• Title/Summary/Keyword: Ladle Furnace Slag

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Desulfurization Reaction according to Ladle Slag Recycling Method in Shaft-Type EAF Operation (Shaft형 전기로 공정에서 ladle 슬래그 재활용 방법에 따른 탈황반응)

  • Jung-Min Yoo
    • Resources Recycling
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    • v.33 no.2
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    • pp.46-53
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    • 2024
  • The residual heat and high CaO content present in the slag remaining in the ladle after the completion of continuous casting in the electric arc furnace (EAF) steelmaking process have been utilized to reduce power consumption and lime usage in the ladle furnace (LF) process. However, if the timing of such processes does not align with the LF and continuous casting operations, the recycling rate will decrease. To increase the slag recycling rate, the effect of ladle slag recycling methods, specifically pouring ladle slag into the slag pot in advance for subsequent recycling, on LF operations was analyzed. The slag liquefaction rate was calculated using the thermodynamic program Factsage 8.3 for ladle molten slag recycling methods. By applying each of the 10 heats operations for the ladle slag recycling methods, the desulfurization ability and LF operation performance were compared. It was found that when slag was immediately recycled into the ladle after continuous casting was completed, power consumption decreased by 0.3 MWh, LF operation time was shortened by 1.2 minutes, and the desulfurization rate increased by 5.8%.

Strength Properties of Calcium-aluminate based Foamed Concrete according to Replacement Ratio of GGBFs (고로슬래그 혼입율에 따른 CA계 기포콘크리트의 강도특성)

  • Yu, Jae-Seong;Choi, Sun-Mi;Choi, Hong-Bum;Li, Mao;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.39-40
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    • 2016
  • The aim of this research was evaluating strength characteristics of foamed concrete using Ladle Furnace slag with GGBFs. For all mixtures, because of the early setting and strength development, it was possible to deform the formwork and measure the compressive strength within 3 hours.

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Reaction Characteristics of the CAC with Various Gypsum Type and Mixing Ratio (석고 종류 및 혼입률에 따른 CAC 반응 특성)

  • Choi, Sun-Mi;Kim, Jin-Man;Koo, Ja-Sul
    • Resources Recycling
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    • v.30 no.1
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    • pp.83-91
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    • 2021
  • Ladle furnace slag is a byproduct of the steel-making process, and it contains the mineral β-C2Sandtherapid-settingmineral (dependingonwhichreducingagenthasbeenused). Ladle furnace slag is often treated through slow cooling, which causes the slag to lose its reactivity. In this study, the properties of air-quenched CAC and pulverized ladle furnace slag containing gypsum were evaluated, and the optimal mixing ratio was determined for broadening their usage. Consequently, the properties of CAC aredemonstrated by the dissolution of gypsum after a period of three hours and the content of gypsum after a period of one day. The optimal mixing ratio of anhydrate and hemihydrate gypsum is found to be within 30% and that of dihydrate gypsum is found to be higher than 35%. Furthermore, based on the results of CAC with dihydrate gypsum, the applicability of the by-product dihydrate gypsum has been verified.

Utilization of ladle furnace slag from a steelwork for stabilization of soil cement

  • Ayawanna, Jiratchaya;Kingnoi, Namthip;Sukchaisit, Ochakkraphat;Chaiyaput, Salisa
    • Geomechanics and Engineering
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    • v.31 no.2
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    • pp.149-158
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    • 2022
  • Ladle furnace (LF) slag, waste from the steel-making process, was incorporated to improve the compressive strength of soil cement. LF slag was mixed to replace the cement in the soil-cement samples with wt% ratio 20:0, 15:5, and 10:10 of cement and slag, respectively. LF slag in the range of 5, 10, and 20 wt% was also separately added to the 20-wt% cement-treated soil samples. The soil-cement mixed LF slag samples were incubated in a plastic wrapping for 7, 14, and 28 days. The strength of soil cement was highly developed to be higher than the standard acceptable value (0.6 MPa) after incorporating slag into soil cement. The mixing of LF slag resulted in more hydration products for bonding soil particles, and hence improved the strength of soil cement. With the LF slag mixing either a replacement or additive materials in soil cement, the LF slag to cement ratio is considered to be less than 1, while the cement content should be more than 10 wt%. This is to promote a predominant effect of cement hydration by preventing the partially absorbed water on slag particles and keeping sufficient water content for the cement hydration in soil cement.

Evaluation for Applicability as the Inorganic Binder with Rapid Setting Property for Construction Material of LFS Produced from Various Manufacturing Process (다양한 철강제조공정에서 부산되는 전기로 환원슬래그의 급경성 무기결합재로의 적용성 검토)

  • Kim, Jin-Man;Choi, Sun-Mi;Kim, Ji-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.70-77
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    • 2012
  • The Ladle Furnace Slag, about 20% of the electric arc furnace slag, has high content of free CaO and free MgO, which generates the expansion collapse by hydration reaction. Although many researchers have been endeavoring to recycle the EAF reducing slag in construction fields, there is not found the effective recycling method up to now. However, the LFS(Ladle Furnace Slag) contains mineral composition of the system of calcium aluminate with high-reactivity. Therefore, it is possible to developed the quick setting property and the high strength at the early age by the rapid cooling. This study aimed to check the reactive minerals and predict the reactivity with water on the LFS discharged from different steel product plants. The test results show that many types of LFS has hydration reactivity and can use in construction field as a inorganic binder with the rapid setting property.

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Trend on the Recycling Technologies on the High-efficiency Rapid Cooling Method of Ladle Furnace Slag by the Patent and Paper Analysis (특허와 논문으로 본 제강 환원슬래그의 고효율 급냉 자원순환기술 동향)

  • Kim, Jin Man;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.23 no.2
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    • pp.90-97
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    • 2014
  • The artificial dry silica used as dry aggregates in domestic is collected increasing every year. It is required drying process for the production of dry aggregates, therefore, it is main culprit of the cost up of aggregates and air pollution by using fossil fuel for the solution, it is developed alternative aggregates for the replacement of dry aggregates very ungently. In this article, the patents and papers for the recycling technology on the high-efficiency rapid cooling method of ladle furnace slag were collected and analyzed. The open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) and SCI journals from 1977 to 2013 were investigated. The patents and journals were collected using key-words and filtered by the definition of the technology. The patents and journals were analyzed by the years, countries, companies, and technologies and the technical trends were discussed in this paper.

Up-cycling of Air-cooled Ladle Furnace Slag : Environmental Risk Assessment and Mortar Compressive Strength Assesment of Binary and Ternary Blended Cement Using Air-cooled Ladle Furnace Slag (전기로 환원슬래그 Up-cycling : 환경위해성 평가 및 환원슬래그를 혼합하여 제조한 2성분계 및 3성분계 혼합시멘트 모르타르 압축강도 평가)

  • Cho, Han Sang;Mun, Young Bum;Moon, Won Sik;Park, Dae Cheol;Kim, Hyeong Cheol;Choi, Hyun Kook
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.3
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    • pp.159-164
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    • 2015
  • This study investigated the environmental risk for up-cycling of air-cooled ladle furnace slag (LFS) and evaluated the mortar compressive strength of binary and ternary blended cements using LFS of 3, 5, 10 wt%. Based on the Soil Environment Conservation Act standard, there was no environmental risk of the up-cycling of LFS. Results of mortar compressive strength assesment showed that the compressive strength of two blended cements using LFS of lower than 5 wt% was about 1.1 times superior to that of un-substituted cement (ordinary portland cement, OPC); however the compressive strength of those with LFS of 10 wt% decreased with 10% compared with that of OPC.

Dissolved organic matter characteristics and bacteriological changes during phosphorus removal using ladle furnace slag

  • Noh, Jin H.;Lee, Sang-Hyup;Choi, Jae-Woo;Maeng, Sung Kyu
    • Membrane and Water Treatment
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    • v.9 no.3
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    • pp.181-188
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    • 2018
  • A sidestream contains the filtrate or concentrate from the belt filter press, filter backwash and supernatant from sludge digesters. The sidestream flow, which heads back into the sewage treatment train, is about 1-3% less than the influent flow. However, the sidestream can increase the nutrient load since it contains high concentrations of phosphorus and nitrogen. In this study, the removal of PO4-P with organic matter characteristics and bacteriological changes during the sidestream treatment via ladle furnace (LF) slag was investigated. The sidestream used in this study consisted of 11-14% PO4-P and 3.2-3.6% soluble chemical oxygen demand in influent loading rates. LF slag, which had a relatively high $Ca^{2+}$ release compared to other slags, was used to remove $PO_4-P$ from the sidestream. The phosphate removal rates increased as the slag particle size decreased 19.1% (2.0-4.0 mm, 25.2% (1.0-2.0 mm) and 79.9% (0.5-1.0 mm). The removal rates of dissolved organic carbon, soluble chemical oxygen demand, color and aromatic organic matter ($UV_{254}$) were 17.6, 41.7, 90.2 and 77.3%, respectively. Fluorescence excitation-emission matrices and liquid chromatography-organic carbon detection demonstrated that the sidestream treatment via LF slag was effective in the removal of biopolymers. However, the removal of dissolved organic matter was not significant during the treatment. The intact bacterial biomass decreased from $1.64{\times}10^8cells/mL$ to $1.05{\times}10^8cells/mL$. The use of LF slag was effective for the removal of phosphate and the removal efficiency of phosphate was greater than 80% for up to 100 bed volumes.

Setting Properties of High Aluminate Composite According to Various Temperature and Components

  • Li, Mao;Kim, Jin-Man;Choi, Sun-Mi;Lee, Dong-Won
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.36-37
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    • 2016
  • Among all the slags, ladle furnace slag (LFS) is reducing slag generated from electric arc furnace. After cooled rapidly by high-pressured air (atomizing technology), LFS has more amorphous phase than slow cooled slag. Therefore, it shows higher reactivity than another recycling slag. This material also is named by rapid cooling LFS (RC-LFS). Pulverized RC-LFS should be fully understood. This paper deal with the present some basic experimental properties and discussions about the setting time of pulverized RC-LFS with different gypsum under the various temperatures. According to the experimental results, the pulverized RC-LFS with gypsum can hydrate in a low-temperature environment, even though the initial and final setting time are delayed.

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