• Title/Summary/Keyword: Lead Battery

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Improvement of Electrochemical Properties and Thermal Stability of a Ni-rich Cathode Material by Polypropylene Coating

  • Yoo, Gi-Won;Son, Jong-Tae
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.179-184
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    • 2016
  • The interface between the surface of a cathode material and the electrolyte gives rise to surface reactions such as solid electrolyte interface (SEI) and chemical side reactions. These reactions lead to increased surface resistance and charge transfer resistance. It is consequently necessary to improve the electrochemical characteristics by suppressing these reactions. In order to suppress unnecessary surface reactions, we coated cathode material using polypropylene (PP). The PP coating layer effectively reduced the SEI film that is generated after a 4.3 V initial charging process. By mitigating the formation of the SEI film, the PP-coated Li[(Ni0.6Co0.1Mn0.3)0.36(Ni0.80Co0.15Al0.05)0.64)]O2(NCS) electrode provided enhanced transport of Li+ ions due to reduced SEI resistance (RSEI) and charge transfer resistance (Rct). The initial charge and discharge efficiency of the PP-coated NCS electrode was 96.2 % at a current density of 17 mA/g in a voltage range of 3.0 ~ 4.3 V, whereas the efficiency of the NCS electrode was only 94.7 %. The presence of the protective PP layer on the cathode improved the thermal stability by reducing the generated heat, and this was confirmed via DSC analysis by an increased exothermic peak.

Design and Construction of 35 kWh Class Superconductor Flywheel Energy Storage System Main Frame (35 kWh급 초전도 플라이휠 에너지 저장 시스템 프레임 설계 및 제작)

  • Jung, S.Y.;Han, Y.H.;Park, B.J.;Han, S.C.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.52-57
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    • 2011
  • A superconductor flywheel energy storage system (SFES) is an electro-mechanical battery which transforms electrical energy into mechanical energy for storage, and vice versa. The 35 kWh class SFES is composed of a main frame, superconductor bearings, electro-magnetic dampers, a motor/generator, and a composite flywheel. The energy storing capacity of the SFES can be limited by the operational speed range of the system. The operational speed range is limited by many factors, especially the resonant frequency of the main frame and flywheel. In this study, a steel frame has been designed and constructed for a 35 kWh class SFES. All the main parts, their housings, and the flywheel are aligned and assembled on to the main frame. While in operation, the flywheel excites the main frame, as well as all the parts assembled to it, causing the system to vibrate at the rotating speed. If the main frame is excited at its resonant frequency, the system will resonate, which may lead to unstable levitation at the superconductor bearings and electro-magnetic dampers. The main frame for the 35 kWh class SFES has been designed and constructed to improve stiffness for the stable operation of the system within the operational speed range.

Forest Environment Monitoring Application of Intelligence Embedded based on Wireless Sensor Networks

  • Seo, Jung Hee;Park, Hung Bog
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.4
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    • pp.1555-1570
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    • 2016
  • For monitoring forest fires, a real-time system to prevent fires in wider areas should be supported consistently. However, there has still been a lack of the support for real-time system related to forest fire monitoring. In addition, the 'real-time' processing in a forest fire detection system can lead to excessive consumption of energy. To solve these problems, the intelligent data acquisition of sensing nodes is required, and the maximum energy savings as well as rapid and accurate detection by flame sensors need to be done. In this regard, this paper proposes a node built-in filter algorithm for intelligent data collection of sensing nodes for the rapid detection of forest fires with focus on reducing the power consumption of the remote sensing nodes and providing efficient wireless sensor network-based forest environment monitoring in terms of data transmission, network stability and data acquisition. The experimental result showed that battery life can be extended through the intelligent sampling of remote sensing nodes, and the average accuracy of the measurement of flame detection based on the distance is 44%.

Energy Efficient and Secure Multipoint Relay Selection in Mobile Ad hoc Networks

  • Anand, Anjali;Rani, Rinkle;Aggarwal, Himanshu
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.4
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    • pp.1571-1589
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    • 2016
  • Nodes in MANETs are battery powered which makes energy an invaluable resource. In OLSR, MPRs are special nodes that are selected by other nodes to relay their data/control traffic which may lead to high energy consumption of MPR nodes. Therefore, employing energy efficient MPR selection mechanism is imperative to ensure prolonged network lifetime. However, misbehaving MPR nodes tend to preserve their energy by dropping packets of other nodes instead of forwarding them. This leads to huge energy loss and performance degradation of existing energy efficient MPR selection schemes. This paper proposes an energy efficient secure MPR selection (ES-MPR) technique that takes into account both energy and security metrics for MPR selection. It introduces the concept of 'Composite Eligibility Index' (CEI) to examine the eligibility of a node for being selected as an MPR. CEI is used in conjunction with willingness to provide distinct selection parameters for Flooding and Routing MPRs. Simulation studies reveal the efficiency of ES-MPR in selection of energy efficient secure and stable MPRs, in turn, prolonging the network operational lifetime.

용해 납 흐름 배터리용 여러 카본 전극의 에너지 효율 특성 비교

  • Min, Hyeong-Seop;Yang, Min-Gyu;Kim, Sang-Sik;Lee, Jeon-Guk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.59.1-59.1
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    • 2009
  • 레독스 흐름 배터리 (Redox Flow Battery)는 외부의 탱크 등에 저장해 둔 활성물질(이온 가수가 변화는 금속) 의 용액을 펌프로 전해셀에 공급하여 충전 방전하는 배터리로 신재생 에너지인 풍력과 태양광 발전, 야간의 잉여 전력 저장 등 대용량 전력 저장 장치로 관심이 높아지고 있다. 대표적인 레독스 흐름 배터리로 알려진 바나듐 레독스 흐름 배터리는 이온 교환막 사용으로 인하여 전기전도도, 기계적 강도, 투과도 및 전해질 내의 화학적 안정성 등 여러 가지 문제점과 함께 비용 문제점을 야기한다. 하지만 새로운 용해 납 레독스 흐름 배터리는 이온 교환막을 사용하지 않아 바나듐 레독스 흐름 배터리의 문제점 및 시설비가 절약되는 장점이 있어 새로이 연구되지고 있다. 본 연구는 레독스 흐름 배터리에 주로 이용되는 카본 전극재료의 따라 형성되는 Pb, $PbO_2$ 박막의 미세 구조를 및 에너지 효율 특성을 분석하였다. 실험은 half-cell로 이루어졌으며 작업전극은 Carbon felt, Ordered Graphite, Disordered Graphite, Glassy Carbon 등을 여러 카본 재료를 사용하였고, 상대전극은 Pt, 기준전극으로 Ag/AgCl를 사용하여 Cyclic Voltammetry특성과 충방전 특성을 연구하였다. 전해질은 Lead Carbonate ($PbCO_3$)+Methanesulfonic acid ($CH_3SO_3H$) 들어간 수용성 전해질을 교반을 통해 이용하였다. 여러 carbon 전극재료와 생성된 Pb, $PbO_2$ 막의 표면구조, 미세구조, 상들의 변화는 XRD, SEM, EDX, Raman등을 통하여 분석하였으며, 전기화학 공정의 변수와 전극에 따른 에너지 효율특성에 대하여 고찰해 보았다.

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Radiotelemetry for ECG and Event Signals Using FDM (주파수분할 다중방식에 의한 심전신호 및 부가정보신호 무선전송)

  • 이훈규;박동철
    • Journal of Biomedical Engineering Research
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    • v.21 no.4
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    • pp.345-351
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    • 2000
  • This study is to dvelop a radiotelemetry system to transmit and receive ECG (electrocardiograph) and event signals by using the frequency division multiplexing(FDM) technique. ECG signal sensed by the electrodes is amplified and added to the event signals acting in different frequency range for lead-off, nurse call and low level battery by using FDM. The sub-carrier oscillator using Colpitts circuits and main carrier frequency which is multiplied is frequency modulated by this superhetrodyne technique, and demodulated from the compose IF signal through the quadrature demodulator. A pulse counter demodulator and filtering circuits extract the original ECG and event signals.

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A Study on the Urban Air Mobility(UAM) Operation Pilot Qualification System

  • Kim, Su-Ro;Cho, Young-Jin;Jeon, Seung-Mok
    • International Journal of Internet, Broadcasting and Communication
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    • v.14 no.1
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    • pp.201-208
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    • 2022
  • As around the world, ground and underground transportation capacity is reaching its limit, centering on urban areas. As urban traffic becomes congested, time and cost are astronomical, and environmental destruction caused by urban pollution is becoming increasingly serious. As a way to solve this problem, the means of flying over the air are in the spotlight as the next generation of future transportation, and the concept of urban air mobility (UAM, Urban Air Mobility) is defined as systematic planning. The development of an electric-powered vertical take-off (eVTOL) aircraft that obtains electric power through a battery using a personal aerial vehicle (PAV) as a means of transportation has accelerated. As the aircraft development of new technology aircraft in the evtol method is actively carried out, the need to prepare systems such as aircraft certification standards, pilot qualification systems, and qualification management is emerging. The Federal Aviation Administration (FAA) and the European Union Aviation Safety Agency (EASA), which lead international standards, announced new special technical conditions and temporary regulations SCVTOL-01, respectively. However, the pilot qualification system for operating the uam aircraft has not yet been clearly announced. Therefore, this paper analyzes the recently announced FAA regulations and EASA regulations to identify differences and directions in perspectives on UAMs and study the existing vertical take-off and landing aircraft (VTOL) pilot qualification system to present directions for qualification classification.

Cohort Observation of Blood Lead Concentration of Storage Battery Workers (축전지공장 근로자들의 혈중 연농도에 대한 코호트 관찰)

  • Kim, Chang-Yoon;Kim, Jung-Man;Han, Gu-Wung;Park, Jung-Han
    • Journal of Preventive Medicine and Public Health
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    • v.23 no.3 s.31
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    • pp.324-337
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    • 1990
  • To assess the effectiveness of the interventions in working environment and personal hygiene for the occupational exposure to the lead, 156 workers (116 exposed subjects and 40 controls) of a newly established battery factory were examined for their blood lead concentration (Pb-B) in every 3 months up to 18 months. Air lead concentration (Pb-A) of the workplaces was also checked for 3 times in 6 months interval from August 1987. Environmental intervention included the local exhaust ventilation and vacuum cleaning of the floor. Intervention of the personal hygiene included the daily change of clothes, compulsory shower after work and hand washing before meal, prohibition of cigarette smoking and food consumption at the work site and wearing mask. Mean Pb-B of the controls was $21.97{\pm}3.36{\mu}g/dl$ at the preemployment examination and slightly increased to $22.75{\pm}3.38{\mu}g/dl$ after 6 months. Mean Pb-B of the workers who were employed before the factory was in operation (Group A) was $20.49{\pm}3.84{\mu}g/dl$ on employment and it was increased to $23.90{\pm}5.30{\mu}g/dl$ after 3 months (p<0.01). Pb-B was increased to $28.84{\pm}5.76{\mu}g/dl$ 6 months after the employment which was 1 month after the initiation of intervention program. It did not increase thereafter and ranged between $26.83{\mu}g/dl\;and\;28.28{\mu}g/dl$ in the subsequent 4 tests. Mean Pb-B of the workers who were employed after the factory had been in operation but before the intervention program was initiated (Group B) was $16.58{\pm}4/53{\mu}g/dl$ before the exposure and it was increased to $28.82{\pm}5.66{\mu}g/dl$(P<0.01) in 3 months later (1 month after the intervention). The values of subsequent 4 tests remained between 26.46 and $28.54{\mu}g/dl$. Mean Pb-B of the workers who were employed after intervention program had been started (Group C) was $19.45{\pm}3.44{\mu}g/dl$ at the preemployment examination and gradually increased to $22.70{\pm}4.55{\mu}g/dl$ after 3 months(P<0.01), $23.68{\pm}4.18{\mu}g/dl$ after 6 months, and $24.42{\pm}3.60{\mu}g/dl$ after 9 months. Work stations were classified into 4 parts according to Pb-A. The Pb-A of part I, the highest areas, were $0.365mg/m^3$, and after the intervention the levels were decreased to $0.216mg/m^3\;and\;0.208mg/m^3$ in follow-up tests. The Pb-A of part II was decreased from $0.232mg/m^3\;to\;0.148mg/m^3,\;and\;0.120mg/m^3$ after the intervention. Pb-A of part III and W was tested only after intervention and the Pb-A of part III were $0.124mg/m^3$ in Jannuary 1988 and $0.081mg/m^3$ in August 1988. The Pb-A of part IV not stationed at one place but moving around, was $0.110mg/m^3$ in August 1988. There was no consistent relationship between Pb-B and Pb-A. Pb-B of the group A and B workers in the part of the highest Pb-A were lower than those of the workers in the parts of lower Pb-A. Pb-B of the workers in the part of the lowest Pb-A incerased more rapidly. Pb-B of group C workers was the highest in part I and the lowest in part IV. These findings suggest that Pb-B is more valid method than Pb-A for monitoring the health of lead workers and intervention in personal hygiene is more effective than environmental intervention.

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Thirteen-year Experience of Permanent Epicardial Pacing in Children (소아연령군에서의 영구 심외막 심박 조율 13년 경험)

  • 한국남;임홍국;김웅한;김용진;노준량;배은정;노정일;윤용수;안규리
    • Journal of Chest Surgery
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    • v.37 no.6
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    • pp.499-503
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    • 2004
  • Background: We investigated the longevity, thresholds of epicardial pacemaker and causes of reoperation in the pediatric patients who underwent epicardial pacemaker implantation performed during the last 13 years Material and Method: 121 operations were performed in 83 patients from January 1989 to July 2002. We analyzed the stimulation threshold, resistance, R-wave and P-wave, and sensitivity of pacemaker lead at initial implantation. Longevity and causes of reoperations were investigated. Result At implantation, epicardial ventricular mean stimula-tion threshold was 1.2$\pm$0.1 (0.1∼5) mV, mean resistance was 519.1$\pm$18.1 (319∼778) Ohm, and mean R-wave sensitivity was 8.9$\pm$0.7 (4∼20) mV, and mean P wave sensivity was 2.5$\pm$0.7 (0.4∼12) mV. The mean longe-vity of pacemaker generator was 64.7$\pm$3.7 (2∼196) months. The reoperation free rate was 94.6% for 1 year, 93.6% for 2 years, 80.8% for 5years, 63.7% for 7 years, and 45.5% for 10 years. The causes of reoperation were battery waste in 26 cases and lead malfunction in 9 cases. There was no postoperative death related to pacemaker malfunction. Conclusion: in the childrens, average longevity of epicardial pacemaker was within accep-table range. 19.1% of the patients required pacemaker related reoperation. However, recent developments, including steroid eluting lead, 6.7% of the patients required pacemaker related reoperation, look promising in expansion of pacemaker life span.

The relationships between lead exposure indicies and urinary δ-ALA by HPLC and colorimetric method in lead exposure workers (연노출근로자에 있어서 흡광광도법과 HPLC법에 의한 요중 δ-ALA 배설량과 연노출지표들 간의 관련성)

  • Ahn, Kyu-Dong;Lee, Sung-Soo;Hwangbo, Young;Lee, Gab-Soo;Yeon, You-Yong;Kim, Yong-Bae;Lee, Byung-Kook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.1
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    • pp.77-87
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    • 1996
  • In order to compare the difference of the measurement of delta aminolevulinic acid(${\delta}$-ALA) in urine between HPLC method(HALA) and colorimetric method(CALA), and also to provide useful information for the new diagnostic criteria of ${\delta}$-ALA in urine in lead poisoning, if at all possible in the future, authors studied 234 male lead workers who were selected from 7 storage battery factories, 3 secondary smelting industries, and 2 litharge making industries. Study subjects were selected on the basis of blood Zinc protoporphyrin(ZPP) level from low to high concentration to cover wide range of lead exposure. Study variables for this study were ${\delta}$-ALA measured by two different methods, blood lead(PbB), and blood ZPP. The results were as follows: 1. There was very high correlation between ${\delta}$-ALA measured by two method(r = 0.989 : HALA = -0.8194 + 0.8110 ${\times}$ CALA), but the value of CALA was measured about 2mg/L greater than HALA. 2. While the correlations of ${\delta}$-ALA by two method with blood lead and blood ZPP were 0.46 and 0.37 respectively, they were increased to 0.63 and 0.57 if ${\delta}$-ALA values were log-transformed. 3. Simple linear regression of ${\delta}$-ALA measured by two method on ZPP were as follows: CALA = 2.0421 + 0.0341 ${\times}$ ZPP ($R^2=0.1385$ p = 0.0001) HALA = 0.8006 + 0.0280 ${\times}$ ZPP ($R^2=0.1389$ p = 0.0001) 4. Simple linear regression of ${\delta}$-ALA measured by two method on PbB were as follows: CALA = - 0.4134 + 0.1545 ${\times}$ PbB ($R^2=0.2085$ p = 0.0001) HALA = -1.2893 + 0.1287 PbB ($R^2=0.2154$ p = 0.0001), 5. Simple linear regression of log-transformed ${\delta}$-ALA by two method on ZPP and PbB were as follows: logHALA = 0.3078 + 0.0060 ZPP ($R^2=0.3329$ p = 0.0001) logCALA = 1.0189 + 0.0044 ZPP ($R^2=0.3290$ p = 0.0001) logHALA = -0.0221 + 0.0246 PbB ($R^2=0.4046$ p = 0.0001) logCALA = 0.7662 + 0.0184 PbB ($R^2=0.4108$ p = 0.0001) 6. The cumulative percent of colorimetric method to detect lead workers whose value of PbS and ZPP were over screening level such as $40{\mu}/dl$ and $100{\mu}/dl$ respectively was higher than HPLC method if cut-off level of ${\delta}$-ALA for screening of lead poisoning was 5 mg/L. But if cut-off level of ${\delta}$-ALA measured by HPLC was reduced to 3 mg/L which is compatible to 5 mg/L of ${\delta}$-ALA measured by colorimetric method, there were good agreement between two methods and showed dose-response relationship with other lead exposure indices such as PbB and ZPP.

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