• Title/Summary/Keyword: Lead dioxide

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Development of Fast-Response Portable NDIR Analyzer Using Semiconductor Devices

  • Kim, Woo-Seok;Lee, Jong-Hwa;Park, Young-Moo;Yoo, Jai-Suk;Park, Kyoung-Seok
    • Journal of Mechanical Science and Technology
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    • v.17 no.12
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    • pp.2099-2106
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    • 2003
  • In this paper, a novel fast response NDIR analyzer (FRNDIR), which uses an electrically pulsed semiconductor emitter and dual type PbSe detector for the PPM-level detection of carbon dioxide (CO$_2$) at a wavelength of 4.28 $\mu\textrm{m}$, is described. Modulation of conventional NDIR energy typically occurs at 1 to 20 Hz. To achieve real time high-speed measurement, the new analyzer employs a semiconductor light emitter that can be modulated by electrical chopping. Updated measurements are obtained every one millisecond. The detector has two independent lead selenide (PbSe) with IR band pass filters. Both the emitter accuracy and the detector sensitivity are increased by thermoelectric cooling of up to -20 degrees C in all semiconductor devices. Here we report the use of semiconductor devices to achieve improved performance such that these devices have potential application to CO$_2$ gas measurement and, in particular, the measurement of fast response CO$_2$ concentration at millisecond level.

Sulfur Dioxide, Heavy Metal and Curcumin Contents in Market-Available Turmeric (Curcuma longa L.) (유통 강황의 이산화황, 중금속 및 쿠르쿠민 함량)

  • Lee, Young Ju;Kim, Ae Kyung;Kim, Ouk Hee;Lee, Chun Young;Lee, Hyun Kyung;Jung, Sun Ok;Lee, Sae Ram;Kim, Hee Sun;Kim, Il Young;Yu, In Sil;Jung, Kweon
    • Korean Journal of Medicinal Crop Science
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    • v.24 no.2
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    • pp.121-128
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    • 2016
  • Background: Turmeric (Curcuma longa L.) that is used as a food material has antioxidant, anticancer and anti-inflammatory properties. Recently the demand for functional foods and drugs has increased. The present study was carried out to determined of contents of residual sulfur dioxide, heavy metals, ash, acid insoluble ash and curcuminoids in turmeric from the Seoul Yak-ryeong market. Methods and Results: A total of 31 samples were obtained. Residual sulfur dioxide was not detected in any samples. Heavy metals (arsenic, cadmium, lead and mercury) were analyzed by ICP-MS (Inductively Coupled Plasma Mass Spectrometer) and a mercury analyzer and were detected in the ranges of 0.00 - 0.28, 0.00 - 0.07, 0.00 - 0.29 and 0.002 - 0.027mg/g respectively. No significant difference were observed between the average heavy metal contents of domestic and imported tumeric. However, average content of ash in domestic samples (7.8%) were significantly higher than that in imported samples (6.1%), whereas that of curcuminoids was significantly higher in imported samples (47.6mg/g) than in domestic samples (11.2mg/g). The average content of acid insoluble ash was not significantly different between two sample types (0.9% in each). Conclusions: There are no specific standards for turmeric used as food materials. Therefore, this study can be provided as basic data for the establishment of quality standards for turmeric.

Heuristic based Energy-aware Resource Allocation by Dynamic Consolidation of Virtual Machines in Cloud Data Center

  • Sabbir Hasan, Md.;Huh, Eui-Nam
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.8
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    • pp.1825-1842
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    • 2013
  • Rapid growth of the IT industry has led to significant energy consumption in the last decade. Data centers swallow an enormous amount of electrical energy and have high operating costs and carbon dioxide excretions. In response to this, the dynamic consolidation of virtual machines (VMs) allows for efficient resource management and reduces power consumption through the live migration of VMs in the hosts. Moreover, each client typically has a service level agreement (SLA), this leads to stipulations in dealing with energy-performance trade-offs, as aggressive consolidation may lead to performance degradation beyond the negotiation. In this paper we propose a heuristic based resource allocation of VM selection and a VM allocation approach that aims to minimize the total energy consumption and operating costs while meeting the client-level SLA. Our experiment results demonstrate significant enhancements in cloud providers' profit and energy savings while improving the SLA at a certain level.

Feasibility Study of IAQ Enhancement by Visible Light Photocatalyst (가시광 응답형 광촉매 제조와 이를 활용한 실내공기환경 개선 적용 타당성 조사)

  • Lee, Tai-Kyu;Yoon, Woo-Sug;Kim, Dong-Hyung;Hwang, Chul-Soon;Lim, Ji-Hun;Yoon, Jung-Ho;Kim, Young-mi
    • KIEAE Journal
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    • v.4 no.2
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    • pp.37-40
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    • 2004
  • New visible photocatalyst(Nanovis$^{(R)}$) has been synthesized to overcome the barrier of limitation of UV light utilization of current $TiO_2$ photocatalyst. It was found that red shift of absorption spectrum to 550nm was achieved. Its physical properties were characterized by XRD, BET and TEM. It is also observed that Nanovis$^{(R)}$ has a photocatalytic activity for photodegradation of Trichloroethylene under visible light irradiation. V,VII group doped into substitutional sites of $TiO_2$ has proven to be indispensable for band-gap narrowing and photocatalytic activity. These test results lead us to conclude that Nanovis$^{(R)}$ can be used for IAQ improvemen and for photocatalytic water splitting to hydrogen.

Titanium dioxide by spray deposition for buried contact silicon solar cells fabrication (전극함몰형 실리콘 태양전지의 제작시 스프레이 방법에 의한 타이타늄 옥사이드층의 적용에 관한 연구)

  • A.U. Ebong;S.H. Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.2
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    • pp.263-274
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    • 1996
  • Titanium dioxide ($TiO_{2}$) film has been widely used as anti-reflection coating for solar cells but not as masking oxide for metallisation and diffusion of impurities. In this paper we have investigated the properties of $TiO_{2}$ for possible incorporation into solar cell processing sequence. Thus the use of a spray deposition system to form the $TiO_{2}$ film and the characterisation of this film to ascertain its suitability to solar cell processing. The spray-on $TiO_{2}$ film was found to be resistant to all the chemicals used in conjunction with solar cell processing. The high temperature anealing (in oxygen ambient) of the spray-on $TiO_{2}$ film resulted in an increased refractive index, which indicated the growth of an underlying thin film of $SiO_{2}$ film for the passivation of silicon surface which would reduce the recombination activities of the fabricated device. Most importantly, the successful incorporation of the $TiO{2}$ film will lead to the reduction of the many high temperature processing steps of solar cell to only one.

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Fundamental Characteristics of CO2-cured Mortar with Varied Rates of Blast Furnace Slag Fine Powder Substitution (고로슬래그 미분말 치환율에 따른 이산화탄소 양생 모르타르의 기초 물성)

  • Ryu, Ji-Su;Jang, Kyung-Su;Na, Hyeong-Won;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.1
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    • pp.11-21
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    • 2024
  • This research elucidates the fundamental properties of carbon dioxide (CO2)-cured mortar as influenced by varying substitution rates of blast furnace slag fine powder. The findings indicate that CO2 curing enhances the formation of calcium carbonate (CaCO3), contributing to pore reduction and the early development of strength. While calcium hydroxide (Ca(OH)2) plays a more pivotal role in the primary development of strength compared to CaCO3, an increase in the substitution rate of blast furnace slag fine powder results in reduced production of Ca(OH)2. Nonetheless, the maintenance of strength through CaCO3 formation is observed even after the depletion of Ca(OH)2, suggesting that the required performance can be sustained post-exposure to the atmosphere following CO2 curing. It is noted that substitution rates exceeding 50% lead to performance deterioration due to CO2, highlighting the necessity for careful adjustment of the substitution ratio.

Effects of Electrodeposition Parameters on Electrochemical Hydroxyl Radical Evolution of PbO2 Electrode (이산화납 전극 제조 시 전기화학적 증착인자가 수산화라디칼 발생에 미치는 영향)

  • Shim, Soojin;Yoon, Jeyong
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.12
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    • pp.647-655
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    • 2016
  • Lead dioxide ($PbO_2$) is an electrode material that is effective for organic pollutant degradation based on hydroxyl radical ($^{\bullet}OH$) attack. Representative parameters for $PbO_2$ electrodeposition are summarized to current, temperature, reaction time, concentration of Pb(II) and electrolyte agent. In this study, $Ti/PbO_2$ electrodes were fabricated by electrodeposition method under controlled reaction time, current density, temperature, concentration of $HNO_3$ electrolyte. Effects of deposition parameters on $^{\bullet}OH$ evolution were investigated in terms of electrochemical bleaching of p-Nitrosodimethylaniline (RNO). As major results, the $^{\bullet}OH$ evolution was promoted at the $PbO_2$ that was deposited in longer reaction time (1-90 min), lower current density ($0.5-50mA/cm^2$), higher temperature ($5-65^{\circ}C$) and lower $HNO_3$ concentration (0.01-1.0 M). Especially, the $PbO_2$ which was deposited in 0.01 M of lowest $HNO_3$ concentration by applying $20mA/cm^2$ for above 10 min was most effective on $^{\bullet}OH$ evolution. The performance gap between $PbO_2$s that was best and worst in $^{\bullet}OH$ evolution was about 41%. Among the properties of $PbO_2$ related on $^{\bullet}OH$ evolution performance, conductivity of $Ti/PbO_2$ significantly influenced on $^{\bullet}OH$ evolution. The increase in conductivity promoted $^{\bullet}OH$ evolution. In addition, the increase in crystal size of $PbO_2$ interfered $^{\bullet}OH$ evolution at surface of some $PbO_2$ deposits.

Investigation into Air Pollution in Car Shipping Workshop in Pyeongtaek Port (자동차 선적작업장의 공기오염 실태조사)

  • Kim, Ji-Ho;Won, Jong-Uk;Kim, Chi-Nyon;Roh, Jaehoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.1
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    • pp.44-53
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    • 2006
  • This study purposed to investigate air pollution in car shipping yards and, for this purpose, we selected an outdoor open-air yard and an indoor ramp into the ship and measured the concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10, PM2.5 and heavy metals in the air. The results of this study are as follows. No significant difference was observed in temperature and humidity between the outdoor and indoor workshop, and the average air flow was 0.52 m/s in the indoor workshop, which is higher than 0.19 m/s in the outdoor workshop(p<0.01). The average concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10 and PM2.5 according to workplace were 0.03 ppm(${\pm}0.01$), 0.03 ppm(${\pm}0.01$), 0.46 ppm(${\pm}0.22$), $39.44{\mu}g/m^3$(${\pm}2.45$) and $5.45{\mu}g/m^3$(${\pm}1.15$) respectively in the outdoor workshop, and 0.15 ppm(${\pm}0.05$), 0.22 ppm(${\pm}0.06$), 8.85 ppm(${\pm}3.35$), $236.39{\mu}g/m^3$(${\pm}58.21$) and $152.43{\mu}g/m^3$(${\pm}35.42$) respectively in the indoor workshop. Thus, the concentrations of gaseous substances in the indoor workshop were 4.9-19.2 times higher than those in the outdoor workshop, and the concentrations of fine dusts were 5.9-27.9 times higher(p<0.01). In addition, according to the result of investigating pollutant concentrations according to displacement and the number of car loaded when shipping gasoline cars into the ship, no significant relation between the number of cars loaded and pollutants was observed in shipping passenger cars, but the concentrations of nitrogen dioxide and carbon monoxide got somewhat higher with the increase of the number of cars loaded(p<0.05). In addition, the concentrations of nitrogen dioxide, carbon monoxide, PM10 and PM2.5 in the air were significantly higher when shipping recreational vehicles, the displacement of which is larger than passenger cars, than when shipping passenger cars(p<0.01). On the other hand, the average heavy metal concentrations of the air in indoor workshop were: lead $-0.05{\mu}g/m^3$(${\pm}0.10$); chromium $-0.90{\mu}g/m^3$(${\pm}0.18$); zinc $-0.38{\mu}g/m^3$(${\pm}0.24$); copper $-0.18{\mu}g/m^3$(${\pm}0.22$); and manganese and cadmium not detected. In addition, the complaining rates of 'asthma,' a major symptom of chronic respiratory diseases, were 18.5% and 22.5% respectively in indoor workers and outdoor workers. Thus the rate was somewhat higher in indoor workers but the difference was not statistically significant. The complaining rates of 'chronic cough' and 'chronic phlegm' were very low and little different between indoor and outdoor workers. The results of this study show that the reason for the higher air pollution in indoor than in outdoor workshop is incomplete combustion of fuel due to sudden start and over-speed when cars are driven inside the ship. In order to prevent high air pollution, efficient management measures should be taken including the observance of the optimal speed, the improvement of old ships and the installation of efficient ventilation system.

Effect of Sulfur Dioxide and Hydrogen Fluoride on Rice Plant Growth in Industrial Estate (공업단지 주변에서의 아황산가스 및 불화수소가 수도 생육에 미치는 영향)

  • Wan Cheol, Park;Kwang-Ho Kim;Ki Joon, Kim
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.1
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    • pp.17-21
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    • 1991
  • The study was performed to investigate the effects of gaseous emission of sulfur dioxide and hydrogen fluoride on the growth of rice plant under stressed field conditions. This study is specifically dealt with multiple effects of sulfur dioxide and hydrogen fluoride on various plant growth indicators such as leaf damage, weight of grain, panicles per hill, spikelets per panicle and percent fertility. It appears that there is a good correlation between ambient concentrations of sulfur oxides and sulfur contents found in leaves with an average correlation coefficient of 0.868 within a 1% significance level. A better multiple correlation was found between percent leaf damage and sulfur and fluorine contents found in leaf with a significance of 1% level. The correlation coefficient ranges from 0.807 to 0.978 with an average being 0.922. An evaluation of data observed has demonstrated that both panicles per hill and percent fertility are significantly affected by air pollutants. As expected, hydrogen fluorides have more effects than sulfur oxides. It is, however, interesting to note that spikelets per panicle has slightly been affected while no indication of effects on l000-grain weight has been observed. This may lead to a conclusion that a reduction in yield of rice under polluted field conditions may have more been caused by the diminution panicles per hill and percent fertility rather than by the diminution of spikelets per panicle and grain weight.

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Performance Evaluation of Nitrogen Oxide Removal by Air Purification Blocks with Titanium Dioxide (이산화티타늄을 이용한 대기정화 블록의 질소산화물 제거 성능 평가)

  • Oh, Ri-On;Kim, Hwang-Hee;Park, Sung-Ki;Cha, Sang-Sun;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.5
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    • pp.39-46
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    • 2020
  • This study evaluated the nitrogen oxide (NOx) removal efficiency by air purification concrete blocks with titanium dioxide (TiO2). The concrete in the mixtures had a 30% water:cement ratio, to which TiO2 was added at 0%, 5%, and 10% of cement weight. The compressive strength reduction rate and removal efficiency of NOx were investigated. The result of the compressive strength test in the study indicated that addition rate of TiO2 did not lead to signifcant effect. In terms of the average removal efficiency of NOx, mix No. 1 using a TiO2 mixing ratio of 0% had a removal efficiency of 0.57% on average; thus, the removal effect w as not significant. For the other samples prepared by mixing, the average removal efficiencies for mix No. 2 (5% TiO2) were 58.86% and 62.05% for normal and washing surface treatments, respectively, and those of sample No. 3 (10% TiO2) were 59.94% and 67.61%. mixs No. 4 (5%) and No. 5 (10%), in which TiO2 diluted with distilled water was sprayed onto the block surface, had an average NOx removal efficiency of 61.72% and 68.48%, respectively. In terms of NOx removal efficiency, Mixs No. 3 and No. 5 with 10% TiO2 were better than Mixs No. 2 and No. 4 with 5% TiO2. In addition, analyzing the NOx removal efficiency results from the fixing method, it was capable to apply mixing (washing) and the diluted spray methods. Therefore, it was found that the diluted spray method applied in this study can be employed in any manufacture of air purification concrete blocks.