• Title/Summary/Keyword: Li-ion

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Charge-discharge behaviour of $LiNi_{0.85}Co_{0.15}O_2>/MPCF$ cell ($LiNi_{0.85}Co_{0.15}O_2/MPCF$전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.25-28
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    • 1998
  • Lithiated cobalt and nickel oxides are becoming very attractive as active cathode materials for secondary lithium ion secondary battery. $LiCoO_2$ is easily synthesized from lithium cobalt salts, but has a relatively high oxidizing potential on charge. LiNiOz is synthesized by a more complex procedure and its nonstoichiometry significantly degraded the charge-discharge characteristics. But $LiNiO_2$ has a lower charge potential which increases the system stability. Lithiated cobalt and nickel oxides are iso-structure which make the preparation of solid solutions of $LiNi_{1-x}Co_xO_2$ for O$LiCoO_2 and LiNiO_2$ electrode. The aim of the presentb paper is to study the electrochemical behaviour, as weU as the possibilities for practical application of layered Iithiated nickel oxide stabilized by $Co^{3+}$ substitution as active cathode materials in lithium ion secondary battery.

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The study on Fabrication and Characterization of $LiMn_{2-x}Cu_{x}O_{4}$for cathode material of Lithium-ion Battery (리튬이온 이차전지 양극활물질 $LiMn_{2-x}Cu_{x}O_{4}$의 제작과 전극특성에 관한 연구)

  • 박종광;고건문;홍세은;윤기웅;안용호;한병성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.713-716
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    • 2001
  • In many papers, the electrochemical analysis of LiMn$_2$O$_4$shows the transition results of Mn$^{3+}$ ion. Charge ordering is accompanied by simultaneous orbital ordering due to the Jahn-Teller effect in Mnl$^{3+}$ ions. To analyze the cycle performance of LiMn$_{2-x}$Cu$_{x}$ O$_4$as the cathode of 4 V class lithium secondary batteries, XRD, TGA analysis were conducted. Although the cycle performance of the LiMn$_{2-x}$Cu$_{x}$ O$_4$was improved from pure LiMn$_2$O$_4$, the discharge capacity was significantly lower than LiCoO$_2$. In this paper, We study the Electrochemical characterization and enhanced stability of Cu-doped spinels in the LiMn$_{2-x}$Cu$_{x}$ O$_4$upon initial cycling.l cycling.

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Study on Design Parameter of Aluminum Micro V-notched Component with Thin Sheet Metal (알루미늄 박판 미세 V-notching 가공부위의 성형 Parameter 관한 연구)

  • Kim, S.M.;Park, J.W.;Lee, H.M.;Ku, T.W.;Kim, J.;Kang, B.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.249-252
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    • 2008
  • Micro V-notching process has been used to manufacturing the safety component in Li-Ion battery. These kinds of safety component in Li-Ion battery plays an important role in the explosion from excessive overheating. Therefore, it is very crucial to estimate accurately the working pressure range of the safety component with micro V-notch. In this study, the relationship with the working internal pressure in Li-Ion battery and fracture phenomenon in micro V-notch was investigated through the numerical analysis. The numerical analysis is especially adopted the finite element method with ductile fracture criteria.

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A Review of Li-ion Battery Equivalent Circuit Models

  • Zhang, Xiaoqiang;Zhang, Weiping;Lei, Geyang
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.6
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    • pp.311-316
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    • 2016
  • Batteries are critical components of electric vehicles and energy storage systems. The connection of a battery to the power grid for charge and discharge greatly affects energy storage. Therefore, an accurate and easy-to-observe battery model should be established to achieve systematic design, simulation, and SOC (state of charge) estimations. In this review, several equivalent circuit models of representative significance are explained, and their respective advantages and disadvantages are compared to determine and outline their reasonable applications to Li-ion batteries. Numerous commonly used model parameter identification principles are summarized as well, and basic model verification methods are briefly introduced for the convenient use of such models.

Study on Optimization of Li-ion Battery Pack Design by RSM (RSM 방법에 의한 리튬이온 배터리 팩의 최적 설계)

  • Joo, Kangwo;Jang, Kyungmin;Kim, Kwang sun
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.39-43
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    • 2015
  • This paper is to derive information about the optimal shape of the pack has a minimum temperature range of a Li-ion battery equipped with a module. We selected the shape of the pack in order to reduce the temperature deviation between the batteries as a variable. And we derived the experimental points with a minimum of DOE by D-optimal. We analyzed the temperature and the flow within the battery pack by using a numerical analysis verified in previous studies. We derive the equation for the temperature variation in the objective function using the RSM and performed optimization. As a result, it was confirmed that with the variation in the $1.706e-4^{\circ}C$ when to apply an optimized shape.

Electrochemical Performance of Tricredyl Phosphate and Trispentafluorophenly Phosphine as Flame Retardant Additives for Lithium-ion Batteries (리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo;Nam, Sang-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.756-760
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    • 2007
  • Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.

Thermal and Electrochemical Studies of Tris(2,4,6-trimethoxyphenyl)Phosphine as a Flame Retardant Additive for Li-ion Battery (리튬이차전지 난연성 전해액 첨가제로서의 Tris(2,4,6-trimethoxyphenyl)Phosphine의 열적, 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1130-1134
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    • 2008
  • Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

Non-isolated Boost Charger for the Li-Ion Batteries Suitable for Fuel Cell Powered Laptop Computers

  • Sang, Nguyen Van;Choi, Woojin;Kim, Dae-Wook
    • Journal of Power Electronics
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    • v.13 no.1
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    • pp.31-39
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    • 2013
  • The conventional non-isolated boost converter has some drawbacks such as poor dynamic performance and a discontinuous output current, which make it unsuitable for battery charging applications. In spite of its compactness and lightness, it is not preferred as a charger of portable electronic devices. In this paper, a non-isolated boost converter topology for Li-ion batteries suitable for fuel cell powered laptop computers is proposed and analyzed. The proposed converter has an additional inductor at the output to make a continuous output current. This feature makes it suitable for charger applications by eliminating the disadvantages of the conventional non-isolated boost converter mentioned above. A prototype of the proposed converter is built for the Li-ion battery charger of a laptop computer to prove the validity and advantages of the proposed topology.

Analog-Digital Switching Mixed Mode Low Ripple - High Efficiency Li-Ion Battery Charger (아날로그 - 디지털 스위칭 혼합형 저 리플- 고 효율 Li-Ion 배터리 충전기)

  • Jung, Sang-Hwa;Woo, Young-Jin;Kim, Nam-In;Cho, Gyu-Hyeong
    • Proceedings of the KIEE Conference
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    • 2001.07d
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    • pp.2531-2533
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    • 2001
  • This paper describes a low noise and high efficiency analog-digital switching mixed mode battery charger for production facilities of Li-Ion batteries. The requirements for battery chargers for production facilities are very strict. The accuracy of output voltage and output current should be below 0.1% with very low ripple current. Therefore analog type linear regulators are widely used for battery charger in spite of their inefficiency and bulkiness. We combined linear regulator as a voltage source with digital switching converter as a dependent current source. Low current ripple and high accuracy are obtained by linear regulator while high efficiency is achieved by digital switching converter. Experimental results show that proposed method has 0.1% ripple and 90% efficiency at an output current of 1A for a battery voltage of 4V.

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