• Title/Summary/Keyword: Laser-induced Plasma Spectroscopy

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Non-contact Measurement and Analysis of Surface Hardness on Welding Steel using Laser-induced Breakdown Spectroscopy (레이저 유도 플라즈마 분광 기법을 이용한 용접 연강에서의 비접촉 강도 측정과 해석)

  • Kim, Joohan;Ko, Chansol
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.2
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    • pp.141-148
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    • 2014
  • In this work, effects of plasma on different hardness of welding steel using laser-induced breakdown spectroscopy were investigated. The ratios of ionic to atomic spectrum peaks were related to its material hardness. The major spectrum peak (Fe) and minor spectrum peak (Mn) were considered as monitoring elements. The stronger repulse plasma was generated, the harder material it was. The ratios of ionic to atomic spectrum peaks increased with respect to the material hardness as well. The correlation of minor spectrum peaks was stronger than that of major spectrum peaks. However, the major spectrum peaks indicated a similar trend, which could be used to estimate the hardness, too. Based on this result, the method could be used as a non-contact remote measurement of material properties.

Laser Diagnostic in a Plasma Display Panel Discharge Cell

  • Choi, Young-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.21-22
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    • 2000
  • Laser diagnostic method in a plasma display discharge cell was introduced. The information of electric field, potential and electron temperature et al. in the surface of plasma display panel can be measured using laser induced fluorescence spectroscopy. However, because of the very small discharge dimension of ${\sim}$ 100 ${\mu}m$, the measurement attempt has almost not been performed. In this paper, the direct measurement possibility of the parameters and the recent work of electric field measurement are demonstrated in the plasma display panel.

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Planar Laser-Induced Fluorescence (PLIF) Measurements of a Pulsed Electrothermal Plasma Jet

  • Kim, Jong-Uk;Kim, Youn J.;Byungyou Hong
    • Journal of Mechanical Science and Technology
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    • v.15 no.12
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    • pp.1808-1815
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    • 2001
  • The characteristics of a pulsed plasma jet originating from an electrothermal capillary discharge have been investigate using laser-induced fluorescence (LIF) measurement. Previous emission measurements of a 3.1 kJ plasma jet show trial upstream of the Mach disk the temperature and electron number density are about 14,000 K and and 10$\^$17/ cm$\^$-3/, while downstream of the Mach dick tole values are about 25,000 K and 10$\^$18/ cm$\^$-3/, respectively. However, these values are barred on line-of-sight integrated measurements that may be misleading. Hence, LIF is being used to provide both spatially and temporally resolved measurements. Our recent work has been directed at using planar laser-induced fluorescence (PLIF) imaging of atomic copper in the plasma jet flow field. Copper is a good candidate for PLIF studies because it is present throughout the plasma and has electronic transitions that provide an excellent pump-detect strategy. Our PLIF results to date show that emission measurements may give a misleading picture of the flow field, as there appeals to be a large amount of relatively low temperature copper outside the barrel shock. which may lead to errors in temperature inferred from emission spectroscopy. In this paper, the copper LIF image is presented and at the moment, relative density of atomic copper, which is distributed in the upstream of the pulsed plasma jet, is discussed qualitatively.

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Elemental Composition of the Soils using LIBS Laser Induced Breakdown Spectroscopy

  • Muhammad Aslam Khoso;Seher Saleem;Altaf H. Nizamani;Hussain Saleem;Abdul Majid Soomro;Waseem Ahmed Bhutto;Saifullah Jamali;Nek Muhammad Shaikh
    • International Journal of Computer Science & Network Security
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    • v.24 no.6
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    • pp.200-206
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    • 2024
  • Laser induced breakdown spectroscopy (LIBS) technique has been used for the elemental composition of the soils. In this technique, a high energy laser pulse is focused on a sample to produce plasma. From the spectroscopic analysis of such plasma plume, we have determined the different elements present in the soil. This technique is effective and rapid for the qualitative and quantitative analysis of all type of samples. In this work a Q-switched Nd: YAG laser operating with its fundamental mode (1064 nm laser wavelength), 5 nanosecond pulse width, and 10 Hz repetition rate was focused on soil samples using 10 cm quartz lens. The emission spectra of soil consist of Iron (Fe), Calcium (Ca), Titanium (Ti), Silicon (Si), Aluminum (Al), Magnesium (Mg), Manganese (Mn), Potassium (K), Nickel (Ni), Chromium (Cr), Copper (Cu), Mercury (Hg), Barium (Ba), Vanadium (V), Lead (Pb), Nitrogen (N), Scandium (Sc), Hydrogen (H), Strontium (Sr), and Lithium (Li) with different finger-prints of the transition lines. The maximum intensity of the transition lines was observed close to the surface of the sample and it was decreased along the axial direction of the plasma expansion due to the thermalization and the recombination process. We have also determined the plasma parameters such as electron temperature and the electron number density of the plasma using Boltzmann's plot method as well as the Stark broadening of the transition lines respectively. The electron temperature is estimated at 14611 °K, whereas the electron number density i.e. 4.1 × 1016 cm-3 lies close to the surface.

Hardness Analysis of Surface Treated Magnesium Alloy using Laser Induced Breakdown Spectroscopy (레이저 플라즈마 분광분석법을 이용한 표면처리 된 마그네슘 합금 표면의 경도 분석)

  • Kang, Dongchan;Kim, Joohan
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.6
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    • pp.625-631
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    • 2015
  • The hardness of surface treated magnesium alloy was evaluated using laser induced breakdown spectroscopy. The surface of the specimen was hardened mechanically, and the hardness profiles were measured using a traditional measurement technique. A laser beam was irradiated to generate a plasma, and the peaks of the components of the specimen were analyzed. A wavelength of 333.66 nm and 293.65 nm were selected as the atomic and ionic peaks, respectively. The ratios of the ionic peak to the atomic peak were obtained so as to compare the hardness profile. As the depth increased, the ratio decreased. These results are in good agreement with the previous hardness measurement results. It can be considered that this technique could be applied for remote and time-efficient hardness measurement.

Spark-induced Breakdown Spectroscopy System of Bulk Minerals Aimed at Planetary Analysis (스파크 유도 플라즈마 분광 시스템을 이용한 우주탐사용 암석 분석연구)

  • Jung, Jaehun;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.12
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    • pp.1013-1020
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    • 2020
  • Spark-induced breakdown spectroscopy (SIBS) utilizes an electric spark to induce a strong plasma for collecting atomic emissions. This study analyses the potential for usinga compact SIBS instead of conventional laser-induced breakdown spectroscopy (LIBS) in discriminating rocks and soils for planetary missions. Targeting bulky solids using SIBS has not been successful in the past, and therefore a series of optimizations of electrode positioning and electrode materials were performed in this work. The limit of detection (LOD) was enhanced up to four times compared to when LIBS was used, showing a change from 78 to 20 ppm from LIBS to SIBS. Because of the higher energy of plasma generated, the signal intensity by SIBS was higher than LIBS in three orders of magnitude with the same spectrometer setup. Changing the electrode material and locating the optimum position of the electrodes were considered for optimizing the current SIBS setup being tested for samples of planetary origin.

The Study of Two-dimensional Chemical Distribution about Soil using Laser Spectroscopy (레이저 분광법을 활용한 토양 2차원 화학적 분포도 검출 연구)

  • Yang, Jun-Ho;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.45 no.6
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    • pp.523-530
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    • 2017
  • Laser-Induced Breakdown Spectroscopy (LIBS) which a plasma is irradiated at a specific wavelength depending on the material when a high-energy laser is irradiated, and a Raman spectroscopy which measures rotation and vibration in molecules as light-scattering phenomenon occurs, are attracting attention as a space exploration technology because of the advantages of high accuracy and real-time analysis, and the ability to perform long-range detection. In this study, the tendency of the laser spectrum according to the change of the soil component was analyzed by laser spectroscopy and the two - dimensional chemical distribution was conducted based on the trend of laser spectrum. We have also established the environment of Mars (4-7 torr) and lunar atmosphere (<1 torr) in experimental setup, to prove that it is possible to measure by difference of soil chemical composition using LIBS and Raman spectroscopy even in artificial space environment.

Qualitative and Quantitative Analysis of Space Minerals using Laser-Induced Breakdown Spectroscopy and Raman Spectroscopy (레이저 유도 분해 분광법과 라만 분광법을 이용한 우주 광물의 정성 및 정량 분석 기법)

  • Kim, Dongyoung;Yoh, Jack J.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.6
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    • pp.519-526
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    • 2018
  • In order to analyze space resources, it had to be brought to earth. However, using laser-induced breakdown spectroscopy(LIBS) and Raman spectroscopy, it is possible to analyze qualitative and quantitative analysis of space minerals in real time. LIBS is a spectroscopic method in which a high energy laser is concentrated on a material surface to generate a plasma, and the emitted light is acquired through a spectroscope to analyze the atomic composition. Raman spectroscopy is a spectroscopic method that analyzes the molecular structure by measuring scattered light. These two spectroscopic methods are complementary spectroscopic methods for analyzing the atoms and molecules of unknown minerals and have an advantage as space payloads. In this study, data were analyzed qualitatively by using principal component analysis(PCA). In addition, a mixture of two minerals was prepared and a quantitative analysis was performed to predict the concentration of the material.

Characteristics of Laser-Induced Breakdown Spectroscopy (LIBS) at Space Environment for Space Resources Exploration (우주 자원 탐사를 위한 레이저 유도 플라즈마 분광분석법의 우주 환경에서의 특성 분석)

  • Choi, Soo-Jin;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.4
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    • pp.346-353
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    • 2012
  • The Laser-Induced Breakdown Spectroscopy (LIBS) has great advantages as an analytical technique, namely real-time analysis without sample preparation, ideal for mobile chemical sensor for space exploration. The LIBS plasma characteristics are strongly dependent on the surrounding pressure. In this study, seven types of target (C, Ti, Ni, Cu, Sn, Al, Zn) were investigated for their elemental lifetime. The target was located in vacuum chamber which has the pressure range of 760 to $10^{-5}$ torr. As the pressure is decreased, the elemental lifetimes of carbon and titanium declined, while all other targets showed increased lifetimes until reaching 1 torr and declined with continued pressure decrease. The boiling point and electronegativity amongst the physicochemical properties of the samples are used to explain this peculiarity.

Forensic Classification of Latent Fingerprints Applying Laser-induced Plasma Spectroscopy Combined with Chemometric Methods (케모메트릭 방법과 결합된 레이저 유도 플라즈마 분광법을 적용한 유류 지문의 법의학적 분류 연구)

  • Yang, Jun-Ho;Yoh, Jai-Ick
    • Korean Journal of Optics and Photonics
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    • v.31 no.3
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    • pp.125-133
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    • 2020
  • An innovative method for separating overlapping latent fingerprints, using laser-induced plasma spectroscopy (LIPS) combined with multivariate analysis, is reported in the current study. LIPS provides the capabilities of real-time analysis and high-speed scanning, as well as data regarding the chemical components of overlapping fingerprints. These spectra provide valuable chemical information for the forensic classification and reconstruction of overlapping latent fingerprints, by applying appropriate multivariate analysis. This study utilizes principal-component analysis (PCA) and partial-least-squares (PLS) techniques for the basis classification of four types of fingerprints from the LIPS spectra. The proposed method is successfully demonstrated through a classification example of four distinct latent fingerprints, using discrimination such as soft independent modeling of class analogy (SIMCA) and partial-least-squares discriminant analysis (PLS-DA). This demonstration develops an accuracy of more than 85% and is proven to be sufficiently robust. In addition, by laser-scanning analysis at a spatial interval of 125 ㎛, the overlapping fingerprints were separated as two-dimensional forms.