• Journal of Photoscience
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• 제10권1호
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• pp.97-104
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• 2003

The excitation wavelength dependence of laser ablation dynamics of an azobenzene-containing urethane-urea copolymer film was investigated by measuring the laser fluence dependence of etch depth, transient absorbance change at each excitation wavelength, and transient absorption spectra. Moreover expansion/contraction dynamics was studied by applying nanosecond time-resolved interferometry. The threshold was determined at several excitation wavelengths from etch depth measurement, while time-integrated absorbance was obtained under excitation conditions. The photon energy required to remove the topmost of surface layer of the film did not .depend on excitation wavelength, and the penetration depth of excitation pulse dominated the etch depth. When the excitation wavelength was longer than 500 nm, permanent swelling was clearly observed but not for shorter wavelength excitation. In the latter case, photoisomerization occurred during excitation and the following photoreduction may play an important role. On the basis of the observations made in this study, a photochemical and photothermal mechanisms can explain mostly the short and long wavelength excitation results, respectively.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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• pp.13-21
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• 1997

Excitations of eight pumping transitions for nitric oxide fluorescence imaging are analyzed under equivalent experimental conditions to determine the detection. Frequency mixed dye laser pumping, 1st anti-Stokes $H_2$ Raman of KrF excimer laser pumping and ArF excimer laser pumping show good sensitivities.

• 한국광학회지
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• 제16권5호
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• pp.450-455
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• 2005

본 논문에서는 기존의 TE(transverse excitation) 방식과 달리 LE(longitudinal excitation) 방식을 사용하여 유전체 표면을 따라 발생하는 미끄럼 방전에 의해서도 질소레이저 발진이 가능함을 보였다. 이는 방전여기 방식인 엑시머 레이저 등의 기체 레이저에서도 미끄럼 방전을 이용한 레이저 발진이 가능함을 의미한다. 또한, 레이저빔의 형상이 공진기의 원둘레를 따라 발진이 되어 빔이 환 모양으로 출력이 됨을 보임에 따라 직사각형이나 타원형의 빔 등 폐곡선을 이루는 어떤 특정한 형태의 질소레이저 빔도 만들어 낼 수 있다는 가능성을 보였다. 레이저의 동작특성인 출력과 안정성은 TE 방식에 비해서도 뒤떨어지지 않는 다는 것을 알 수 있었으며, 공진기의 지름이 2배 증가하면 미끄럼 방전이 일어나는 표면이 2배, 체적은 4배 증가하여 그에 따른 방전간극과 유동률이 비례관계에 있음을 알 수 있었다.

• 한국광학회:학술대회논문집
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• 한국광학회 1989년도 제4회 파동 및 레이저 학술발표회 4th Conference on Waves and lasers 논문집 - 한국광학회
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• pp.36-38
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• 1989

We have developed Magnetic Pulse Compression System to realize repetitive excimer laser excitation. The principle of this system is to use the large change in permiability owing to the nolinear characteristics of ferro-magnetic material (Metglas2605s-2 metal ribon). Prior to the laser operation, the MPC system was tested with a dummy load (5$\Omega$) and laser head. Laser head has a discharge volume of 1.0 (w) x 2.0 (h) x 20.0(1) cm. This MPC system compressed a 6.2us (FWHM), 80 A pulse into a 0.4us(FWHM), 1.3kA pulse.

• 방사성폐기물학회지
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• 제18권4호
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• pp.497-508
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• 2020

In the geochemical field, the chemical speciation of hexavalent uranium (U(VI)) has been widely investigated by performing measurements to determine its luminescence properties, namely the excitation, emission, and lifetime. Of these properties, the excitation has been relatively overlooked in most time-resolved laser fluorescence spectroscopy (TRLFS) studies. In this study, TRLFS and continuous-wave excitation-emission matrix spectroscopy are adopted to characterize the excitation properties of U(VI) surface species that interact with amorphous silica. The luminescence spectra of U(VI) measured from a silica suspension and silica sediment showed very similar spectral shapes with similar lifetime values. In contrast, the excitation spectra of U(VI) measured from these samples were significantly different. The results show that distinctive excitation maxima appeared at approximately 220 and 280 nm for the silica suspension and silica sediment, respectively.

• 한국광학회지
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• 제3권2호
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• pp.117-122
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• 1992

2색 3-단계 공명이온화 구도를 이용하여 수은 도우이원소들을 선택적으로 광이온화시켰다. 중간 여기 준위로서 $6^3P_1$ 및 $6^1D_2$를 선택했으며, 이때 사용된 레이저파장은 253.7nm(1차 여기)와 313.2nm(2차 여기 및 이온화)이었다. 동위원소들의 선택적 여기는 선폭 ~700MHz의 단일종모드 펄스 레이저를 사용한 1차 여기단계에서 이루어졌으며, 2차 여기 및 이온화 단계에서는 비교적 큰 선폭(~5GHz)의 레이저를 사용하였다. 본 연구에서는 time-of-flight 질량분석기를 사용하여 질량 스펙트럼을 실시간으로 얻었으며. 이를 이용하여 레이저 세기가 수은동위원소 선택성에 미치는 영향을 분석하였다.

• 한국광학회:학술대회논문집
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• 한국광학회 2002년도 하계학술발표회
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• pp.248-249
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• 2002

The gaseous molecular condensation retardation by laser excitation has been known, but with limited success. Condensation inhibition between the gas phase molecules by laser excitation was clearly shown in many experiments.(1)-(2) However, surface condensation inhibition of the excited molecules has been controversial for the last several decades.(3)-(4) In 1994, S. J, Sibener and Y. T. Lee published an experimental evidence of the internal energy dependence of the surface condensation of gaseous $SF_{6}$ and $CCl_4$ molecules. (omitted)

• 한국진공학회지
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• 제9권1호
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• pp.76-80
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• 2000

CF & $CF_2$ radicals in a $C_4F_8$ inductively coupled plasma were observed with laser induced fluorescence. 251.9nm UV laser was used for the $CF_2$ excitation and 265.3nm UV emitted light for the detection which has the maximum intensity among many induced fluorescence lights. In the case of CF radical detection, 232.9nm UV laser was used for the excitation and 247.6nm for the detection. $CF_2$ radical density increased toward substrate, while CF radical had its maximum at about 10nm away from the substrate. The atomic fluorine density which was studied by the actinometry increased as the position moves away from the substrate. This phenomena was thought to have a close relation with the polymer growth on the wafer. When the bias voltage increased, $CF_2$ , CF radicals decreased while the atomic fluorine increased tio some extent and then decreased, which was thought to be due to the change in the ionization and dissociation.

• Journal of the Optical Society of Korea
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• 제1권1호
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• pp.10-14
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• 1997

Single pulse laser excitation at 656 nm and successive pulse excitation at 635.2 and 648.4 nm produced blue emission at 480 nm by two-step upconversion process in Tm/sup 3+/:LaF/sub 3/. The excited-state absorption cross-section of the /sup 3/F/sub 4/ to /sup 1/G/sub 4/ transition was estimated by a looping mechanism with cross-relaxation processes. The dynamics of up-conversion andthe possibility of the photon avalanche by a pulse laser excitation were studied by numerical simulation with the rate equation model.

• 한국광학회지
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• 제11권4호
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• pp.289-293
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• 2000

다이오드 레이저 뒷면 여기 방식을 이용하여 발진 파장이 $2.02\mu\textrm{m}$인 중적외선 Tm:YAG 레이저를 제작하고, 출력 특성을 조사하였다. 레이저의 출력은 Tm:YAG 결정의 온도에 민감하게 변화하였으며, 레이저의 출력경이 곡면경인 경우에 평면적인 격우보다 더 큰 출력을 얻을 수 있었다. 곡면경을 사용하고 Tm:YAG 결정을 지지하는 구리 지지대의 온도를 $6^{\circ}C$로 낮추었을 때, 최고 1.2W의 출력을 얻을 수 있었다. 이 때, 문턱 여기 출력은 약 1.6W이었고, 기울기 효율(slope efficiency) 및 광학 효율(optical to optical efficiency)은 각각 29%와 20%이었다.