• 보존과학연구
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• s.36
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• pp.4-10
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• 2015

This paper confirms characteristics of lead isotopes of bronze artifacts excavated from Korea peninsula using 673 data classified according to Age, type and region. Lead isotopes data in Early iron ages are distributed in the southern Korean peninsula, but data in Joseon ages are concentrated in zone 3. Also Bronze artifacts excavated from Seoul, Gyeonggi, Chungcheong, Jeolla and Gyeonsang are manufactured using raw materials of the entire Korea peninsula, but bronzes excavated from North Korea aren't produced using raw materials of Gyeonsang provinces. Lead isotopes data will be able to find moving routes of raw materials and to separate the period of mixing and recycling of lead.

• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.187-193
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• 2015

The purpose of the present study is to trace the provenance of lead raw materials using the lead isotope ratio of 9 lead glasses excavated from the Sarira hole of Mireuksaji stone pagoda and to determine correlation between them and other lead glasses excavated from the Wanggungri site. The results of chemical analysis of the 9 lead glasses show that they are common lead glass system($PbO-SiO_2$) with respect to the contents of PbO (70 wt.%) and $SiO_2$ (30 wt.%). The lead isotope ratios of them plot to northern Korean peninsula when applied to the distribution map of lead isotopes of East Asia. On the other hand, southern Korean peninsula is verified as the main deposits of the lead ore in the distribution map of lead isotopes of South Korea. With respect to the results, it is notable that the provenance of the 9 lead glasses can be very different depending on the distribution map. In addition, a comparative study between them and the lead glasses excavated from the Wanggungri which was built in the same region and period shows that their lead isotopes are highly correlated.

• Nuclear Engineering and Technology
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• v.54 no.11
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• pp.4022-4029
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• 2022

We investigated the possibility of using graphene for control of hydrogen isotopes by exploring adsorption, reflection, and penetration of hydrogen isotopes on graphene using molecular dynamics. Reflection is the dominant interaction when hydrogen isotopes have low incident energy. Adsorption rates increase with increasing incident energy until 5 eV is reached. After 5 eV, adsorption rates decrease as incident energy increases. At incident energies greater than 5 eV, adsorption rates increase with the number of graphene layers. At low incident energies (<1 eV), no isotopic effects on interactions are observed since the predominant interaction is derived from the force of π electrons. Between 1 eV and 50 eV, heavier isotopes exhibit higher adsorption rates and lower reflection rates than lighter isotopes, due to the greater momentum of heavier isotopes. Adsorption rates are consistently higher when the incident angle of the impacting atoms is smaller between 0.5 eV and 5 eV. At higher energies (>5 eV), larger incident angles lead to higher reflection and lower penetration rates. At high incident energies (>5 eV), crumpled graphene has higher adsorption and lower penetration rates than wrinkled or unwrinkled graphene. The results obtained in this research study will be used to develop novel nanomaterials that can be employed for tritium control.

• Korean Journal of Heritage: History & Science
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• v.49 no.3
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• pp.4-11
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• 2016

This study compares eight bronze spoons in the Goryeo Dynasty and analyzes their components and lead isotopes in order to confirm the relationship between their production sites and excavation sites. Most of the excavated spoons have elliptical heads, and their handles are categorized into two types. Bronze spoons are made of binary Cu-Sn alloys, but Pb is not added. The same artifacts can have different trace elements depending on location, and the spoons had high Ag content. According to an analysis of their lead isotopic ratio, they were made with raw materials produced in Zone 3 of the South Korean galena map. If the data of the trace elements in the raw ores of the bronze is accumulated, it can be used to indicate the provenance of the artifacts.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.3
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• pp.174-182
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• 2011

The present study evaluated the major lead sources in a steel metallurgy industrialized city by measuring lead isotopes/lead concentrations of ambient air and potential sources in an industrial area and residential areas according to relative distance. The quality control program obtained during the measurement procedure for lead isotopes and concentrations exhibited $0.5ng/m^3$ for method detection limit, more than 90% for recoveries of standard particulate matters, and lower than 0.2% for reproducibility errors of four lead isotopes ($^{204}Pb$, $^{206}Pb$, $^{207}Pb$, $^{208}Pb$). For all three lead isotope ratios ($^{206}Pb/^{204}Pb$, $^{207}Pb/^{206}Pb$, $^{208}Pb/^{206}Pb$), the ratios were obtained in the industrial area were closer to nearby residential area than those of a residential area far away from the industrial area, thereby suggesting that lead sources were more similar each other in the industrial and nearby residential area. Furthermore, for both summer and winter seasons ambient lead concentrations were more than four times higher in the industrial area than in the residential areas and in turn, they were higher in the nearby residential area compared with the far-away residential area. As a result, it was suggested that lead emitted from the industrial area would influence more the ambient lead in the nearby residential area than the far-away residential area. Both slag and traffic emissions are likely to be major lead sources in the industrial and nearby residential areas, since their three lead isotope ratios ($^{206}Pb/^{204}Pb$, $^{207}Pb/^{206}Pb$, $^{208}Pb/^{206}Pb$) were similar to the ratios obtained from ambient air of these two areas. In addition, the lead isotope ratios revealed different pattern between seasons, and the ambient lead concentrations were higher for winter than for summer.

• Economic and Environmental Geology
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• v.38 no.2 s.171
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• pp.129-134
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• 2005

The $^{87}Sr/^{86}Sr$ ratios between water and biogenic material are similar in marine and lacustrine environment. Pb isotope ratios we, however, reported not to have been corresponding between the biological tissues and ambient water in aquatic system, contrary to the Sr isotope ratios. In order to explore the potential application of two isotopes as environmental tracers, we report here the isotopic compositions of strontium and lead of gastropod shell in fresh water in Jinan area. The $^{87}Sr/^{86}Sr$ ratios of carbonate shells of gastropod living in fresh stream water, are similar as that of ambient water but are different by sites. The different $^{87}Sr/^{86}Sr$ ratios of stream water between the sites is likely caused by the difference of the isotopic composition of Sr derived form rocks in the basin. In contrast, there is a distinct difference of the lead isotopic values between the water and the gastropod shell, suggesting that shell-fish available lead in aquatic system is different from dissolved lead in water. It is assumed that the majority of Pb in stream water is derived from atmospheric Pb accumulated on soil materials over years rather than from rock.

• Economic and Environmental Geology
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• v.57 no.3
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• pp.343-352
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• 2024

Composition analysis and lead isotope ratio analysis were conducted to determine the coloring machanism on lead glaze used in Gyeongbokgung Palace and the provenance of the lead used as a flux. 31 blue tiles were classified into green, blue, and yellow. The chemical analysis of lead glazes on the blue tiles revealed that Pb, Si, and Cu were the main components, and trace amounts of Fe, Ca, Mg, and Al were detected. The Cu content was high in blue lead glaze, while Cu was not detected in yellow or brown lead glaze which instead had high Fe content. Therefore, it was found that lead was used as a flux and copper oxide as a coloring agent in the production of lead glaze. In addition, the lead isotope ratios of the lead glaze used in the blue tiles of Gyeongbokgung palace were plotted in zone 3 on the distribution map of lead isotope ratios on the Korean Peninsula, which includes Chungcheong-do and Jeolla-do. It is presumed that the flux for the lead glaze was sourced from galena found in these regions. The lead isotope ratios of the green glaze from the Three Kingdoms and Unified Silla period were mostly located outside the Korean Peninsula, showing that the provenance of lead had changed. In particular, the lead isotope ratios of the green glaze from the Three Kingdoms and Unified Silla period suggest exchange with neighboring countries. Also the lead isotope ratios of the green glazes from the same temple are different, so it is believed that they were made at different times or in different workshops.

• Proceedings of the Optical Society of Korea Conference
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• 2003.07a
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• pp.174-175
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• 2003

안정 동위원소는 원자력, 정밀전자, 제약 및 의료 분야 등에서 다양하게 사용되고 있다(그림1 참고). 원자로의 핵반응 조절을 위해 chemical shim으로 사용되는 B-10과 low activation 내부식성 재료인 감손 아연(Zn depleted in Zn-64)은 원자력 분야에서 사용되는 대표적인 안정 동위원소이다. 정밀 전자 분야에서 low alpha lead (LAL： Pb-210이 제거된 납)는 고집적 반도체 패킹 시 soft error를 줄이는 솔더 물질로 사용되고 있고, Si-28 은 열전도도가 높은 새로운 반도체 소재로 부각되고 있다. (중략)

• Nuclear Engineering and Technology
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• v.56 no.6
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• pp.2317-2323
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• 2024

Medical linear accelerators with an energy of 8 MV or higher are radiated owing to photonuclear reactions and neutron capture reactions. It is necessary to quantitatively evaluate the concentration of radioactive isotopes when replacing or disposing them. HPGe detectors are commonly used to identify isotopes and measure radioactivity. However, because the detection efficiency is generally calibrated using a standard material with a density of 1.0 g/cm³, a self-absorption effect occurs if the density of the measured material is high. In this study, self-absorption correction factors were calculated for tungsten, lead, copper, and SUS-303, which are the main materials of medical linear accelerator head parts, for each gamma-ray energy using MCNP 6.2 code. The self-absorption effect was more pronounced as the energy of the emitted gamma rays decreased and the density of the measured materials increased. These correction factors were applied to the radioactivity measurements of the in-built and portable HPGe detectors. Furthermore, compared to the surface dose rate measured by the survey meter, the accuracy of the measurements of radioactivity improved by an average of 124.31 and 100.53 % for inbuilt and portable HPGe detectors, respectively. The results showed a good agreement, with an average difference of 3.70 and 5.24 %.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.219-226
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• 2021

We examined component analysis and lead isotope ratio analysis to find out the relationship between the excavation and the production site of 25 bronze weapons from prehistoric ages. All 25 bronze weapons are ternary alloys of copper-tin-lead and lead is artificially added. The lead isotope ratios of 25 bronze weapons show that bronze are made by raw materials in the southern regions of the Korean Peninsula, including northern China. The raw materials of narrow-shaped bronze dagger are supplied in zone 1-3 and northern China. In addition, provenance of lead for bronze halberd and pearhead are the rest of the region except for zone 1 and zone 4. Silver are enriched in most samples and zinc and cobalt are deficient. Arsenic and antimony detected only specific samples and can be used as critical parameter for provenance study. Lead isotopes and trace elements of archaeological bronzes will provide conservation scientist with useful tool to study the provenance of raw materials