• Title/Summary/Keyword: Lee constant

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Correlation Between Cross Interaction Constant and Bond Length in the S$_N$2 Transition State

  • Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.179-182
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    • 1988
  • A simple correlation between cross interaction constants ${\rho}_{ij}$ and bond lengths in the transition state was obtained ; it has been shown that ${\rho}_{ij}$ corresponds to force constant of activation, which in turn is related to bond length by Badger's rule involving only universal constants. A satisfactory correlation between 4-31G ab initio calculated values of bond length and force constant for C-X streching in the transition state of the methyl transfer reaction, $X^-\;+\;CH_3X\;=\;XCH_3\;+\;X^-$, indicated that Badger's rule can be extended to bonds in the transition state. Independence of ${\rho}_{ij}$ values from the variable charge transmission of reaction centers has been demonstrated with nearly constant, experimentally determined I${\rho}$XYI values, and hence similar degree of bond formation, for various $S_N2$ reactions.

Research on Variable Constant Current Efficiency Measuring Device for Solar Panel to Reuse (태양광 패널 재사용을 위한 가변 정전류 기반의 효율 측정장치에 관한 연구)

  • Sang-Jin Woo;Dae-Heon Kim;Jae-Jin Lee;Oh-Min Kwon
    • IEMEK Journal of Embedded Systems and Applications
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    • v.18 no.1
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    • pp.9-17
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    • 2023
  • This paper relates to the development of a device for measuring the efficiency of a solar panel based on a variable constant current, and proposed a standard for reuse of the solar panel. By applying a variable constant current circuit to a solar panel efficiency measuring device, it was easy to apply a maximum power point tracking (MPPT) algorithm. In addition, a load dispersion method was applied to measure the efficiency of a high-capacity solar panel. and it is possible to solve a problematic thermal runaway during a MOSFET parallel operation by applying the load dispersion method. As a result of the experiment, the solar panel efficiency measuring device was able to accommodate a large solar panel of 350W, which is the maximum measurement goal. In this paper, the validity was confirmed through the 310W solar panel efficiency measurement experiment collected after removal.

Seismic Performance Evaluation of Reinforced Concrete Columns Under Constant and Varying Axial Forces (일정 및 변동 축력을 받는 철근콘크리트 기둥의 내진성능 평가)

  • Lee, Do Hyung
    • Journal of the Earthquake Engineering Society of Korea
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    • v.28 no.1
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    • pp.59-65
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    • 2024
  • This paper describes the seismic performance evaluation of reinforced concrete bridge columns under constant and varying axial forces. For this purpose, nine identical circular reinforced concrete columns were designed seismically by KIBSE (2021) and KCI (2021). A comparison of lateral forces with theoretical strength shows that the safety factor for columns under varying axial forces is less marginal than those under constant axial forces. In addition, columns under varying axial forces exhibit significant fluctuations in the hysteretic response due to continuously varying axial forces. This is particularly prominent when many varying axial force cycles within a specific lateral loading cycle increase. Moreover, the displacement ductility of columns under varying axial forces does not meet the code-specified required ductility in the range of varying axial forces. All varying axial forces affect columns' strength, stiffness, and displacement ductility. Therefore, axial force variation needs to be considered in the lateral strength evaluation of reinforced concrete bridge columns.

Design of a Track Guidance Algorithm for Formation Flight of UAVs (무인기의 편대비행을 위한 트랙유도 알고리즘 설계)

  • Lee, Dongwoo;Lee, Jaehyun;Kim, Seungkeun;Suk, Jinyoung
    • Journal of Institute of Control, Robotics and Systems
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    • v.20 no.12
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    • pp.1217-1224
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    • 2014
  • This paper presents a modified track guidance algorithm for formation flight of multiple UAVs. The suggested guidance algorithm is the spatial version of the first order dynamic characteristics for a time-dependent system so the algorithm is able to generate a path without overshoot to track the desired line. A crucial design parameter is a spatial constant that controls the shape of the convergence to an assigned flight path similarly to a time constant. Reference flight trajectories are designed based on a two-dimensional vehicle model, and the performance of the proposed guidance law is verified by numerical simulation using rigid body UAV dynamics with MATLAB/Simulink Aerosim Blockset.

Free Vibrations of Cantilever Arches with Constant Volume (일정체적 캔틸레버 아치의 자유진동)

  • Lee, Byoung-Koo;Lee, Tae-Eun;Yoon, Hee-Min
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.05a
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    • pp.1169-1172
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    • 2007
  • This paper deals with the free vibrations of cantilever arches with constant volume. Its cross-sectional shape is the regular polygon whose depth is varied with the linear functional fashion. The non-dimensional differential equations governing the free vibration of such arch are derived and solved numerically for calculating the natural frequencies. As the numerical results, the effects of arch parameters such as side number of cross section, section ratio and aspect ratio on the natural frequencies are reported in figures.

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The Microwave Dielectric Properties on Glass Frit Addition of Low Temperature Co-fired Ceramic (Glass Frit 첨가에 따른 LTCC용 마이크로파 유전체의 유전 특성)

  • Yoon, Jung-Rag;Lee, Serk-Won;Lee, Heon-Young;Kim, Jee-Gyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.611-615
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    • 2003
  • The crystalline and dielectric properties on $Al_2O_3$ filled glass frit ($CaO-Al_2O_3-SiO_2-MgO-B_2O_3$) with admixtures of $TiO_2$ have been investigated. The dielectric constant value of $7.5{\sim}7.8$, quality factor value of 700 were obtained for glass frit : $Al_2O_3$ (50 : 50 wt%) ceramics. As the amount of $TiO_2$ increased, temperature coefficient of dielectric constant were decreased.

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Microwave Dielectric Properties of 0.15BaO-$0.15Sm_2O_3-0.7TiO_2$ Ceramics (0.15BaO-$0.15Sm_2O_3-0.7TiO_2$ 세라믹스의 마이크로파 유전 특성)

  • Lee, Geun-Ill;Park, In-Gil;Lee, Young-Hie;Yoon, Seok-Jin
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.185-187
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    • 1993
  • 0.15BaO-$0.15Sm_2O_3-0.7TiO_2$, ceramics were fabricated by mixed-oxide method. Microwave dielectric properties were investigated with sintering temperature and annealing time. In the specimen sintered at 1350[$^{\circ}C$], dielectric constant, quality factor and temperature coefficient of resonant frequency had a good values of 80.19, 2006 (at 4.6851[GHz]), -27.54[ppm/$^{\circ}C$], respectively. Increasing the annealing time, dielectric constant was almost constant and quality factor was increased. Temperature coefficient of resonant frequency was minimum value (-1.28[ppm/$^{\circ}C$]) at 4 [hr] annealed.

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Time Optimal Performance of a Varying-Time Sharing Sequential Paired Thrusting Logic (순차적 가변시간할당 추력방식 최적성능 분석)

  • Oh, Hwa-Suk;Lee, Byung-Hoon;Lee, Bong-Un
    • Journal of Institute of Control, Robotics and Systems
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    • v.11 no.3
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    • pp.254-261
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    • 2005
  • Time-optimal performances are analyzed in the sense of inner loop. A varying-time sharing thrusting logic is suggested as a new sequential paired thrusting logic for fast maneuvers of satellites with coupled thruster configuration. Its time-optimal maneuvering performance is compared with two conventional thrusting logics: separate thrusting logic and constant-time sharing sequential paired thrusting logic. It is found that the newly suggested varying-time sharing thrusting logic can be easily implemented by adjusting the conventional constant-time logic with its thrust on-time, while it can reduce the maneuvering time enormously as much as the separate thrusting logic. The performance of the logic is simulated on the agile maneuvering spacecraft model KOMPSAT-II.

Design and Machining Precision Evaluation of Pneumatic Clamping Type Guide-bush System (공압식 소재물림 가이드부쉬 시스템의 설계 및 가공정도 평가)

  • Lee, Jae-Hoon;Yi, Su-Min;Park, Seong-Hun;Lee, Shi-Bok
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.19 no.6
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    • pp.859-866
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    • 2010
  • Generally, a fixed type guide-bush system is installed during machining miniature work-pieces with high precision in the multi-task CNC lathe. But a conventional guide-bush system does not provide a constant clamping force under the condition of varying work-piece diameters. It is important to maintain a constant clamping force for guaranteeing machining precision. This paper proposes a new guide-bush system with a pneumatic clamping device for the CNC Swiss-turn lathe to keep constant clamping force with changes in work-piece diameters. Through performance tests, new clamping system developed in the study showed better machining precision at the cost of a small increase in the temperature of the system than conventional systems due to an increase in the frictional heat and a change in the heat transfer route.

A Study on the Geometrically Nonlinear Analysis of Spatial Structures by Using Arc Length Method (호장법을 이용한 공간구조의 기하학적 비선형 해석에 관한 연구)

  • Han, Sang-Eul;Lee, Sang-Ju;Lee, Kyoung-Soo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2007.04a
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    • pp.381-386
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    • 2007
  • The present study is concerned with the application of Constant arc-length method that proposed by Crisfield in the investigation of the geometrically nonlinear behaviour of spatial structures composed by truss or beam element. The arc-length method can trace the full nonlinear equilibrium path of Spatial structure far beyond the critical point such as limit or bifurcation point. So, we have developed the constant arc-length method of Crisfield to analysis spatial structure. The finite element formulation is used to develop the 3d truss/beam element including the geometrical nonlinear effect. In an effort to evaluate the merits of the methods, extensive numerical studies were carried out on a number of selected structural systems. The advantages of Constant arc length method in tracing the post-buckling behavior of spatial structures, are demonstrated.

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