• Bulletin of the Korean Chemical Society
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• v.25 no.2
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• pp.203-206
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• 2004

The kinetics of reactions between Z-aryl thiophene-2-carbodithioates and X-pyridines in acetonitrile at 60.0 $^{\circ}C$ have been investigated. The Bronsted plots obtained for the pyridinolysis of aryl thiophene-2-carbodithioates are curved, with the center of curvature at $pK_a$ ~ 5.2 ($pK_a^{\circ}$). The Bronsted plots for these nucleophilic reactions show a change in slope from a large ( ${\beta}_X{\cong}$0.78-0.87) to a small ( ${\beta}_X{\cong}$0.33-0.35) value, which can be attributed to a change in the rate-determining step from breakdown to formation of a zwitterionic tetrahedral intermediate in the reaction path as the basicity of the pyridine nucleophile increases. A clear-cut change in the crossinteraction constants, ${\rho}_{XZ}$, from +0.92 to -0.23 supports the proposed mechanistic change. The breakpoint at $pK_a$ = 5.2 for R = thiophene ring in the present work is in agreement with those for the pyridinolysis of R = Me and 2-furyl, and attests to the insignificant effects of acyl group, R, on the breakpoint.

• Journal of the Korean Society for Precision Engineering
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• v.16 no.2 s.95
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• pp.123-129
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• 1999

Ball-end milling process is widely used in the die and mold manufacturing because of suitable one for the machining of free-form surface. During the process, the pencil cutting operation can be adopted before finish cut to eliminate overload in uncut area caused by large diameter of ball-end mill. The ball-end mill cutter for the pencil cutting is easily deflected by cutting force due to the long and thin shape, and the tool deflection in pencil cutting is one of the main reason of the machining errors in a free-form surface. The purpose of this study is to find the characteristics of deflected cutter trajectory by constructing measurement system with eddy-current sensor. It was found that the severe reduction of corner radius produced the overcut during the plane cutting. Up cutting method induced the overcut both plane and slope cutting, but down cutting one induced the undercut. From the experiments, down cutting with upward cutting path can generate the small undercut surface.

• Geomechanics and Engineering
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• v.38 no.4
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• pp.367-380
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• 2024

In this study, a prediction model for the cutting force evolution in brittle rocks was developed. This model is based on indentation tests using a conical pick at a cutting depth of 9 mm. The behavior of the indentation mechanism was analyzed in three phases by using Evans' cutting mode. The peak values in the force history identified these phases. The variation in the local strength of the rock caused a large offset in the model prediction of chipping. Regression analyses showed that there is a strong power relationship between the upper bound of the cutting force along with chipping and depth of cut. The slope of the three crushing phases has been found to increase sequentially (α₁<α₂<α₃). In addition, a positive correlation existed between the Schmidt hardness and brittleness index that affects the lower and upper bounds of chipping. Consequently, the results clearly demonstrate that the new model can reasonably predict the evolution of the cutting force based on experimental data. These results would be beneficial for engineers to design and select the optimum excavation machine to reduce mechanical vibration and enhance cutting efficiency.

• The Journal of Engineering Geology
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• v.14 no.4 s.41
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• pp.487-498
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• 2004

There is an increasing trend of construction works in mountainous areas by the urban development in Busan that is mainly composed of mountains. The study area, Hwangryeong Mt., is one of developing sites in the urban area, too. Landslides and cut-slope failures that occur large damages of human beings and the properties are influenced by soil characteristics as well as rock properties. This study analyzed geotechnical characteristics of soil dependent on geology at Hwangryeong Mt. where a large slope failure had been occurred in 1999. Geology of the study area is composed of the Cretaceous sedimentary rocks and volcanic rocks. Soil layer of the slopes can be grouped into sand mixed with clay and silt. The cohesion is plotted between $0.001\;and\;0.066kg/cm^2$. The friction angles are distributed in the ranges between $32^{\circ}\;and\;39^{\circ}$, meaning soil bearing a high friction angle. The permeability coefficients are plotted between $2.34\times10^{-4}cm/sec\;and\;2.58\times10^{-2}cm/sec$, indicating fine sand and loose silt with a medium grade of permeability. The sedimentary rocks area shows relatively higher permeability coefficients than those volcanic rocks area.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.10 no.2
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• pp.1-15
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• 2007

A variety of revegetation methods are being utilized and developed. However, most of revegetation methods used on highway slopes in Korea are based on foreign-introduced plant varieties to stabilize road surfaces and to administer afforestation for surface covering at an earlier phase. Therefore. it results in various problems. such as failure to achieve harmony with the surrounding vegetation and 10 cause re-denudation of slopes as the foreign-in introduced plant varieties wane out from 2~3 years after hydro-seeding, etc. In addition, some of the revegetation plants seeded in the earlier phase grow excessively high, thus causes successional problems, such as to inhibit the invasion of the secondary vegetation from the surrounding areas, etc. Therefore, in this study, 160 slopes located in the nationwide express highways have been investigated and analyzed in order to produce basic data for restoration of ecological environment in slopes created on a long-term basis by investigating and analyzing locational characteristics of cut and filled slopes in express highways, status of revegetation methods, characteristics of soil and plant-ecological environment. 1. Investigation on cut and embanked slopes in express highways was carried out in the total of 160 locations, which include 108 cut slopes and 52 embanked slopes. As a whole, the most frequently used revegetation method was seed spray, which was found to be used in the total of 55 target slops investigated. 2. Planting method of Wistaria floribunda applied to some of the blasted rock zones was found to cause damages as Wistaria floribunda trailed up the surrounding vegetation and the secondary invaded trees. In order to prevent this, this method must be used only in the lowest parts of large-sized slopes. Also, it will be required to administer continuous management and maintenance in the areas already planted with this plants. 3. The areas of blasted rock and ripping rock slopes were applied with coir net (net + seeding) method. However, many of these areas failed in achieving ground covering. Most areas where revegetation was in progress, they were covered with Eragrostis curvula(Weeping lovegrass) only. In areas with soil, such as decomposition of granite, where afforestation is difficult. In this slopes, soil base must be improved by hrdroseeding with thin-layer vegetation base application methods in order to achieve success in afforestation with native plants. 4. Woody species, rather than herb species, are more helpful in stabilization of slope surfaces. Therefore, it is important to be able to grow and protect woody species on highway slopes. Growth of woody vegetation is most largely influenced by soil depth. Thus, when hydro-seeding woody plants, it is recommended to apply at the upper layer of the slopes, which is capable to sufficiently provide the fundamentals required in plant growth.

• Korean Journal of Agricultural Science
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• v.45 no.4
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• pp.847-857
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• 2018

Recently, customers' demand and attention to dried agricultural products or foods have increased due to their convenience and nutritional values. Conventional drying methods such as solar drying and hot air drying have been most widely used for producing a large amount of dried agricultural products; however, those methods require quite a long time and high energy consumption. To compensate for these issues associated with conventional methods, dielectric heating such as microwave and radio frequency heating has been used as a supplemental method in the drying procedure. This study investigated the microwave drying characteristics of squash slices with different thicknesses under different microwave power intensities and determined the best drying model that could precisely describe the experimental drying curves of the squash slices. The squash was cut into slices with two different thicknesses (5 and 10 mm), and then, they were dried under different microwave power intensity ranges between 90 and 900 W with an increase interval of 90 W. Six drying models were tested to evaluate the fit to the experimental drying data, and the effective moisture diffusivity ($D_{eff}$) values of the squash slices under microwave drying were determined. The results clearly show that as the microwave power was increased, the drying time of both squash slices was significantly decreased, and the slope of the drying rate increased. The effective moisture diffusivity was also significantly related with the microwave power intensities and thicknesses of the slices. In addition, the Page model was most suitable to delineate the drying curves of both squash slices under different microwave power intensities.

• Journal of the Korean GEO-environmental Society
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• v.24 no.11
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• pp.19-24
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• 2023

Ground anchor has been widely used specially for maintaining stability on reinforced cut slope in expressway. While the durability of the ground anchors should be ensured over the service life. However, the long-term loss of tensile force has occurred in most of field-installed anchors. Main causes are not clearly identified and very few studies have been made for analyzing long-term behavior of ground anchor in slopes. In this study, full-scale model tests and long-term measurements were made to obtain the load-displacement data and identified the causes of the long-term behaviors of ground anchor. As a result, the bond strength decreases exponentially with increasing water-binder ratio. Especially, groundwater is the most influencing factor to the bond strength. In the long-term behavior, the load decreases sharply until the initial settlement stabilized, and thereafter the tension force decreases constantly.

• Tunnel and Underground Space
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• v.16 no.2 s.61
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• pp.109-134
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• 2006

Rocks undergo weathering processes influenced by changing in pressure-temperature condition, atmosphere, underground water, and rainfall. The weathering processes change physical and chemical characteristics of the rocks. Once the rocks are weathered, the characteristics of them are changed and, because of the changing, several disadvantages such as rock slope failures and underground water spouts are can occur. Before we cut a large rock slope, therefore, we must analyze current weathering conditions of rocks and predict weathering processes in the future. Through the results of such analyses, we can judge reinforcement works. In order to comply with such requests, chemical weathering sensitivity analysis which was analyzed from chemical weathering velocities and other characteristics of rocks has been applied in several prior construction works in Korea. But, It is defective to use directly in engineering fields because it was developed for soils(not rocks), it has too mny factors must be considered and the relationships between the factors are not clear, and it is hard to explain the weathering processes in engineering time range. Besides above, because it has been used for isotropic rocks, this method is hard to apply to anisotropic rocks such as sedimentary rocks. Acceding to studies from morphologists (e.g. Oguchi et al., 1994; Sunamura, 1996; Norwick and Dexter, 2002), time dependent strength reduction influenced by weathering shows a negative exponential function form. Appling this relation, one can synthesize the factors which influence the weathering processes to the strength reduction, and get meaningful estimates in engineering viewpoint. We suggest this weathering sensitivity characterization method as a technique that can explain time dependent weathering sensitivity characteristics through strength changes and can directly applied the rock slope design.

• Tunnel and Underground Space
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• v.17 no.5
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• pp.350-359
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• 2007

Most large cut slopes of open pit mines, roadways, and railways are steeply inclined and composed with rocks that do not contain soils. However, these rock slopes suffer both weathering and fragmentation. In the case of steep slopes, falling rock and collapse of a slope may often occur due to surface erosion. Cast-in place concrete and rubble work are the most widely used earth structure-based pressure supports that act as restraints against the collapse of the rock slope. In order to overcome the shortcomings of conventional retaining walls, a segmental grid retaining wall is being used with connects precasted segments to construct the wall. In this study, laboratory model test was conducted to estimate deformation behavior of segmental grid retaining wall with configuration of rear strecher, height and inclination of the wall. In order to examine the behavior characteristics of a segmental grid retaining wall, this research analyzes the aspects of spacial displacement through relative displacement according to change in the inclination of the wall. Also, the walls behavior according to the formation and status of the rear stretcher which serves the role of transferring the load from the header and the stretcher which make up the wall, the displacement of backfill materials in the wall, and the location of the maximum load were surveyed and the characteristics of displacement in the segmental grid retaining wall were observed. The test results of the segmental grid retaining wall showed that there was a sudden increase in failure load according to the decrease in the wall's height and the size of the in was greatly decreased. Furthermore, it revealed that with identical inclination and height, the structure of the rear stitcher did not greatly affect the starting point or size of maximum horizontal displacement, but rather had a stronger effect on the inclination of the wall.

• Journal of the Korean GEO-environmental Society
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• v.18 no.7
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• pp.13-20
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• 2017

Soil nailing is ground reinforcement method using the shear strength of ground and the pullout shear resistance force of nail. It is mainly used for reinforcement of cut slopes, earth retaining structures and retaining walls, etc. It may be designed considering the pullout resistance of nail in the case of earth retaining structure and retaining wall, but it should be designed considering not only pullout resistance but also shear and bending resistance in the case of slope. However, conservative designs considering only pullout resistance are being done and most of the studies are about increasing pullout resistance by improving of material, shape and construction method of nail. Actually, Shear bending deformations occur centering on the active surface in ground reinforced with the nail. The grout with relatively low strength is destroyed and separated from the reinforcing material. As a result, the ground is collapsed while reducing the frictional resistance rapidly. Therefore, it is necessary to develop the method to increase the shear resistance while preventing separation of nail and grout body. In this study, an experimental study was conducted on new soil nailing method which can increase shear resistance by forming protrusions through pressurized grouting after installing a packer on the outside of deformed bar.