• Title/Summary/Keyword: Lee Sam

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7Li MAS NMR studies of Li4P2O7 and LiFePO4 materials (LiFePO4와 Li4P2O77Li MAS NMR 특성 연구)

  • Han, Doug-Young;Park, Nam-Sin;Lee, Sang-Hyuk;Lee, Hak-Man;Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.1
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    • pp.15-20
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    • 2011
  • [ $^7Li$ ]Magic Angle Spinning (MAS) NMR spectroscopy has been used to study the lithium local environments in $Li_4P_2O_7$ and$LiFePO_4$ materials. The purpose of this study was to know the structure of the solid electrolyte interphase (SEI) in lithium ion cells composed of $LiFePO_4$ as cathode material. $Li_4P_2O_7$ and $LiFePO_4$ were prepared by a solid-state reaction. The $^7Li$ MAS NMR experiments were carried out at variable temperatures in order to observe the local structure changes at the temperatures in $Li_4P_2O_7$ system. The $^7Li$ MAS NMR spectra of in $Li_4P_2O_7$ indicate that the lithium local environments in $Li_4P_2O_7$ were not changed in the temperature range between $27^{\circ}C$ and $97^{\circ}C$ Through this work, we confirmed that the small amount of $Li_4P_2O_7$ less than 5.0 wt% in $LiFePO_4$ could be clearly measured by the $^7Li$ MAS NMR spectroscopy at high spinning rate over than 11 kHz.

Characterizations of graded AlGaN epilayer grown by HVPE (HVPE 방법에 의해 성장된 graded AlGaN 에피층의 특성)

  • Lee, Chanbin;Jeon, Hunsoo;Lee, Chanmi;Jeon, Injun;Yang, Min;Yi, Sam Nyung;Ahn, Hyung Soo;Kim, Suck-Whan;Yu, Young Moon;Sawaki, Nobuhiko
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.2
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    • pp.45-50
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    • 2015
  • Compositionally graded AlGaN epilayer was grown by HVPE (hydride vapor phase epitaxy) on (0001) c-plane sapphire substrate. During the growth of graded AlGaN epilayer, the temperatures of source and the growth zone were set at $950^{\circ}C$ and $1145^{\circ}C$, respectively. The growth rate of graded AlGaN epilayer was about 100 nm/hour. The changing of Al contentes was investigated by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). From the result of atomic force microscope (AFM), the average of roughness in 2 inch substrate of graded AlGaN epilayer was a few nanometers scale. X-ray diffraction (XRD) with the result that the AlGaN (002) peak ($Al_{0.74}Ga_{0.26}N$) and AlN (002) peak were appeared. It seems that the graded AlGaN epilayer was successfully grown by the HVPE method. From these results, we expect to use of the graded AlGaN epilayer grown by HVPE for the application of electron and optical devices.

Design and fabrication of the MMIC frequency doubler for 29 GHz local oscillator application (29GHz 국부 발진 신호용 MMIC 주파수 체배기의 설계 및 제작)

  • Kim, Jin-Sung;Lee, Seong-Dae;Lee, Bok-Hyoung;Kim, Sung-Chan;Sul, Woo-Suk;Lim, Byeong-Ok;Kim, Sam-Dong;Park, Hyun-Chang;Park, Hyung-Moo;Rhee, Jin-Koo
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.38 no.11
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    • pp.63-70
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    • 2001
  • We demonstrate the MMIC (monolithic microwave integrated circuit) frequency doublers generating stable and low-cost 29 GHz local oscillator signals from 14.5 GHz input signals. These devices were designed and fabricated by using the M MIC integration process of $0.1\;{\mu}m$ gate-length PHEMTs (pseudomorphic high electron mobility transistors) and passive components. The measurements showed S11 or -9.2 dB at 145 GHz, S22 of -18.6 dG at 29 GHz and a minimum conversion loss of 18.2 dB at 14.5 GHz with an input power or 6 dBm. Fundamental signal of 14.5 GHz were suppressed below 15.2 dBe compared to the second harmonic signal at the output port, and the isolation characteristics of fundamental signal between the input and the output port were maintained above :i0 dB in the frequency range 10.5 GHz to 18.5 GHz. The chip size of the fabricated MMIC frequency doubler is $1.5{\times}2.2\;mm^2$.

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Design of A Microstrip Linear Tapered Slot Antenna (마이크로스트립 선형 테이퍼형 슬롯 안테나 설계)

  • Jang, Jae-Sam;Kim, Cheol-Bok;Lee, Ho-Sang;Jung, Young-Ho;Jo, Dong-Ki;Lee, Mun-Soo
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.45 no.5
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    • pp.40-45
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    • 2008
  • In this paper, a microstrip linear tapered slot antenna is designed. A tapered slot antenna(TSA) has many advantages such as low profile, low weight, easy fabrication, and compatibility with monolithic microwave integrated circuits(MMIC). In addition, it has demonstrated multi octave bandwidth, moderately high gain, and symmetrical E- and H-plane beam patterns. A feed network is implemented with transition between a microstrip and a slot line for the microstrip linear tapered slot antenna. The transition is consist of two sides. One side has a microstrip line, the other side has a slot line. The dimensions of the microstrip and slot line are ${\lambda}_m/4$ and ${\lambda}_s/4$ at the center of the cross section of the microstrip and slot line. In order to get broad bandwidth antenna characteristics, the tapered length is chosen as $4{\lambda}_o$ and termination width is chosen as $1.75{\lambda}_o$. Experimental results show that the microstrip tapered slot antenna has symmetrical E- and H-plane beam patterns with around 5GHz of bandwidth at center frequency of 5.0GHz.

Face Stability Assessment of Slurry-shield Tunnels - Concentrating on Slurry Clogging Effect - (슬러리 쉴드 터널의 막장 안정성 평가 - 슬러리의 폐색효과를 중심으로 -)

  • Lee, In-Mo;Lee, Sam;Cho, Kook-Hwan
    • Journal of the Korean Geotechnical Society
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    • v.20 no.6
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    • pp.95-107
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    • 2004
  • In this paper, the rheological characteristics of slurry used fur slurry-shield tunnels were studied with emphasis on penetration characteristics. The slurry penetration was modeled by soil-filter clogging theory. The coefficient of particle deposition was suggested as an indicator of sin clogging during tunnel construction and calculated through model tests. The measured slurry weight, clogged in the base soil, was compared with the value obtained from clogging theory. Based on the testing results, a stability analysis of a tunnel face was performed to pinpoint the most influential factor affecting stability of slurry-shield tunnels. It was found that the stability of tunnel face is dependent on the ratio of infiltration velocity to the coefficient of particle deposition, and the penetration distance of slurry increases with the ratio of infiltration velocity to the coefficient of particle deposition. Since the stability of tunnel face decreases with the slurry penetration distance, it was necessary to add some additives in order to reduce the slurry penetration distance. It was found that the ground condition needs additives when the soil has the effective particle diameter$(D_{10})$ larger than 0.75mm. It was also found that the tunnel face stability due to slurry penetration is significantly affected by the tunnel advance rate.

Evaluation of the Stability of Quay Wall under the Earthquake and Tsunami (지진 및 지진해일파 작용하의 해안안벽의 안정성평가)

  • Lee, Kwang-Ho;Ha, Sun-Wook;Lee, Kui-Seop;Kim, Do-Sam;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.27 no.3
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    • pp.41-54
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    • 2011
  • The present study analyzes the stability of waterfront quay wall under the combined action of earthquake and tsunami. Adopting the limit equilibrium method, the stability of waterfront quay wall is checked for both the sliding and overturning. Forces due to tsunami are compared with the proposed formula and the 3-D one-field Model for immiscible TWO-Phase flows (TWOPM-3D). Variations of the stability of wall are also proposed by the parametric study including tsunami water height, horizontal seismic acceleration coefficient, internal friction angle of soil, friction angle between the wall and the soil and the pore water pressure ratio. The present study about the stability of wall is also compared with the case when earthquake and tsunami are not considered. As a result, the result of numerical analysis about the tsunami force is similar to that of proposed formula. When earthquake and tsunami are simultaneously considered, the stability of wall in passive case significantly decreases and tsunami forces in active case are affected as a resistance force on the wall and so the stability of wall increases.

Experimental Investigations of Combination Effects of Installation Damage and Creep Deformation on Long-Term Design Strength of Geogrids (지오그리드의 장기설계인장강도에 미치는 시공시 손상 및 크리프 변형 복합효과에 대한 실험적 평가)

  • Cho, Sam-Deok;Lee, Kwang-Wu;Oh, Se-Yong;Lee, Do-Hee
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.4
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    • pp.23-37
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    • 2005
  • The factors affecting the long-term design strength of geogrid can be classified into factors on creep deformation, installation damage, temperature, chemical degradation and biological degradation. Especially, creep deformation and installation damage are considered as main factors to determine the long-term design strength of geogrid. Current practice in the design of a reinforced soil structures is to calculate the long-term design strength of a geosynthetic reinforcement damaged during installation by multiplying the two partial safety factors, $RF_{ID}$ and $RF_{CR}$. This method assumes that there is no evaluation of synergy effect between installation damage and creep deformation of geogrids. This paper describes the results of a series of experimental study, which are carried out to assess the combined effect of the installation damage and the creep deformation for the long-term design strength of geogrid reinforcements. A series of field tests was carried out to assess installation damage of various geogrids with respect to different fill materials, and then creep tests are conducted to evaluate the creep deformation of both undamaged and damaged geogrids. The results indicated that the tensile strength reduction factors, RF, considering the combined effect between the installation damage and the creep deformation is less than that calculated by the current design method.

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The Effects of Dietary Interventions on mRNA Expression of Peroxisome Proliferator Activated Receptor Isoforms (PPAR Isoforms) in Rat Skeletal Muscle (장기간의 고지방 식이 섭취가 골격근 내 PPAR Isoforms 유전자 발현에 미치는 영향)

  • Lee, Jang-Kyu;Kim, Jung-Kyu;Moon, Hee-Won;Shin, Young-Oh;Lee, Jong-Sam
    • Journal of Nutrition and Health
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    • v.40 no.3
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    • pp.221-228
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    • 2007
  • We determined the effects of dietary manipulations on messenger RNA of peroxisome proliferators activated receptor isoforms (i.e., PPAR ${\alpha},\;{\beta}/{\delta},\;{\gamma}$) in red vastus lateralis muscle of rats. Total 16 male Sprague-Dawley rats were used, and animals were divided into one of two dietary conditions: either chow diet group (CHOW; n=8) in which animals were 134 with standard rodent chow (61.8% carbohydrate, 15.7% fat, 22.5% protein) or high fat diet group (FAT n=8) in which animals were fed 24.3% carbohydrate, 52.8% fat, 22.9% protein. At the end of the 8 weeks of experimental period, red vastus lateralis muscle was dissected out from all animals, and PPAR ${\alpha},\;{\beta}/{\delta},\;{\gamma}$ mRNA expression was determined. There was no significant difference in body mass (BM) between CHOW and FAT. As expected, blood glucose and free fatty acid (FFA) concentration was higher in FAT than CHOW (p<0.05), and lactate concentration was significantly lower in FAT compared to CHOW (p<0.05). Insulin concentration tended to higher in FAT than CHOW ($67.2{\pm}21.9\;vs.\;27.0{\pm}5.2$ pmol/L), but it did not reach to the statistical significance. Gene expression of PPAR ${\alpha}$ was not significantly different between CHOW and FAT. It was not also significantly different in PPAR ${\beta}/{\delta}$. Interestingly, expression of mRNA in PPAR ${\gamma}$ however, was markedly depressed in FAT compared to CHOW (approximately 3 fold higher in CHOW; p<0.05). Results obtained from present study implies that PPAR ${\gamma}$ (as compensatory function of PPAR ${\alpha}$ is expressed) possibly exerts another major tuning roles in fatty acid transport, utilization, as well as biosynthesis in skeletal muscle cells. The situations and conditions that can be postulated for this implication need to be further examined.

Characterization and Fermentation Characteristics of Lactic Acid Bacteria Isolated from Soybean Curd Residue (Biji) (비지에서 분리된 젖산균의 동정 및 발효특성)

  • Baek, Joseph;Lee, In-Seon;Lee, Sam-Pin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.4
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    • pp.583-588
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    • 2002
  • Two microorganisms isolated from soybean curd residue (biji) were identified as Enterococcus faecium (51% homology) and Lactobacillus rhamnosus (99.5% homology) by using gram positive identification (GPI) card and API 50 CHL kit, respectively. Ent. faecium grew well in micronized full-fat soyflour (MFS) milk, indicating pH 4.9, 0.38% acidity and 1.8$\times$10$^{9}$ CFU/$m\ell$ of viable cell counts after fermentation for 20 hr. L. rhamnosus LL showed pH 6.5 and 4.6$\times$10$^{8}$ CFU/$m\ell$ viable cell counts, but enhanced acid production in MFS milk mixture fortified with skim milk or by the addition of 1% of glucose and lactose. On the other hand, Ent. faecium LL did not show increased acid production in MFS/skim milk and MFS milk fortified with sugar. The MFS/skim milk fermented by L. rhmnosus LS and Ent. faecium LL showed 600 mg% and 350 mg% lactic acid, respectively.

Effects of Antiseptics on the Protein Change of Plasma Membrane in various Fungal Cells (진균류의 원형질막 단백질 변화에 미치는 식품보존제의 영향)

  • Lee, Hak-Mi;Lee, Chong-Sam
    • The Korean Journal of Mycology
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    • v.26 no.4 s.87
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    • pp.551-561
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    • 1998
  • Plasma membrane from the fungal cells (Aspergillus phoenicis, Rhizopus acidus, Candida albicans) treated with sodium benzoate (S.B), potassium sorbate (P.S) and calcium propionate (C.P) during the cultivation were separated. The contents and patterns of plasma membrane proteins compared with those of the control. The growth of A. phoenicis was decreased by the average 64.0% in the S.B treatment. That of R. acidus was inhibited by the average 69.0% in the P.S treatment. Also, That of C. albicans was showed the deminution of the average 59.5% in the S.B treatment. The contents of protein involved in the plasma membrane of the each fungal cells were inhibited the average 41.0%, 41.7% and 59.5% in the S.B treatment, respectively. In case of A. phoenicis, the changes in the protein pattern involved in the plasma membraneshowed the aspect similar to the control on the 1st day and 2nd day of cultivation in the treatment group, but $116\;KD{\sim}97\;KD$ band almost disappeared in the 5th day of cultivation, and $45\;KD{\sim}29\;KD$ band was uncleared through the cultivation. In S.B treatment group R. acidus was showed the loss of $116\;KD{\sim}97\;KD$ band from the middle stage of cultivation and P.S, and C.P treatment group were started the loss at the early stage and completely lost at the 36 hours of cultivation. In C. albicans, $116\;KD{\sim}97\;KD$ band were started the loss at the early stage to compare with the control and $66\;KD{\sim}45\;KD$ band were dimmed at the 96 hours of cultivation. Especially, the C.P treatment group were perfectly lost at the 96 hours of cultivation.

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