• Title/Summary/Keyword: LiNbO$_3$

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Fabrication of SAW filter using PZT ceramics (PZT압전세라믹을 이용한 SAW필터의 제작)

  • 정연호;송준태
    • Electrical & Electronic Materials
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    • v.10 no.1
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    • pp.1-7
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    • 1997
  • SAW filter has been used in mobile communication device, bandpass filter and resonator for merits )f miniaturization and high reliability. Materials for substrate mainly used single crystal such as LiNbO$_{3}$, LiTaO$_{3}$, ZnO. In this study, it was attempted that LiNbO$_{3}$ was substituted for piezoelectric ceramics(PZT4, PZT5A and PZT8) which had simple fabrication process because fabrication of crystal is difficult and it's cost is high. SAW filters were fabricated by the photolithography on piezoelectric ceramics substrates in order to compare their characteristics with LiNbO$_{3}$'s. The experimental value of center frequency was compared with theoretical one. The average difference of center frequency was 3.7%. PZT8 showed the best bandwidth properties among them. It is considered that PZT8 has higher mechanical quality factor and propagation velocity than others.

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Dielectric and Piezoelectric Characteristics of 0.95(K0.5Na0.5)NbO3-0.05Li(Sb0.8Nb0.2)O3 Pb-free Ceramics with amount of Ag2O Addition (Ag2O 첨가량에 따른 0.95(K0.5Na0.5)NbO3-0.05Li(Sb0.8Nb0.2)O3 무연 세라믹스의 유전 및 압전특성)

  • Kim, Do-Hyung;Yoo, Ju-Hyun;Jeong, Yeong-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.11
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    • pp.925-929
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    • 2009
  • In this study, $0.95(K_{0.5}Na_{0.5})NbO_3-0.05Li(Sb_{0.8}Nb_{0.2})O_3$ ceramics were investigated as a function of the amount of $Ag_2O$ addition in order to improve dielectric and piezoelectric properties of lead-free piezoelectric ceramics. With increasing the amount of $Ag_2O$ addition, density and electromechanical coupling factor ($k_p$) increased up to 0.2 wt.% $Ag_2O$ and decreased above 0.2 wt.% $Ag_2O$. At the sintering temperature of $1020^{\circ}C$, electromechanical coupling factor ($k_p$), density, dielectric constant (${\varepsilon}r$) and curie temperature (Tc) of ceramics with 0.2 wt% $Ag_2O$ showed the optimal values of 0.42, $4.33\;g/cm^3$, 738 and $393^{\circ}C$, respectively.

Diffractive characteristics of the photorefractive gratings in $LiNbO_3$:MgO ($LiNbO_3$:MgO 결정에서 광굴절 격자의 회절 특성)

  • 이재철;장지웅;김준태;신승호
    • Korean Journal of Optics and Photonics
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    • v.10 no.5
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    • pp.391-395
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    • 1999
  • We present the measurement of the diffraction efficiency and response time of the photorefractive grating recorded in $LiNbO_3$ photorefractive crystal doped with 4%-mole MgO. Two laser sources were used in the experiments; frequency-doubled Q-switched Nd:YAG laser ($\lambda$=532 nm) and cw Ar-ion laser ($\lambda$=514.5 nm). The same optical geometry was also used in both experiments in order to maintain the experimental consistency. Using the two-wave mixing scheme in both experiments we measured the maximum diffraction efficiency in the range of beam intensity of 1.6~100 W/ $\textrm{cm}^2$, and the response times for both cases of recording and erasing. Two sets of results obtained from the experiments are compared and analyzed.

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Dielectric and Piezoelectric Properties of Li-Substituted $(K_{0.5}Na_{0.5})(Nb_{0.96}Sb_{0.04})O_3$ Ceramics (Li 치환에 따른 $(K_{0.5}Na_{0.5})(Nb_{0.96}Sb_{0.04})O_3$ 세라믹스의 유전 및 압전 특성)

  • Seo, Byeong-Ho;Oh, Young-Kwang;Yoo, Ju-Hyun;Yoon, Hyun-Sang;Hong, Jae-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.307-307
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    • 2010
  • 최근 유한연료의 고갈로 인해 세계 유가가 불안정 됨으로서 대체 에너지에 대한 연구가 많이 진행 되고 있다. 특히 압전 소자를 이용한 에너지 하베스팅은 압전 역효과를 이용한 것으로서 주변에서 무의미하게 버려지는 진동이나 바람, 열 에너지를 실 생활에 사용할 수 있는 전기 에너지로 변환할 수 있는 유망한 기술 중 하나이다. 이러한 에너지 하베스팅 기술은 일본과 같은 선진국에서 이미 지하철 및 일반 다리와 같이 진동이 극히 많은 곳에서 응용되고 있다. 이러한 에너지 하베스팅 기술을 응용 하려면 전압출력 계수($g_{33}$)가 높아야 한다. 이것은 압전 d 상수와 유전상수에 영향을 많이 받는 것으로 알려져 있다. 현재가지 응용되는 압전 하베스팅 조성은 Pb(Zr,Ti)$O_3$ (PZT)를 기초로한 세라믹이 응용되고 있다. Pb(Zr,Ti)$O_3$ (PZT) 세라믹은 Morpohotropic phase boundary(MPB)에서 전기기계 결합계수 (kp) 와 기계적 품질계수 (Qm) 이 각각 0.5와 500으로 우수한 특성을 나타낸다. 또한 큐리온도 (Tc) 도 $400^{\circ}C$로 온도 안정성 또한 높다. 하지만 $1000^{\circ}C$ 이상에서 소결하는 PbO는 소결 중 급격한 휘발로 환경적 오염 뿐 아니라 특성의 저하를 야기시킨다. 그래서 몇몇 나라에서는 그 사용을 제한하고 점차적으로 사용을 줄여 나가고 있는 동시에 PbO가 첨가되어 있지 않은 Lead-Free 세라믹의 연구가 많이 진행되고 있다. Lead-Free 세라믹 중 alkaline niobate를 기초로 한 페로브스카이트 구조의 ($Na_{0.5}K_{0.5})NbO_3$ (NKN) 은 PbO를 기초로 한 세라믹을 대체할 유망한 후보자 중 하나이다. 하지만 NKN세라믹의 K 성분의 조해성 및 고온에서의 휘발로 인해 일반 적인 소결 방법으로는 고밀도의 세라믹을 얻기 매우 어렵다. 그래서 Hot pressing, Hot forging, RTGG(Reactive Template Grain Growth), SPS(Spark plasma Sintering)와 같은 특별한 소결 법을 이용하거나 $K_8CuNb_4O_{23}$(KCN) 이나 $K_{5.4}Cu_{1.3}Ta_{10}O_{29}$(KCT) 등을 첨가하여 그 소결성을 향상 시키는 방법도 있다. 또한 압전 d상수를 향상 시키기 위해 $Nb_2O_5$나, $La_2CO_3$, $CeO_2$, $Li_2CO_3$ 등을 치환함으로써 압전 d상수를 향상 시켜 전압출력 계수를 높이는 연구 또한 많은 보고가 되어 있다. 특히 $Li_2CO_3$의 첨가는 일반 적인 소결 방법으로도 밀도의 조밀함을 향상 시켜 그에 따른 높은 유전율과 전기기계 결합계수, 압전 d상수를 가져 많은 연구가 되어지고 있다. 그래서 본 연구에서는 일반적인 ($K_{0.5}N_{0.5})_{1-x}Li_x(Nb_{0.96}Sb_{0.04})O_3$ + 0.2mol%$La_2O_3$ + 1.2mol%$K_8CuNb_4O_{23}$ 세라믹에 x(=Li) 치환에 따른 유전 및 압전특성을 조사하였다.

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Piezoelectric and Dielectric Characteristics of $((Na_{0.5}K_{0.5})_{1-x}Li_x)(Nb_{0.8}Ta_{0.2})O_3$ Ceramics using Conventional Solid State Sintering method (상용 소결법을 이용한 $((Na_{0.5}K_{0.5})_{1-x}Li_x)(Nb_{0.8}Ta_{0.2})O_3$ 세라믹스의 압전 및 유전 특성)

  • Kim, Min-Soo;Kim, Sin-Woong;Oh, Seok;Jeong, Soon-Jong;Min, Bok-Ki;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.210-220
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    • 2006
  • Dense $((Na_{0.5}K_{0.5})_{1-x}Li_x)(Nb_{0.8}Ta_{0.2})O_3$ ceramics were developed by conventional sintering process. The electrical properties of $((Na_{0.5}K_{0.5})_{1-x}Li_x)(Nb_{0.8}Ta_{0.2})O_3$ ceramics were investigated as a function of Li substitution. When the sample sintered at $1100^{\circ}C$ for 4 h with the Substitution of 2 mol% Li, electro-mechanical coupling factor ($k_p$) and piezoelectric coefficient ($d_{33}$) were found to reach the highest values of 0.42 and 210 pC/N, respectively.

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Piezoelectric Properties of Lead-Free $(Na_xK_{0.94-x}Li_{0.06})NbO_3$ Ceramics ($(Na_xK_{0.94-x}Li_{0.06})NbO_3$ 세라믹스의 압전 및 유전 특성)

  • Jeon, So-Hyun;Kim, Min-Soo;Park, Jeong-Joo;Jeong, Soon-Jong;Kim, In-Sung;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.276-276
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    • 2007
  • As a candidate for lead-free piezoelectric materials, dense $(Na_xK_{0.94-x}Li_{0.06})NbO_3$ ceramics were developed by conventional sintering process. Sintering temperature was lowered by adding 1 mol% $Li_2O$ as a sintering aid. The electrical properties of $(Na_xK_{0.94-x}Li_{0.06})NbO_3$ ceramics were investigated as a function of Na/K ratio. When the sample sintered at $950^{\circ}C$ for 4 h with the compositions of morphotropic phase boundary, 0.47 < x < 0.51, electro-mechanical coupling factor ($k_p$) and piezoelectric coefficient ($d_{33}$) were found to reach the highest values of 0.42 and 190 pC/N, respectively. These excellent piezoelectric and electro-mechanical properties indicate that this system is potentially good candidate for lead-free material for a wide range of electro-mechanical transducer applications.

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2×2 Ti:LiNbO3 optical add/drop multiplexers utilizing tilted film-loaded SAW waveguides (Tilted Film-Leaded SAW 도파로를 이용한 2×2 Ti:LiNbO3 광 삽입/분기 멀티플렉서)

  • 강창민;정흥식
    • Korean Journal of Optics and Photonics
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    • v.14 no.6
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    • pp.657-662
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    • 2003
  • Optimum Hamming apodized acousto-optic 2${\times}$2 add/drop multiplexers, using SiO$_2$ film loaded acoustic waveguide with angular offset to the Ti:LiNbO$_3$ waveguide, were fabricated. The four-port device consists of two input waveguides, a polarization beam splitter (PBS), two polarization conversion/acoustooptic tuning waveguide sections, a second PBS and two output waveguides. Insertion loss <7.1 ㏈ has been obtained and side-lobe of -19 ㏈ for -32 ㎽ RF driving power has been realized. Add/drop performance has been confirmed and a linear tuning rate of 8.1 nm/MHz and a 3 ㏈ spectral width of -1.5 nm were demonstrated.