• 제목/요약/키워드: Lead (II)

검색결과 524건 처리시간 0.026초

열시효 처리된 무연 솔더 볼 연결부의 충격 전단강도 평가 (Evaluation of the Impact Shear Strength of Thermal Aged Lead-Free Solder Ball Joints)

  • 정진성;김호경
    • 한국안전학회지
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    • 제30권6호
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    • pp.7-11
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    • 2015
  • The present study investigates the impact shear strength of thermal aged Sn-3Ag-0.5Cu lead-free solder joints at impact speeds ranging from 0.5 m/s to 2.5 m/s. The specimens were thermal aged for 24, 100, 250 and 1000 hours at $100^{\circ}C$. The experimental results demonstrate that the shear strength of the solder joint decreases with an increase in the load speed and aging time. The shear strength of the solder joint aged averagely decreased by 43% with an increase in the strain rate. For the as-reflowed specimens, the mode II stress intensity factor ($K_{II}$) of interfacial IMC between Sn-3.0Ag-0.5Cu and a copper substrate also was found to decrease from $1.63MPa.m^{0.5}$ to $0.97MPa.m^{0.5}$ in the speed range tested here. The degradations in the shear strength and fracture toughness of the aged solder joints are mainly caused by the growth of IMC layers at the solder/substrate interface.

신문혈(神門穴) 침자극(鍼刺戟)이 심전도(心電圖) 변화(變化)에 미치는 영향(影響) (Effect of Acupuncture Stimulation ($HT_7$), on the Change of Standard Leads in ECG)

  • 이익재;김이화;김순중
    • Korean Journal of Acupuncture
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    • 제22권3호
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    • pp.17-26
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    • 2005
  • Objectives : The aim of this study is to investigate the effect of Shinmun-acupuncture stimulation on the relationship of change in electrocardiopgraphy (ECG). Methods : For this purpose, 11 healthy volunteers were acupunctured at Shinmun acupoint using the reinforcing or reducing by inserting the needle in the same direction as the channel runs or in the opposite direction (迎隨補瀉). Then, we measured and observed the change of standard leads I, II and III in ECG. Results : In lead I , acupuncture treated groups were increased the activity of PR interval and PR segment compared to the control group. In lead II, during the acupuncture treated group by inserting the needle in the opposite direction as the channel runs was increased the activity of T wave duration, and after the acupuncture group by inserting the needle in the same direction as the channel runs was increased the activity of PR interval. In lead III, acupuncture treated groups were increased the activity of ST duration, PR interval and QT interval. Conclusions : These results suggested that Shinmun acupuncture stimulation plays an important role on the activities of ECG.

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인도기간(引導期間)을 갖는 세가지 형태(形態)의 검사(檢査).주문정책(注文政策) (Three Types of Inspection-Ordering Policies with Lead Times)

  • 김호균;이창훈
    • 대한산업공학회지
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    • 제7권1호
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    • pp.13-20
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    • 1981
  • 본 연구에서는 세가지 형태의 검사주문정책이 제시되었다. 부품 주문시 원래부품의 상태가 가동상태, 퇴화상태, 고장상태인가에 따라 보통주문, 특별주문, 긴급주문으로 분류되고, 각 주문형태는 각기 다른 인도기간으로 특정지워진다. 정책 I은 대체부품이 도착되면 원래부품이 가동중이라도 대체시키는 경우이고 정책 II는 도착된 대체부품을 원래부품의 고장발생때까지 재고시켜 두는 것이다. 정책 III은 대체부품이 도착되면 가동중인 원래부품에 검사를 한번 더 시행하여, 이것이 가동상태에 있으면 퇴화가 발생되는 평균시간까지 더 사용하고 난뒤 대체시키고, 퇴화상태에 있으면 대체부품과 즉시 대체시키는 것이다. 이와 같은 세가지 정책하에서 비용유효성 함수가 제시되고, 퇴화밀도함수와 고장밀도함수가 각각 Weibull과 지수분포를 따르는 경우 적정검사주문 시간을 구하고, 고장비용에 대한 부품가격과 고장비용에 대한 검사 비용의 변화에 따른 정책 변화가 분석되었다.

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Effects of heavy metal lead on differential cell counts in occupationally-exposed subjects from Saudi Arabia

  • Abjal P. Shaik;Abbas H. Alsaeed;Asma S. Shaik;Abdullah A. Alyousef;Vamsee K. Bammidi;Kiranmaye Sampathirao
    • Advances in environmental research
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    • 제11권1호
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    • pp.31-38
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    • 2022
  • The current observational epidemiological study analyzed blood lead levels (BLLs) in occupationally exposed workers from Riyadh region, Saudi Arabia and correlated them with the alterations in the differential cell populations of the WBC panel (lymphocytes [Lym %], mixed [Mid %] cells, and neutrophils [Neu %]). In addition, we examined the effect of confounding factors and their relation to BLLs. BLLs were estimated using the LeadCare II analyzer and hematological parameters using the ADVIA 120 analyser. An inferential analysis was conducted to detect association between the observations and the subjects' clinical characateristics. A total of 132 male subjects were included in the final analyses. Based on CDC guidelines, the subjects were categorized as Group I (BLL <10 ㎍/dL; n=118) or Group II (BLL >10 ㎍/dL; n=14) with average BLLs of 4.4 ㎍/dL and 18.1 ㎍/dL, respectively (p <0.0001). The percentages of Mid cells (p <0.0001) and neutrophils (p=0.048), were significantly altered in subjects with High BLL. A regression analysis indicated that subjects > 50 years of age had significantly higher BLLs (53.2 ㎍/dL) than younger age sub-groups (p <0.0001). Age, education, and profession were significant predictors for lead toxicity. Pb exposure is a major public health issue in Saudi Arabia and calls for further investigations on the cellular and molecular effects on hematological system.

은평 뉴타운 유적 출토 유리구슬의 성분조성과 납동위원소비 (Chemical Composition and Lead Isotope Ratio of Glass Beads Excavated from Eunpyeong Newtown Site)

  • 강형태;조남철;한민수;김우현;홍지윤
    • 보존과학회지
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    • 제25권3호
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    • pp.335-345
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    • 2009
  • 은평 뉴타운 유적 토광묘에서 출토된 유리구슬 60점에 대하여 성분조성, 납동위원소비를 주사전자현미경-에너지분산형분광기와 열이온화질량분석기로 분석하여 성분조성별 차이점과 납유리를 제작할 때 사용한 납의 산지를 추정코자 하였다. 성분조성을 분석한 결과 출토유리는 크게 포타쉬 유리($K_2O$-CaO-$SiO_2$)와 포타쉬납유리($K_2O$-PbO-$SiO_2$)계통으로 분류됨을 확인할 수 있었으며, III-3지구 1005호 토광묘에서 출토된 시료는 유리가 아니라 석영으로 판단된다. II-3지구 101호 토광묘와 III-3지구 908호 토광묘에서 출토된 무색투명한 9점의 납유리는 성분조성이 매우 일정하며 오차가 작아 동일한 원료로 동일 장소에서 함께 제작한 것으로 보인다. 주성분분석(PCA)결과에서도 출토된 유리구슬은 크게 두 개의 그룹인 포타쉬 유리($K_2O$-CaO-$SiO_2$)와 포타쉬납유리($K_2O$-PbO-$SiO_2$)로 나뉘어진다. 즉, 은평 뉴타운 유적은 주요 성분조성이 상이한 두 계통의 유리구슬로 이루어져 있음을 확인할 수 있었다. 또한 납동위원소비를 분석하여 납유리를 제작할 때 사용한 납의 산지를 추정한 결과 대부분의 납유리는 중국 북부 지역의 방연석을 사용한 것으로 나타났다.

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Lead Effects among Secondary Lead Smelter Workers with Blood Lead Levels below $80{\mu}g/100\;ml$

  • Lilis Ruth;Fischbein Alf;Diamond Sidney;Anderson Henry A.;Selikoff Irving J.;Blumberg William E.;Eisinger Josef
    • 대한예방의학회:학술대회논문집
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    • 대한예방의학회 1994년도 교수 연수회(환경)
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    • pp.549-559
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    • 1994
  • A subgroup or workers from a secondary lead smelter was defined to include those with blood lead levels not exceeding $80{\mu}g/100\;ml$ and with no pest history of elevated blood lead. Central nervous system symptoms (tiredness, sleeplessness, irritability, headache) were reported by 55% of the group and muscle and joint pain by 39%. Zinc proteporphyrin (ZPP) levels were elevated in 71% or cases. Low hemoglobin levels (less than 14 gm/l00 ml) were round in more than a third of the workers. While BUN and creatinine were mostly in the normal range, there - nevertheless n correlation between ZPP and both BUN and creatinine. Reduced nerve-conduction velocities were present in 25% or the group; this was not significantly different from findings in Ii control group. The data indicate that n blood level of $80{\mu}g/100\;ml$ is an inappropriate biological guide in the prevention or lead disease.

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Kinetic and Equilibrium Study of Lead (II) Removal by Functionalized Multiwalled Carbon Nanotubes with Isatin Derivative from Aqueous Solutions

  • Tahermansouri, Hasan;Beheshti, Marzieh
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3391-3398
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    • 2013
  • The carboxylated multiwall carbon nanotubes (MWCNT-COOH) and functionalized with isatin derivative (MWCNT-isatin) have been used as efficient adsorbents for the removal of lead (Pb) from aqueous solutions. The influence of variables including pH, concentration of the lead, amount of adsorbents and contact time was investigated by the batch method. The adsorption of the lead ions from aqueous solution by modified MWCNTs was studied kinetically using different kinetic models. The kinetic data were fitted with pseudo-first-order, pseudo-second-order, and intra-particle diffusion models. The sorption process with MWCNT-COOH and MWCNT-isatin was well described by pseudo-second-order and pseudo-first-order kinetics, respectively which it was agreed well with the experimental data. Also, it involved the particle-diffusion mechanism. The values of regression coefficient of various adsorption isotherm models like Langmuir, Freundlich and Tempkin to obtain the characteristic parameters of each model have been carried out. The Langmuir isotherm was found to best represent the measured sorption data for both adsorbent.

Selective Transport of Lead(II) through a Bulk Liquid Membrane Using a Cooperative Carrier Composed of Benzylaza-12-crown-4 and Oleic Acid

  • Kazemi, Sayed Yahya;Shamsipur, Mojtaba
    • Bulletin of the Korean Chemical Society
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    • 제26권6호
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    • pp.930-934
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    • 2005
  • A chloroform membrane system containing a given mixture of benzylaza-12-crown-4 and oleic acid is introduced for the selective and efficient transport of $Pb^{2+}$ ion. The transport was capable of moving metal ions ‘up-hill’. In the presence of ${S_2O_3}^{2-}$ion as a suitable metal ion acceptor in the receiving phase, the amount of lead ion transport across the liquid membrane after 150 minutes is (95.0 ${\pm}$ 1.7)%. The selectivity and efficiency of lead transport from aqueous solution containing $Tl^+,\;Ag^+,\;Mg^{2+},\;Ca^{2+},\;Co^{2+},$ $Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Hg^{2+}$ and $Cd^{2+}$were investigated. In the presence of thiosulfate as a suitable masking agent in the source phase, the interfering effects of $Ag^+\;and\;Cu^{2+}$ were diminished drastically.

다당류를 이용한 중금속 이온의 흡착특성 비교

  • 김세경;윤현식
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 춘계학술발표대회
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    • pp.386-389
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    • 2000
  • Polysaccharides are very effective adsorbents for heavy metals. In this study, the adsorption characteristics of various polysaccharides for heavy metal adsorption were investigated. Tested polysaccharides were homogeneous polysaccharides such as curdlan, chitin, starch, cellulose, Avicel, and Solka floc and heterogeneous polysaccharides such as zooglan, locust bean gum, ghatti gum, pectin, and xylan. Lead(II) adsoption characteristic on these polysaccharides followed Freundlich isotherm and the isotherm parameters were calculated. For adsorption of lead(ll), Avicel, starch, and zooglan were found to be good adsorbents.

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황화수소(H2S) 감지를 위한 아세트산 납이 침염된 폴리에스터(PET) 섬유 기반의 변색성 센서 (Polyester (PET) Fabric dyed with Lead (II) acetate-based Colorimetric Sensor for Detecting Hydrogen Sulfide (H2S))

  • 이준엽;도남곤;정동혁;정동건;안희경;공성호;정대웅
    • 센서학회지
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    • 제29권5호
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    • pp.360-364
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    • 2020
  • In this study, the colorimetric sensor, polyester (PET) fabric dyed with lead (II) acetate (Pb(C2H3O2)2), was fabricated and characterized for the detection of the hydrogen sulfide (H2S). The surface morphology of the fabric was determined using scanning electron microscope and energy-dispersive X-ray spectroscopy. The optical properties of the fabric were evaluated by measuring the variation in the blue value of an RGB sensor. The fabric showed a significant color change, high linearity (R2 : 0.98256), and fast response time (< 1.0 s) when exposed to H2S. This is because the sensor is highly porous and permeable to the gas. The fabric can not only be used as a hydrogen sulfide sensor but also be used to detect and prevent H2S influx using sticky tape on pipelines.