• Title/Summary/Keyword: Large Surface Area

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Application of Surface Runoff-River flow Model to Small- and Large-Size Catchment Areas (소유역 및 대유역 홍수유출모형의 적용)

  • Yoo, Dong-Hoon
    • Journal of Korea Water Resources Association
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    • v.36 no.1
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    • pp.87-104
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    • 2003
  • A numerical model of surface runoff and river flow has been applied to small- and large-size catchment areas in order to investigate the physical characteristics of river flow during flood period. Several refinements are made on the existing model SIRG-RS for the ways of rainfall input through surface runoff, river junction treatment and the computation of river flow on steep slope. For the computation of frictional forces, employed is the power law of friction factor which is a function of Reynolds number and relative roughness height. The empirical equation of friction factor is developed using recent field data as well as laboratory data. The refined model has been applied to small-size catchment area as well as large-size catchment area, and the computation results are found in good agreement with the observations in both cases.

Template-directed Atomic Layer Deposition-grown $TiO_2$ Nanotubular Photoanode-based Dye-sensitized Solar Cells

  • Yu, Hyeon-Jun;Panda, Sovan Kumar;Kim, Hyeon-Cheol;Kim, Myeong-Jun;Yang, Yun-Jeong;Lee, Seon-Hui;Sin, Hyeon-Jeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.239.1-239.1
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    • 2011
  • Dye sensitized solar cells (DSC) are promising devices for inexpensive, nontoxic, transparent, and large-scale solar energy conversion. Generally thick $TiO_2$ nanoporous films act as efficient photoanodes with their large surface area for absorbing light. However, electron transport through nanoparticle networks causes the slowdown and the loss of electron transport because of a number of interparticle boundaries inside the conduction path. We have studied DSCs with precisely dimension-controlled $TiO_2$ nanotubes array as photoanode. $TiO_2$ nanotubes array is prepared by template-directed fabrication method with atomic layer deposition. Well-ordered nanotubes array provides not only large surface area for light absorbing but also direct pathway for electrons with minimalized grain boundaries. Large enlongated anatase grains in the nanotubes could enhance the conductivity of electrons, but also suppress the recombination with holes through defect sites during diffusion into the electrode. To study the effect of grain boundaries, we fabricated two kinds of nanotubes which have different grain sizes by controlling deposition conditions. And we studied electron conduction through two kinds of nanotubes with different grain structures. The solar cell performance was studied as a function of thickness and grain structures. And overall solar-to-electric energy conversion efficiencies of up to 7% were obtained.

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A Study on the Improvement of Efficiency by Scribing Transparent Conducting Oxide of Dye-sensitized Solar Cell (염료감응형 태양전지의 투명 전극 식각을 통한 효율 향상 연구)

  • Seo, Hyun-Woong;Son, Min-Kyu;Lee, Kyoung-Jun;Kim, Jeong-Hoon;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.416-418
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    • 2008
  • Dye-sensitized solar cell using transparent conducting oxide as electrode has large resistance such as surface resistance, charge transportation impedance in counter electrode and electrolyte, impedance between each interface. Among that resistances, surface resistance of transparent conducting oxide is relatively large. So the change of transparency has a large effect on internal resistance of dye-sensitized solar cell. Consequently, that change cause to increase or decrease the conversion efficiency. We tried to reduce the surface resistance by laser-scribing. The active area is seperated from total transparent conducting oxide by Nd:YAG laser-scribing. As a result, we achieved the improvement of efficiency about 7% and 11% in case of $0.25cm^2$ and $1.00cm^2$ dye-sensitized solar cells.

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Oxidation Behaviors of Porous Ferritic Stainless Steel Support for Metal-supported SOFC

  • Moon, I.J.;Lee, J.W.;Cho, H.J.;Choi, G.M.;Sohn, H.K.
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.196-200
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    • 2010
  • Recently porous metal has been used as supporting metal in planar type SOFC. In order to search optimum alloys for porous metal support and estimate the stability of metal-supported SOFC at high temperature, it is necessary to investigate the oxidation behaviors of porous material for metal support in comparison with dense material. Oxidation tests of porous and dense stainless steels were conducted at $600^{\circ}C$ and $800^{\circ}C$. Since the specific surface area of porous material is much larger than that of dense material, surface area should be considered in order to compare the oxidation rate of porous stainless steel with that of dense stainless steel. The specific surface area of porous body was measured using image analyzer. The weight gain of porous stainless steel was much greater than those of dense stainless steels due to its larger specific surface area. considering the specific surface area, the oxidation rate of porous stainless steel is likely to be the same as that of dense stainless steel with the same surface area. The change in chromium content in stainless steel during oxidation was also investigated. The experimental result in chromium content in stainless steel during oxidation corresponded with the calculated value. While the change in chromium content in dense stainless steel during oxidation is negligible, chromium content in porous stainless steel rapidly decreases with oxidation time due to its large specific surface area. The significant decrease in chromium content in porous stainless steel during oxidation may affect the oxidation resistance of porous stainless steel support and long term stability of metal-supported SOFC.

Improvement of Form Accuracy of Micro-Features on Thin, Large-area Plate using Fast Depth Adjustment in Micro-grooving (대면적 가공물의 마이크로 그루빙에서 고속 절삭 깊이 제어를 통한 미세형상의 정밀도 향상)

  • Kang, Dong Bae;Son, Seong Min;Lee, Hyo Ryeol;Ahn, Jung Hwan
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.3
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    • pp.408-413
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    • 2013
  • Micro-features such as grooves and lenses, which perform optical functions in flat displays, should be manufactured with a good form accuracy because this is directly related to their optical performance. As the size of the display increases, it is very difficult to maintain a high relative accuracy because of the inherent geometric errors such as the waviness of a large-area plate. In this paper, the optical effect of these geometric errors is investigated, and surface-referenced micro-grooving to measure and compensate for such geometric errors on line is proposed to improve the form accuracy of the micro-grooves. A PZT-based fast depth adjustment servo system is implemented in the tool holder to maintain a uniform groove depth in reference to the wavy surface. Through experiments, the proposed method is shown to be an efficient way to produce high-quality micro- grooves on a wavy die surface.

Incorporation of Manganese Oxide Nanoparticles Into Polyaniline Hollow Nanospheres and Its Application to Supercapacitors

  • Kwon, Hyemin;Ryu, Ilhwan;Han, Jiyoung;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.295-295
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    • 2013
  • Supercapacitors with higher energy and power density are attracting growing attention for their wide range of potential applications such as portable electronic equipments, hybrid vehicle and cellular devices. In various classes of materials for supercapacitors, the redox pseudocapacitive materials such as conducting polymers and metal oxides have been most widely studied recently. The nanostructuring of the electrode surface has also been focused on since it can provide large surface area and consequently easy diffusion of ions in the capacitors. Among the active materials, in this work, we have used polyaniline (PANi) and manganese oxide ($MnO_2$). PANi is one of the promising electrode and active materials due to its desirable properties such as high electrochemical activity, high doping level and stability. $MnO_2$ is also widely studied material for supercapacitors since it is relatively cheap and environmentally friendly. In this work, we fabricated PANi hollow nanospheres by polymerizing aniline monomers on the polystyrene (PS) nanospheres and then dissolving the inner PS spheres. This nanostructuring of the PANi surface can provide large surface area and hence easy diffusion of electrolyte ions. We also incorporated $MnO_2$ nanoparticles into the PANi hollow nanospheres and investigated its electrochemical properties. It is expected that the combination of these two active materials with slightly different working potential windows show synergetic effects such as broader working potential range and enhanced specific capacitance.

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A Study on the Landforms Near of Mooseom Village, Naeseongcheon (내성천 무섬마을 인근의 하천 지형 특성에 대한 연구)

  • Kim, Jong Yeon;Shin, Won Jeong
    • Journal of The Geomorphological Association of Korea
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    • v.26 no.3
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    • pp.1-17
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    • 2019
  • Naeseongcheon is Korea's representative sand stream, and it is one of the regions where the dynamic changes of various river topography developed in the sand bed can be observed. Most of drainage area near of the river channel are formed with Daebo granite, and the granite weathering zone is developed at the surface of hill. Due to the massive input of sediment flux, braided channel reaches are found some of the area. However, the results of the study shows that the alluvial layer is very thin in some reaches. In addition, bedrock or weathered materials, including the Tors are exposed at the channel beds. On the other hand, during the flood, a considerable amount of sediment was introduced, causing the massive sediment to be close to 1m thick. In addition, despite the short distance, large changes in the particle size and sorting of the sediment were observed. Vegetation, on the other hand, has been shown to have a significant effect on the development of the overall channel bed topography, as reported in previous studies. In small floods or low water levels, vegetation's protection role of the surface is predominates, but in large flood conditions, herbaceous loss at the surface of the point bars, accelerating the erosion of surface.

A Study on the Development of Insulated Electrode Tip for Spot Welding to Reduce Indentation (점용접 시 압흔 깊이 감소를 위한 절연팁 개발에 관한 연구)

  • 서승일;장상길
    • Journal of Welding and Joining
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    • v.21 no.1
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    • pp.42-47
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    • 2003
  • Stainless rolling stocks are usually fabricated by spot welding process without painting. Indentation on the surface of the car body after spot welding injures the beauty of the stainless rolling stocks. In this study, insulated electrode tips to reduce the indentation are developed and applied to the actual spot welding works. The developed tips are composed of head, neck, hole for cooling water, body and resistance material. They provide large surface contact area with the base materials during spot welding and enhance the current density by necking. Experimental results using the developed tips show that small indentation and sufficient tensile shear strength is produced due to large contact area and enhanced current density.

Effect of Capsule Shape on Heat Storage (캡슐 형상이 축열에 미치는 영향)

  • 정재동
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.11
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    • pp.964-971
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    • 2002
  • A numerical investigation of the constrained melting of phase change materials within spherical-like capsule is presented. A single-domain enthalpy formulation is used for simulation of the phase change phenomenon. The solution methodology is verified with the melting process inside an isothermal spherical capsule. Especially, the effect of capsule shape on the heat storage is emphasized. Two shape parameters are considered from the real capsule shape showing good characteristics of heat storage and the effect of these parameters is examined. Early during the melting process, the conduction mode of heat transfer is dominant. Thus the capsule shape with large surface area is desirable. However, the capsule shape with large surface area plays negative role on the strength of buoyancy-driven convection that becomes more important as melting continues.