• Title/Summary/Keyword: Lead Ion

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Studies on Cd, Pb, Hg and Cr Values in Dog Hairs from Urban Korea

  • Park, S.H.;Lee, M.H.;Kim, S.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.8
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    • pp.1135-1140
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    • 2005
  • Dogs are a very good indicator of the pollution load on the environment. They share people's environment and are exposed to the action of the same pollutants. This study was to estimate the heavy metal contents in dog hairs in domestic districts, and to assess effects of age, sex, feed habits, living area, breeding environment and smoking habit of owner. The mean concentrations of heavy metals in 204 samples were 0.09${\pm}$0.10 ${\mu}g$/g, 0.21${\pm}$0.09 ${\mu}g$/g, 0.82${\pm}$0.09 ${\mu}g$/g and 0.48${\pm}$0.07 ${\mu}g$/g (Cadmium (Cd), Mercury (Hg), Lead (Pb) and Chromium (Cr)) in dog hairs, respectively. Concentrations of Pb, Cd, Hg and Cr in dog hairs in Yeongnam including Ulsan and Seoul, were higher than in Chungchong and Honam, and concentrations of Pb were significantly different (p<0.01). Concentrations of Cd, Hg, Pb and Cr in dog hairs increased with age (p<0.05). Only dogs fed commercial pet foods had significantly higher Cd and Cr concentrations in hairs than dogs fed dog feed and human diet (p<0.01 in Cd and p<0.05 in Cr). Cr concentrations of dog hairsfrom dogs kept on cement floors were the highest of the other environments (p<0.01). Heavy metal concentrations of dogs owned by smokers, were higher than dogs of non-smokers, but there were no significant differences.

A Kinetic Study of the Aluminum Electrode in Molten 60 Mole Percent $AlCl_3$-40 Mole Percent NaCl at 453${\circ}K$ (용융 (60 몰% $AlCl_3$-40 몰% NaCl) 염 속에서의 알루미늄전극의 반응속도론적 연구)

  • G. F. Uhlig;T. N. Andersen;S. Johns;H. Eyring
    • Journal of the Korean Chemical Society
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    • v.18 no.6
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    • pp.400-407
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    • 1974
  • Steady-state anodic and cathodic polarization curves were developed for the Al electrode in 60 mole %$AlCl_3$-40 mole % NaCl at $180^{\circ}C$$453^{\circ}K$). Ohmic resistance contributed substantially to the anodic polarization at current densities greater than 50 mA/$CM^2$ even with capillary tip placed close to the electrode. This could not be rationalized from the resistivity of the melt, which would lead to a much smaller polarization. It was therefore concluded that a layer of high resistance $AlCl_3$ (or $AlCl_3$-rich melt) formed close to the anode surface. From the IR-corrected anodic Tafel and Allen-Hickling plots an apparent anodic charge-transfer coefficient of ${\alpha}_a$ = (2.3 RT/F)(d log i/d${\eta}$) = $1.5{\pm}0.25$ was obtained. At cathodic current densities greater than approximately 30 mA/$cm^2$, slow ion diffusion and dendrite growth both interfered with the measurement of kinetic parameters.

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A Study on the Optimization and the Transient Phenomena of the $Pr^{3+}$ doped Fiber Amplifier ($Pr^{3+}$이 도핑된 광섬유증폭기의 최적화 및 과도현상에 관한 연구)

  • 이재명;지명훈;염진용;이영우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.05a
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    • pp.333-336
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    • 2001
  • The transient response in PDFA(Praseodymium-Doped Fiber Amplifier) is theoretically investigated. The PDFA has the spectral gain band in 1.3${\mu}{\textrm}{m}$. The transient model includes the transient buildup of the population inversion, the pump power, and the signal power and their transient variation along the fiber amplifier. The numerical analysis of transient model can predict the gain saturation, the variation of pump power and the gain as a function of the fiber length. It also shows the gain saturation and recovery effects depending on the pumping rate lead to distortion and saturation in the amplification of optical pulse. The results of numerical analysis, for the case of the Pr ion concentration of 1000ppm and the pump power of 0.5W the gain saturation is obtained 30dB at the length of 5m and the saturation time of upper level is 250 $mutextrm{s}$.

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Prognostics and Health Management for Battery Remaining Useful Life Prediction Based on Electrochemistry Model: A Tutorial (배터리 잔존 유효 수명 예측을 위한 전기화학 모델 기반 고장 예지 및 건전성 관리 기술)

  • Choi, Yohwan;Kim, Hongseok
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.42 no.4
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    • pp.939-949
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    • 2017
  • Prognostics and health management(PHM) is actively utilized by industry as an essential technology focusing on accurately monitoring the health state of a system and predicting the remaining useful life(RUL). An effective PHM is expected to reduce maintenance costs as well as improve safety of system by preventing failure in advance. With these advantages, PHM can be applied to the battery system which is a core element to provide electricity for devices with mobility, since battery faults could lead to operational downtime, performance degradation, and even catastrophic loss of human life by unexpected explosion due to non-linear characteristics of battery. In this paper we mainly review a recent progress on various models for predicting RUL of battery with high accuracy satisfying the given confidence interval level. Moreover, performance evaluation metrics for battery prognostics are presented in detail to show the strength of these metrics compared to the traditional ones used in the existing forecasting applications.

Effect of Interstitial Elements on Ductile-Brittle Transition Behavior of Austenitic Fe-18Cr-10Mn-2Ni Alloys (오스테나이트계 Fe-18Cr-10Mn-2Ni 합금의 연성-취성 천이 거동에 미치는 침입형 원소의 영향)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.649-654
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    • 2013
  • The effect of interstitial elements on the ductile-brittle transition behavior of austenitic Fe-18Cr-10Mn-2Ni alloys with different nitrogen and carbon contents was investigated in this study. All the alloys exhibited ductile-brittle transition behavior because of unusual low-temperature brittle fracture, even though they have a faced-centered cubic structure. With the same interstitial content, the combined addition of nitrogen and carbon, compared to the sole addition of nitrogen, improved the low-temperature toughness and thus decreased the ductile-brittle transition temperature (DBTT) because this combined addition effectively enhances the metallic component of the interatomic bonds and is accompanied by good plasticity and toughness due to the increased free electron concentration. The increase in carbon content or of the carbon-to-nitrogen ratio, however, could increase the DBTT since either of these causes the occurrence of intergranular fracture that lead to the deterioration of the toughness at low temperatures. The secondary ion mass spectroscopy analysis results for the observation of carbon and nitrogen distributions confirms that the carbon and nitrogen atoms were significantly segregated to the austenite grain boundaries and then caused grain boundary embrittlement. In order to successfully develop austenitic Fe-Cr-Mn alloys for low-temperature application, therefore, more systematic study is required to determine the optimum content and ratio of carbon and nitrogen in terms of free electron concentration and grain boundary embrittlement.

Effects of Ginsenosides on $pp60^{c-src}$ Kinase, Intracellular Calcium and Cell Proliferation in NIH 373 Cells

  • Hong, Hee-Youn;Yoo, Gyurng-Soo;Choi, Jung-Kap
    • Journal of Ginseng Research
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    • v.22 no.2
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    • pp.126-132
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    • 1998
  • In the present study, we examined effects of ginseng saponins (ginsenosides) on pp60c-src protein tyrosine kinase (PTK) activity, intracellular calcium concentration ([$Ca^{2+}$]i), and cell proliferation in NIH3T3 cells. Eight different ginsenosides [ginsenoside-Rb1 (G-$Rb_1$), -$Rb_2$, -Rc, -Rd, -Re, -Rf, -$Rg_1$, -$Rg_2$) and ginseng total saponin (GTS) were used for these experiments. All ginsenosides and GTS tested stimulated the activation of $pp60^{c-src}$ kinase, and especially G-$Rb_1$,-Rd,-$Rg_1$, and -$Rg_1$ showed a higher stimulatory effect than others at 16.7 $\mu\textrm{g}$/ml of ginsenosides with a 18 hr-incubation, increasing the activity by 4.5, 3.5, 3.5, and 3.0-fold, respectively, over that of untreated control. In addition, both G-Rd and -$Rg_2$)Rg2 increased ($Ca^{2+}$), to 202 and 334 nM, respectively, about 2-3-fold above the basal level within 7min at 250 $\mu\textrm{g}$/yml of ginsenosides. The increases of ($Ca^{2+}$), were eliminated by Pretreatment of EGTA, an extracellular calcium chelator, suggtasting that they result from an influx of calcium ion from extracellular medium rather than an efflux from intracellular calcium store, endoplasmic reticulum (ER). All ginsenosides studied enhanced cell proliferation to 1.2-1.4-fold over that of untreated control at 5~250 $\mu\textrm{g}$/ml of concentrations. Interestingly the promotion of cell proliferation by ginsenosides corresponded with the activation of c-src kinase, which is an early step in the mitogenic signaling cascade. Taken together, we suggest that some ginsenosides may lead to cellProliferation via the activation of cellular signal transduction Pathway involving $pp60^{c-src}$ kinase.

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Partial Purification and Characterization of Enzymes Involved in the Processing of Pre-M1 RNA at the 3' End in Escherichia coli (대장균에서 선구-M1 RNA의 3'-말단 가공에 관여하는 효소들의 부분 정제와 그 특성 조사)

  • Kim, Ha Dong;Ko, Jae Hyeong;Cho, Bong Rae;Lee, Young Hoon;Park, In Won
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.307-314
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    • 1999
  • Ml RNA, the RNA component of RNase P from Escherichia coli, is produced by 3' processing of pre-Ml RNA, a major primary transcript of the rnpB gene. The enzyme fraction containing the processing activity was partially purified and characterized. Since exposure of the active fraction to the high salt condition results in the inactivation of the processing activity, the processing enzyme seems to be an enzyme complex composed of multiple enzymes. The enzyme fraction loses the processing activity when treated with the chemical nuclease lead(II) ion, but regains its activity by the addition of RNA isolated from the enzyme fraction itself, suggesting that an RNA molecule(s) may be essential for the processing activity. Analysis of cleavage sites produced by the partially purified enzyme fraction also implies that the 3' processing occurs by multiple enzymes and at least in two distinct pathways.

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Theoretical construction of solar wind proton temperature anisotropy versus beta inverse correlation

  • Seough, Jungjoon;Yoon, Peter H.;Kim, Khan-Hyuk;Lee, Dong-Hun
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.118.1-118.1
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    • 2012
  • In situ observations from the Wind spacecraft that statistically analyzed the solar wind proton at 1 AU has indicated that the measured proton temperature anisotropies seems to be regulated by the oblique instabilities (the mirror and oblique firehose). This result is in contradiction with the prediction of linear kinetic theory that the ion-cyclotron (for ${\beta}_{\parallel}$ < 2) and parallel firehose (for ${\beta}_{\parallel}$ <10) would dominate over the oblique instabilities. Various kinds of physical mechanisms have been suggested to explain this disagreement between the observations and linear theory. All of the suggestions consider the solar wind as a unoform magnetized plasma. However the real space environment is replete with the intermediate spatio-temporal scale variations associated with various physical quantities, such as the magnetic field intensity and the solar wind density. In this paper we present that the pervasive intermediate-scale temporal variation of the local magnetic field intensity can lead to the modification of the proton temperature anisotropy versus beta inverse correlation for temperature-anisotropy-driven instabilities. By means of quasilinear kinetic theory involving such temporal variation, we construct the simulated solar wind proton data distribution associated the magnetic fluctuations in (${\beta}_{\parallel}$, $T_{\perp}/T_{\parallel}$) space. It is shown that the theoretically simulated proton distribution and a general trend of the enhanced fluctuations bounded by the oblique instabilities are consistent with in situ observations. Furthermore, the measure magnetic compressibility can be accounted for by the magnetic spectral signatures of the unstable modes.

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Development of High Performance Battery for Navigation Aid's Power (항로표지(등부표) 전원공급용 고성능 축전지 개발)

  • Yoon, Seok-Jun;Cho, Myung-Hun;Lee, Dae-Pyo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2009.06a
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    • pp.435-438
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    • 2009
  • A navigation aid buoy is a kind of safety facility for maritime navigation with a purpose of leading the vessels for navigating, docking and sail off. An advanced rechargeable battery is required for stable power supply for navigation aid buoy as the high magnitude LED lamps, real time location/control for navigation aids and e-Navigation support systems with maritime climate observation equipments have recently been deployed. This study is focused on the lithium battery, especially lithium polymer battery which is believed to be safer than the other types of batteries. The lithium polymer battery reviewed in this study is designed with $LiFePO_4$-based cathode, which has superior safety features to the oxide-based cathodes. Besides, a 3.6kWh battery pack has been built with the above-mentioned unit cells for the purpose of comparative research with lead acid battery system.

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Separating nanocluster Si formation and Er activation in nanocluster-Si sensitized Er luminescence

  • Kim, In-Yong;Sin, Jung-Hun;Kim, Gyeong-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.109-109
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    • 2010
  • $Er^{3+}$ ion shows a stable and efficient luminescence at 1.54mm due to its $^4I_{13/2}\;{\rightarrow}\;^4I_{15/2}$ intra-4f transition. As this corresponds to the low-loss window of silica-based optical fibers, Er-based light sources have become a mainstay of the long-distance telecom. In most telecom applications, $Er^{3+}$ ions are excited via resonant optical pumping. However, if nanocluster-Si (nc-Si) are co-doped with $Er^{3+}$, $Er^{3+}$ can be excited via energy transfer from excited electrical carriers in the nc-Si as well. This combines the broad, strong absorption band of nc-Si with narrow, stable emission spectra of $Er^{3+}$ to allow top-pumping with off-resonant, low-cost broadband light sources as well as electrical pumping. A widely used method to achieve nc-Si sensitization of $Er^{3+}$ is high-temperature annealing of Er-doped, non-stoichiometric amorphous thin film with excess Si (e.g.,silicon-rich silicon oxide(SRSO)) to precipitate nc-Si and optically activate $Er^{3+}$ at the same time. Unfortunately, such precipitation and growth of nc-Si into Er-doped oxide matrix can lead to $Er^{3+}$ clustering away from nc-Si at anneal temperatures much lower than ${\sim}1000^{\circ}C$ that is necessary for full optical activation of $Er^{3+}$ in $SiO_2$. Recently, silicon-rich silicon nitride (SRSN) was reported to be a promising alternative to SRSO that can overcome this problem of Er clustering. But as nc-Si formation and optical activation $Er^{3+}$ remain linked in Er-doped SRSN, it is not clear which mechanism is responsible for the observed improvement. In this paper, we report on investigating the effect of separating the nc-Si formation and $Er^{3+}$ activation by using hetero-multilayers that consist of nm-thin SRSO or SRSN sensitizing layers with Er-doped $SiO_2$ or $Si_3N_4$ luminescing layers.

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