• Title/Summary/Keyword: Light Scattering Effect

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Morphology of Styetched Poly(ethylene terephthalate)/ Poly(m-xylene adipamide) Blends (연신된 폴리(에틸렌 테레프탈레이트)/ 폴리(메타-자이렌 아디프아미드) 블렌드의 형태구조)

  • 남주영;박수현;이광희;정지원;박동화
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.313-322
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    • 2003
  • The morphology of poly(ethylene terephthalate) (PET)/poly(m-xylene adipamide) (MXD-6) blends, which was prepared by adding compatibilizer and interchange reaction agent, was investigated. The morphological change in the stretched blend films was also studied. The stretched film showed a dispersed MXD-6 fibril. This fibril became finer with increasing draw ratio (DR). The addition of compatibilizer and interchange reaction agent had no effect on the improvement of interfacial adhesion but caused a defect between the continuous phase and the dispersed phase, leading to the formation of irregular fibril. The change in the superstructure of blends with composition and draw ratio was examined with light scattering (LS). The H$\sub$v/ LS patterns showed a double-cross type pattern consisting of a broad rod-like pattern and a sharp cross streak. On the basis of the model calculation of the H$\sub$v/ pattern, it was found that the appearance of the double-cross type pattern was attributed to the stacking of crystals oriented along the draw direction. The crystals were gradually oriented to the stretching direction with draw ratio. As a result, the high level of orientation was obtained fur the sample of draw ratio is 6.0.

THE EFFECT OF SURFACE ROUGHNESS OF CSI(TL) MICRO-COLUMNS ON THE RESOLUTION OF THE X-RAY IMAGE; OPTICAL SIMULATION STUDY

  • Kim, Hyun-Ki;Bae, Jun-Hyung;Cha, Bo-Kyung;Jeon, Ho-Sang;Kim, Jong-Yul;Kim, Chan-Kyu;Cho, Gyu-Seong
    • Journal of Radiation Protection and Research
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    • v.34 no.1
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    • pp.25-30
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    • 2009
  • Micro-columnar CsI(Tl) is the most popular scintillator material which is used for many indirect digital X-ray imaging detectors. The light scattering at the surface of micro-columnar CsI(Tl) scintillator was studied to find the correlation between the surface roughness and the resultant image resolution of indirect X-ray imaging detectors. Using a commercially available optical simulation program, Light Tools, MTF (Modulation Transfer Function) curves of the CsI(Tl) film thermally evaporated on glass substrate with different thickness were calculated and compared with the experimental estimation of MTF values by the edge X-ray image method and CCD camera. It was found that the standard deviation value of Gaussian scattering model which is determined by the surface roughness of micro-columns could certainly change the MTF value of image sensors. This model and calculation methodology will be beneficial to estimate the overall performance of indirect X-ray imaging system with CsI(Tl) scintillator film for optimum design depending on its application.

Use of a Combined Photocatalysis/Microfiltration System for Natural Organic Matter Removal (광촉매 반응과 침지형 정밀여과를 이용한 자연산 유기물의 제거)

  • 추광호;박경원;김문현
    • Membrane Journal
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    • v.14 no.2
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    • pp.149-156
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    • 2004
  • This work focused on the degradation of natural organic matter (NOM) present in lake water using a combined pkotocatalysisimicrofiltration (MF) process. The system performances were investigated in terms of organic removal efficiency and membrane permeability. The addition of iron oxide particles (IOP) into the photocatalytic membrane reactor improved initial NOM removal by sorption, but during photocatalysis the removal efficiency was reversed, probably due to the scattering of UV light by IOP. The modification of TiO$_2$ surfaces by IOP deposition was conducted to enhance the photocatalytic NOM removal efficiency. A minimal amount of Impregnation of IOP on TiO$_2$ surfaces was required to prevent the light scattering effect as well. The coating of MF membranes with IOP helped to improve the NOM removal efficiency while sorbing NOM by IOP. Regardless of tile operating conditions and particles addition examined, no significant fouling was occurring at a flux of 15 L/$m^2$-h during entire MF operation.

Effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper (주요제지원료의 특성 및 고해가 종이의 pore structure 및 물성에 미치는 영향)

  • Nam, Ki-Young;Chung, Soon-Ki;Won, Jong-Myoung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2007.11a
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    • pp.127-134
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    • 2007
  • Paper is composed network of fibers. Since paper is plain, most cases paper is considered two-dimensional. But network of fibers creates a network of pores, and pores between fibers are most important part of the paper structure. So we have to make an approach to the paper by three-dimensionally. Pore structure in the Z-direction of the paper can affect directly not only basic properties od the paper such as density, porosity, opacity and strength but also coverage of the coating colors during coatong and printing properties. We studied effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper.

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Effect of Solvent Mixture Ratio on Rheology Property of Slurry and Thickness Control of Ceramic Green Sheets (유기 용매 혼합비에 따른 슬러리의 유동 특성과 세라믹 그린 쉬트의 두께 제어)

  • Kim, Jun-Young;Kim, Seung-Taek;Park, Jong-Chul;Yoo, Myong-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.236-241
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    • 2008
  • The effect of organic solvent mixture ratio on the rheology property of slurry and thickness control of ceramic green sheet was investigated. For selecting a suitable dispersant multiple light scattering method was used to evaluate the particle migration velocity and variation of clarification layer thickness. Using the selected dispersant the dispersion property of solution according to solvent mixture ratio was investigated. Binder and plasticizers were added to formulate slurries and their viscosity was evaluated according to solvent mixture ratio. Ceramic green sheets with average thickness of 30, 50 urn were fabricated via tape casting and their thickness tolerances measured. As a result according to solvent mixture ratio the solution and slurry properties varied and for the mixture ratio of ethanol/toluene of 80/20 the ceramic green sheet with the lowest thickness tolerance was obtained.

Nano-Soot Particle Formation in Inverse Diffusion Flames (인버스 확산화염에서의 나노 수트 입자 생성)

  • Lee, Eui-Ju;Shin, Hyun-Joon;Oh, Kwang-Chul;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.19-26
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    • 2003
  • Experimental measurements of flame structure and soot characteristics were performed for ethene inverse diffusion flames (IDF). IDF has been considered as the excellent flow field to study the incipient soot because soot particle do not experience the oxidation process. In this study, LIF image clarified the reaction zone of IDF with OH signal and PAH distribution. laser light scattering technique also identified the being of soot particle. To address the degree of soot maturing, C/H ratio and morphology of soot sample were investigated. From these measurements, the effect of flow residence time and temperature on soot inception could be suggested, and more details on soot characteristic in the IDF was determined according to fuel dilution and flame condition. The fuel dilution results in a decrease of temperature and enhancement of residence time, but the critical dilution mole fraction is existed for temperature not to effect on soot growth. Also, the soot inception evolved on the specific temperature and its morphology are independent of the fuel dilution ratio of fuel.

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Effect of Dispersion Stability of Particles on Detergency of Particulate Soil(Part 1) - The Dispersion Stability of α-Fe2O3 Particles in the Nonyl Phenol Polyoxyethylene Ether Solution - (입자의 분산안정성이 고형오구의 세척성에 미치는 영향(제1보) - Nonyl Phenol Polyoxyethylene Ether 용액 내에서 α-Fe2O3 입자의 분산안정성 -)

  • Kang, In-Sook
    • Fashion & Textile Research Journal
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    • v.4 no.1
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    • pp.86-91
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    • 2002
  • To estimate dispersion stability of particles, suspending power and particle size were examined as functions of pHs, surfactants, electrolytes and ionic strengths using ${\alpha}-Fe_2O_3$ particle as the model of particulate soil. Suspending power and particle size were determined by UV-Vis spectrumeter and by light scattering using the polarization ratio method, respectively. The suspending power was relatively high with polyanion electrolytes and was low with neutral salts. The suspending power was biphasis, minimum pH 6~7, and the effect of surfactant on the suspending power was insignificant. Generally suspending power increased with decreasing the particle size governed aggregation of dispersed particles regardless of solution conditions. Hence the suspending power was inversely related to the particle size.

Measuring the Light Dosimetry Within Biological Tissue Using Monte Carlo Simulation (Monte Csrlo 시뮬레이션을 이용한 생체조직내의 광선량 측정)

  • 임현수;구철희
    • Journal of Biomedical Engineering Research
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    • v.20 no.2
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    • pp.199-204
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    • 1999
  • As the correct measuring of the light dosimetry in biological tissues give the important affection to the effect of PDT treatment we used Monte Carlo simulation to measure the light dosimetry on this study. The parameters using in experiments are the optical properties of the real biological tissue, and we used Henyey-Greenstein phase function among the phase functions. As we results, we displayed the result the change of Fluence rate and the difference against the previous theory was at least 0.35%. Biological tissues using in experiment were Human tissue, pig tissue, rat liver tissue and rabbit muscle tissue. The most of biological tissue have big scattering coefficient in visible wavelength which influences penetration depth. The penetration depth of human tissue in visible region is 1.5~2cm. We showed that it is possible to measure fluence rate and penetration depth within the biological tissues by Monte Carlo simulation very well.

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Soot Formation Characteristics of Concentric Diffusion Flames with Mixture Fuels (이중동축류 화염을 이용한 혼합연료의 매연생성 특성에 관한 연구)

  • Lee, Won-Nam
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.123-128
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    • 2002
  • The synergistic effect of ethylene/propane and ethylene/methane mixtures on soot formation is studied experimentally with a concentric co-flow burner. The integrated soot volume fractions, laser light scattering signal and PAH concentrations are measured for different fuel supply configurations. The synergistic effect in ethylene/propane diffusion flames is found to be affected not only by the composition of mixture but also by the way of mixing. Comparing to the homogeneously mixed ethylene/propane case, the increase of soot formation is observed when propane is supplied through the inner nozzle, while the decrease is observed when propane is supplied through the outer nozzle. However, the measured PAH concentration distributions are inconsistent with the current view of the synergistic effect of ethylene./propane mixture on soot formation. Virtually no synergistic effect is observed in ethylene-methane flames regardless of the fuel supply configuration, which suggests the important role of $C_3$ species produced during the propane pyrolysis process for the synergistic effect.

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Effects of Multi-layer and TiCl4 Treatment for TiO2 Electrode in Dye-sensitized Solar Cell (염료감응 태양전지의 TiO2 전극의 다중층 및 TiCl4 처리에 따른 효과)

  • Kim, Gyeong-Ok;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.190-195
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    • 2011
  • To investigate the photon-trapping effect and scattering layer effect of $TiO_2$ multi-layer in dye-sensitized solar cell (DSSC) and the degree of recombination of electrons at the electrode treated $TiCl_4$, we formed electrodes of different conditions and obtained the most optimal electrode conditions. To estimate characteristics of the cell, IV curve, UV-Vis spectrophotometer, electrochemical impedance spectroscopy (EIS) and incident photon-to-current conversion efficiency (IPCE) were measured. As a result, we confirmed that the multi-layer's efficiency was higher than that of monolayer in the IV curve and the performance of $TiCl_4$ treated electrode was increased according to decreasing the impedance of EIS. Among several conditions, the efficiency of the cell with scattering layer is higher than that of a layer with the base electrode about 19%. Because the light scattering layer enhances the efficiency of the transmission wavelength and has long electron transfer path. Therefore, the value of the short circuit current increases approximately 10% and IPCE in the maximum peak also increases about 12%.