Measurements of Optical Phantoms and Honan Tissues Using Frequency-Domain Diffuse Optical Tomography (주파수 영역 확산광 단층촬영 장치를 이용한 광 팬텀 및 인체조직의 광 계수 측정)

  • Ho, Dong-Su;Kwon, Ki-Woon;Eom, Gi-Yun;Lee, Seung-Duk;Kim, Beop-Min
    • Journal of Biomedical Engineering Research
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    • v.28 no.2
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    • pp.229-234
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    • 2007
  • Diffuse optical tomography (DOT) is a relatively new medical imaging modality which uses near infrared light to image large-sized tissues noninvasively. We constructed a frequency-domain DOT system to measure the optical properties of optical phantoms and human tissues. The FD-DOT uses the intensity-modulated infrared light source that illuminates the biological tissues. The phase shift and modulation changes at each detector site are separately processed to measure the optical properties. The absorption and scattering coefficients are separately estimated using inverse algorithms.

The Study on Improvement of Acoustic Performance for Automobile Sound-absorbing Materials Using Hollow Fiber (중공 섬유를 이용한 자동차 흡음재 성능 향상 연구)

  • Lee, Jung-Wook;Lee, Su-Nam;Shim, Jae-Hyun;Jung, Pan-Ki;Lee, Won-Ku;Bang, Byoung-Joo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.9
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    • pp.850-857
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    • 2011
  • Generally, sound-absorbing materials in vehicles are used for giving the comfort to passengers by reducing noise while driving. Materials of which targets are light weight, high performance, eco friendliness and recycling have been developed recently. In this study, sound-absorbing materials using PET(polyethylene terephthalate) hollow fibers to achieve the light weight and the high sound absorption performance are developed, and then evaluated to meet a requirement for the automotive components. The test results show that the acoustic performances of developed products having new fiber structure are better than those of the conventional product.

The Novel Functional Chromophores Based on Squarylium Dyes

  • Park, Soo-Youl;Jun, Kun;Oh, Sea-Wha
    • Bulletin of the Korean Chemical Society
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    • v.26 no.3
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    • pp.428-432
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    • 2005
  • Squarylium or squaraine dyes are derived from 1,2-dihydroxycyclobuten-3,4-dione, otherwise known as squaric acids. They are two principal types: the 1,2-bisdonorsubstituted derivatives, and the 1,3-bisdonorsubstituted derivatives. The former are essentially merocyanines and have no distinctive properties, whereas the latter represent a unique type of chromophore, which is neither a merocyanines nor cyanine and has exceptional light absorption characteristics. They also have many functional applications based on their special properties. Thus it was the objective of this research project to synthesize a range of 1,3-squarylium dyes of widely differing structural types, and to investigate their light absorption and fluorescence properties in general, and the color change properties of appropriate examples in particular. Also in this study, the various pHinduced colour change processes were examined.

Photochemical Transformation of Chalcone Derivatives

  • Shin, Dong-Myung;Song, Dong-Mee;Jung, Kyoung-Hoon;Moon, Ji-Hye
    • Journal of Photoscience
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    • v.8 no.1
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    • pp.9-12
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    • 2001
  • The photoisomerization behavior of benzylideneacetophenones, known as chalcones, was studied. We synthesized the chalcone derivatives that have ether groups at 4 and 4' positions. Due to the electron donating ability of the ether oxygen, the bond order of the single bond between two phenyl ring of the chalcone strengthened, which eventually increased the rotational barrier of the single bond. The rotational barrier of the single bond is about 20-22 kcal/mole. Thermal recovery of this process took about 1 min. The UV-visible spectra of these chromophores exhibit two characteristic absorption peaks at 276 nm and 340 nm. The relative intensity of the peaks varies depending on the alkyl chain length of the substituent. Photo-irradiation with the 365 nm light monotonously decreases the 340 nm peak. However, the photo-irradiation with 254 nm light induce two competing processes and produced rather complicated absorption profile.

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A Study on the Photoisomerization of Langmuir-Bledgett Films of Fatty Acid (지방산 Langmuir-Bledgett막의 광이성화에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.193-198
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    • 1999
  • Maxwell displacement current(MDC) measuring technique has been applied on the study of monolayers of fatty acid. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about $130{\AA}^2$. MDCs were investigated in connection with monolayer compression cycles. It was found that the current pulses were generated over the entire range of molecular area, and the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. We investigated the change in absorption spectra of the fatty acid(8A5H) monolayer LB film due to cis-trans photoisomerization. It was found that the absorption spectrum of the 8A5H LB film was induce to photoisomerization by alternate irradiation with UV and visible light irradiation.

High-Power Conversion Efficiency of Photovoltaic Cells Fabricated with a Small-molecular and Polymer Donating Blend Layer

  • Kim, Ji-Heon;Park, Jea-Gun
    • Current Photovoltaic Research
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    • v.2 no.2
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    • pp.48-52
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    • 2014
  • A photovoltaic cell of CuPc:P3HT:PCBM was introduced to extend the light absorption in the visible wavelength between 300~500 and 550~800 nm. By fabricating the photovoltaic cells of ITO / PEDOT:PSS / CuPc:P3HT:PCBM / BCP / Al with small-molecular and polymer donating materials blended layer, we demonstrated a high PCE of 4.20% with high Jsc of $10.05mA/cm^2$. This performance of photovoltaic cell with the blended layer of small-molecular and polymer can be competitive with that of tandem cells.

The Study on Sound Absorption According to Content of Foaming Agent In Lightweight Concrete (경량화 콘크리트에서 기포제의 함량에 따른 흡음특성에 관한 연구)

  • Hong, D.K.;Ahn, C.W.;Kang, J.G.;Woo, B.C.;Choi, J.G.;Kang, H.C.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.955-958
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    • 2006
  • The purpose of this study is to find ways of recycling a great amount of gypsum as by-product from the manufacture of phosphate fertilizer. For the purpose, this researcher investigated physical properties of light weight Porous material using waste gypsum and a foaming agent, Sodium n-dodecyl Sulfate to utilize it as a interior material of construction. To determine such properties, the study examined pore size distribution and pore rate in accordance with contents of Sodium n-dodecyl Sulfate added. Then expanded vermiculite as light-weight aggregate was also added, when pore size distribution, pore rate and sound absorption rate were surveyed and measured.

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Molecular Thin Films and Small-molecule Organic Photovoltaics

  • Yim, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.63-63
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    • 2011
  • In this tutorial session, the field of organic photovoltaic (OPV) cells based on small molecular weight materials will be presented. The previously reported studies on the fabrication, structure, and property of the cells as well as the molecular materials are included. Especially, the factors hampering further enhancement in the power conversion efficiency of the cells such as exciton recombination, light absorption and interfacial morphology between electron donor and acceptor layer will be discussed in detail. The recent progress in our group will also be presented. It includes typical materials and cell fabrication techniques we used as well as the studies on improving the light absorption in the electron donor layer and reducing the extinction of excitons formed by introducing the nanostructured interface between organic layers.

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