• 대한화학회지
• /
• 제18권5호
• /
• pp.373-380
• /
• 1974

저자들에 의해서 이미 보고되어 있는 요오드화염으로부터 요오드산염$(I^-{\to}{IO_3}^-)$ 및 요오드산염으로 부터 과요오드산염$({IO_3}^-{\to}{IO_4}^-)$까지의 전해결과를 참작하여 무격막 전해조와 이산화납양극을 사용하여 요오드화염으로부터 과요오드산염$(I^-{\to}{IO_4}^-)$을 직접 전해제조하기 위한 최적 전해조건에 관하여 검토하였다. 0.5g/l의 환원방지제인 중크롬산칼륨을 함유함 1몰의 요오드화칼륨 수용액을 15A/$dm^2$의 양극전류밀도와 $60^{\circ}C$의 전해온도에서 전해한 결과, 요오드화칼륨으로 부터 과요오드산칼륨까지의 변화율 98%에서 전류효율이 84%이었다. 또한 각종 전해액중에서 이산화납 양극에 의한 분극곡선으로 부터 전극반응의 내용도 설명하였다.

• 한국응용과학기술학회지
• /
• 제25권2호
• /
• pp.211-218
• /
• 2008

The performance of positive plates depends on the structure of the lead dioxide active mass. The positive active materials (PAM) consists of a skeleton, built up of agglomerates and macropores. Agglomerates, in their turn, comprise particles and micropores. This paper described a study conducted to determine the effects of different soaking times between the acid fill and formation stages of the tubular plate production. For the positive plates a lead oxide were filled into tubular bag with a red lead. After filling the positive plates were soaked in $H_2SO_4$ solution. X-ray diffraction(XRD), scanning electron microscopy(SEM) and electrical testing had been used to study the compositional and morphological aspects of the positive active material(PAM) just prior and after formation. Results indicate that PAM compositions were effected by the soaking time and acid density of $H_2SO_4$ solution. It can be seen that as the soaking time duration increases, $\alpha$-PbO, $Pb_3O_4$, and Pb were all gradually sulphating. Composition of 3BS reached a maximum at around 3 h duration and $H_2SO_4$ of sp. gr. 1.10 on soaking. This results would suggest that the most beneficial conditions for soaking were the $H_2SO_4$ of sp. gr. 1.10 and 2 to 6 h of soaking.

• 한국응용과학기술학회지
• /
• 제27권2호
• /
• pp.208-215
• /
• 2010

EAF dust which is contained around 30% of zinc, 15% of iron and 3% of lead individually, is chemically treated by ammonium chloride, ammonia water, ammonia gas and carbon dioxide, and also tested and identified the ratios of the recovery of In by applied the variations of particle size, pH and heating temperature as well, in order to getting optimized recovery of the In metal after performing all of those processes. Experimental results showed that the rate of Zn recovery is 97% when the mixture of 1.3 of $NH_4Cl$/EAF is heated to the temperature of $400^{\circ}C$ and leached by water, and 95% recovery of In when ammonia gas and carbon dioxide is added simultaneously and adjust the 9.5 of pH to the same mixture above. For the purpose of remove the impurities in the mixed sample, which is prepared by the two samples, indicated above showing as the ratio of 95% and 97% recovery, in case of applied the cementation process to it, and also by electrolytic process, produced the In plate of 95~97%, and acquired 99-99.5% of In metal ingot finally by applied the heating process at $470{\sim}500^{\circ}C$.

• 한국정보통신설비학회:학술대회논문집
• /
• 한국정보통신설비학회 2008년도 정보통신설비 학술대회
• /
• pp.205-208
• /
• 2008

This article presents a methodology for the monitoring of air pollution. All over the world, the interest in the environment has been continuously increasing. Unfortunately, much of this interest is due to emerging problems, such as the greenhouse effect and climate change. For this reason, research into carbon dioxide, which causes the greenhouse effect, is progressing rapidly. This article presents a method of measuring the level of carbon dioxide and other substances in the air through the utilization of mobile-networking base stations and measured data. First of all, sensors are attached at the appropriate position of the mobile-networking base stations. These sensors will measure the air quality in their respective positions, and send sensor data to an urban management center via network gateways and data-collecting systems. The measured data can be used for various purposes. In general, it can be used to measure the air quality, which can then be used as a basis for urban planning. The method described herein utilizes airpollution sensors that are attached to the base stations in different locations and at varying heights. The data obtained hereby will be applicable in many fields. At this time this is simply a methodology, however we hope that it will lead to a practical application.

• 공업화학
• /
• 제3권3호
• /
• pp.482-490
• /
• 1992

세종류의 금속산화물 전극을 양극으로 사용하여 methanol 용액중에서 furfuryl alcohol을 양극산화 시켜 2,5-dimethoxy-2,5-dihydrofurfuryl alcohol을 전해합성 하였다. 각 전극들은 티타늄 재질상에 산화주석($SnO_2$)과 삼산화이안티몬($Sb_2O_3$)의 반도체 혼합물층을 전기로 내에어 만들고, 그 위에 양극산화방법으로 ${\alpha}-PbO_2$, ${\beta}-PbO_2$, $MnO_2$등의 금속산화물을 전착(electrodeposition)하여 3종의 전극을 제작하였다. 이산화납 전극이 이산화망간 전극에 비하여 양극 내식성이 우수하였으며 생성물의 수율(92%)도 백금전극을 사용했던 결과와 대등하였다.

• Advances in nano research
• /
• 제14권4호
• /
• pp.355-362
• /
• 2023

Physical exercise, especially intense exercise and high intensity interval training (HIIT) by trampoline, can lead to muscle injuries. These effects can be reduced with intelligent products made of nanocomposite materials. Most of these nanocomposites are polymers reinforced with silicon dioxide, alumina, and titanium dioxide nanoparticles. This study presents a polymer nanocomposite reinforced with silica. As a result of the rapid reaction between tetraethyl orthosilicate and ammonia in the presence of citric acid and other agents, silica nanostructures were synthesized. By substituting bis (4-amino phenoxy) phenyl-triptycene in N, N-dimethylformamide with potassium carbonate, followed by catalytic reduction with hydrazine and Pd/C, the diamine monomer bis (4-amino phenoxy) phenyl-triptycene is prepared. We synthesized a new polyaromatic (imide) with triptycene unit by sol-gel method from aromatic diamines and dianhydride using pyridine as a condensation reagent in NMP. PI readily dissolves in solvents and forms robust and tough polymer films in situ. The FTIR and NMR techniques were used to determine the effects of SiO₂ on the sol-gel process and the structure of the synthesized nanocomposites. By using a simultaneous thermal analysis (DTA-TG) method, the appropriate thermal operation temperature was also determined. Through SEM analysis, the structure, shape, size, and specific surface area of pores were determined. Analysis of XRD results is used to determine how SiO₂ affects the crystallization of phases and the activation energy of crystallization.

• Journal of Animal Science and Technology
• /
• 제66권2호
• /
• pp.237-250
• /
• 2024

The emission of noxious gases is a significant problem in pig production, as it can lead to poor production, welfare concerns, and environmental pollution. The noxious gases are the gasses emitted from the pig manure that contribute to air pollution. The increased concentration of various harmful gasses can pose health risks to both animals and humans. The major gases produced in the pig farm include methane, hydrogen sulfide, carbon dioxide, ammonia, sulfur dioxide and volatile fatty acids, which are mainly derived from the fermentation of undigested or poorly digested nutrients. Nowadays research has focused on more holistic approaches to obtain a healthy farm environment that helps animal production. The use of probiotics, prebiotics, dietary enzymes, and medicinal plants in animal diets has been explored as a means of reducing harmful gas emissions. This review paper focuses on the harmful gas emissions from pig farm, the mechanisms of gas production, and strategies for reducing these emissions. Additionally, various methods for reducing gas in pigs, including probiotic interventions; prebiotic interventions, dietary enzymes supplementation, and use of medicinal plants and organic acids are discussed. Overall, this paper provides a comprehensive review of the current state of knowledge on reducing noxious gas in pigs and offers valuable insights for pig producers, nutritionists, and researchers working in this area.

• 교육시설 논문지
• /
• 제25권4호
• /
• pp.19-30
• /
• 2018

The school classroom is a common living place where students spend 7 to 14 hours a day to prepare for their careers. Therefore, if the ventilation of the classroom is not properly performed, it may lead to the deterioration of learning ability due to the unclear air. The concentration of carbon dioxide in the classroom is reported to be high, and the increase in carbon dioxide concentration has a negative effect on the learner's academic performance. In this context, the purpose of this study is to propose a methodology for intelligent and responsive window opening-closing operation process that can reduce the concentration of $CO_2$ in the classroom in order to build a support space that can create an effective teaching-learning environment for adolescents. The specific objectives are as follows. First of all, we define the concept of window opening-closing operation. Secondly, twe develop the operation process of window opening-closing. Thirdly, we develop an algorithm for real-time window opening and closing (process) (Window Opening-Closing Operation Process). Finally, we verify the intelligent responsive window opening-closing operation process through developing examples of window opening-closing operation process using the parametric design program. This study is a preliminary study to develop algorithms necessary for window opening-closing operation. Based on the first-order algorithm, We simulated window opening-closing operations according to a hypothetical scenario. As a result, This study can show that the window is open and close depending on the $CO_2$ concentration, but the $CO_2$ concentration in the room is higher than outdoors. Consequentially, we suggest that it is necessary to develop an algorithm to supplement these results because window is often not working when the temperature difference between indoor and outdoor in winter is large.

• 센서학회지
• /
• 제32권3호
• /
• pp.169-173
• /
• 2023

With the increasing concern of global warming caused by greenhouse gases owing to the recent industrial development, there is a growing need for advanced technology to control these emissions. Among the various greenhouse gases, nitrogen dioxide (NO₂) is a major contributor to global warming and is mainly released from sources, such as automobile exhaust and factories. Although semiconductor-type NO₂ gas sensors, such as SnO₂, have been extensively studied, they often require high operating temperatures and complicated manufacturing processes, while lacking selectivity, resulting in inaccurate measurements of NO₂ gas levels. To address these limitations, a novel sensor using PbS quantum dots (QDs) was developed, which operates at low temperatures and exhibits high selectivity toward NO₂ gas owing to its strong oxidation reaction. Furthermore, the use of P3HT conductive polymer improved the thin film quality, reactivity, and reaction rate of the sensor. The sensor demonstrated the ability to accurately measure NO₂ gas concentrations ranging from 500 to 100 ppm, with a 5.1 times higher sensitivity, 1.5 times higher response rate, and 1.15 times higher recovery rate compared with sensors without P3HT.

• 한국기후변화학회지
• /
• 제6권1호
• /
• pp.1-10
• /
• 2015

Climate change lead to environmental pollution caused by the radical economic growth and development of industry. The amount of damage from abnormal climate is increasing rapidly for this reason in Korea. In particular, the cities is a lot of carbon emission quantity from the radical growth. Thus the government present "low carbon green growth" for eco-friendly city planning. As one of the important factors effecting climate change, active researches on land use change is performed. In this study, we knew land use change of each scenarios using land use equilibrium model which is kind of predictive model of land use in Japan. First, we selected study area to Jeju lsland. For this study, indicators for input data were selected and spatial data for input data were established using GIS program. Second, we established future scenarios based in 2040s. There are 2 future scenarios: dispersion scenario, compact scenario. Third, we compared with residential area of current and residential area for future scenarios. Results showed that residential area of the difference between current and dispersion scenario were 1,230 ha and residential area of the difference between current and compact scenario were 1,515 ha. Finally, for comparing carbon dioxide absorption volume between dispersion scenarios and compact scenarios, we calculated carbon dioxide absorption volume according to residential area decreased of each future scenarios. Results showed that carbon dioxide absorption volume in dispersion scenario was 477,878 ton and carbon dioxide absorption volume in compact scenario was 588,606 ton. Therefore, the study showed that land use equilibrium model is expected to put to use for future enhancement in creating data for climate change stabilization. And it is also expected to be utilized for city planning research in Korea.