• Journal of the Korean institute of surface engineering
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• v.56 no.5
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• pp.299-308
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• 2023

In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo₂O₄) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo₂O₄ and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo₂O₄ electrode exhibited a specific capacitance of 1,129 Fg^-1 at a current density of 1 Ag^-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg^-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo₂O₄ electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.1
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• pp.132-137
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• 2020

Lithium secondary batteries have become an important power source for portable electronic devices such as cellular phones, laptop computers. Presently, commercialized lithium-ion batteries use a LiCoO₂ cathode. However, due to the high cost and environmental problems resulting from cobalt, an intensive search for new electrode materials is being actively conducted. Recently, solid solution LiMn_1-xNi_xO₂ have become attractive because of high capacity and enhanced safety at high voltages over 4.5 V. The Li_1.6Ni_0.35Mn_0.65O₂ compounds were conventionally prepared by a sol-gel method, which can produce the layered Li-Ni-Mn-O compounds with a high homogeneity. And by adding a graphene 2wt% the first charge-discharge voltage profiles was increased over Li_1.6Ni_0.35Mn_0.65O₂ compound. Also, the variation s of the discharge capacities with cycling showed a higher capacity retention rater. In this study, material lifecycle evaluation was performed to analyze the environmental impact characteristics of Li_1.6Ni_0.35Mn_0.65O₂ & graphene 2wt% half-cell manufacturing process. The software of material life cycle assessment was Gabi. Through this, environmental impact assessment was performed for each process. The environmental loads induced by Li_1.6Ni_0.35Mn_0.65O₂ & graphene 2wt% synthesis process were quantified and analyzed, and the results showed that the amount of power had the greatest impact on the environment.

• Journal of the Korean Geotechnical Society
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• v.15 no.4
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• pp.175-184
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• 1999

Several major land reclamation projects such as the Inchon International Airport construction, Songdo New City construction, LNG Tank and LPG storage construction are underway along the coastal line of Inchon in Korea. This study was carried out to investigate the feasible use of waste lime in the land reclamation projects. Waste lime (hydrated lime) used in this study is produced as a by-product in the manufacturing process of $Na_2CO_3$ from local chemical factory in Inchon. This study presents the characteristics of bearing capacity and settlement on the ground formed by layers of waste lime and dredged soil. From the laboratory and in-situ plate load test, the ultimate bearing capacity by in-situ test was 1.25~1.37 times higher than that of the theoretical ultimate bearing capacity. Based on the settlement analysis by Magset- II, the total settlement of layered ground steadly increased up to the ratio of waste lime depth 0.2 and therefore rapidly increased with the increase of waste lime depth. The results of the present study indicate that the ratio of waste lime depth for reclamation work is about 0.2.

• Korean Journal of Heritage: History & Science
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• v.54 no.1
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• pp.220-237
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• 2021

This study carried out the conservation treatment for the mattress put on the bed, which is one of 4 items in National Folklore Cultural Heritage, the Red-lacquered Furniture with the inlaid mother-of-pearl design used by Empress Sunjeonghyo (presumed), after identifying the characteristics of the manufacturing techniques and the used materials. And the study intends to compare it with the mattress placed in the Daejojeong in the Changdeokgung Palace in order to identify the characteristics of mattresses domestically used during the 1920s and 1930s. From the analysis of the mattress presumably used by Empress Sunjeonghyo, it was identified that the mattress frame was made of pinaceous hemlock spruce while the webbing and twine in the structural parts were made of jute. The findings are as follows: the burlap had a filling material that was made of jute; the straw mat was made from Oryza; and, the rest of the filling material was cotton. Rayon was used for the top cover while cotton was used for the bottom. As a result of research on the materials and the inner structure, it was found that mattress was manufactured in the form of the upholstery style mainly found in chairs and day-beds in Western furniture. Based on analysis results, materials identical to the original were adopted during the conservation treatment. Next, the process of dismantling, cleaning, repair, reinforcement and assembling was conducted. During the dismantling process, the top cover was newly discovered and some letters (Yokohama, Kobe, and Joseon) were found in the burlap filling, but there was no trace which can clarify its maker or production place. dry cleaning was carried out on the structural parts, filling materials, and the cover, and then the repair and reinforcement were done, preserving the existing materials in the upholstery structure and using the same materials for conservation. The webbing in the structural parts was reinforced using materials identical to the original, and the twine was used for arranging and fixing the springs into wooden frames. For the damaged cotton cloth and burlap, reinforcement materials identical to the original were put over it and sown. For the damaged area of the top cover, reinforcement cloth was cut and then added inside and the damaged area was sown. Assembling was carried out in the reverse order of the dismantling. After the burlap identical to the original material was inserted into the areas in contact with the springs and then fastened, a filling pad, reinforcement cloth, a straw mat, cotton cloth, cotton felt, wide cotton cloth for protecting the cover, and the cover were layered and fastened with tacks. The two mattresses used by Empress Sunjeonghyo differed only by the period of production and followed the same Western upholstery style consisting of the frames, filling materials, and covers. During the conservation treatment process, a velvet cover was newly discovered and the traces of repair in the past were found. Furthermore, identifying straw mats, straw bags, and straws for filling material, this study confirmed changes in the materials used according to the production environment. In the future, it is expected to see changes in the conservation materials during the conservation treatment and manufacturing techniques used for chairs and sofas in the upholstery style belonging to the modern cultural artifacts.