• Title/Summary/Keyword: LI5

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Effect of Li3BO3 Additive on Densification and Ion Conductivity of Garnet-Type Li7La3Zr2O12 Solid Electrolytes of All-Solid-State Lithium-Ion Batteries

  • Shin, Ran-Hee;Son, Sam-Ick;Lee, Sung-Min;Han, Yoon Soo;Kim, Yong Do;Ryu, Sung-Soo
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.712-718
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    • 2016
  • In this study, we investigate the effect of the$Li_3BO_3$ additive on the densification and ionic conductivity of garnet-type $Li_7La_3Zr_2O_{12}$ solid electrolytes for all-solid-state lithium batteries. We analyze their densification behavior with the addition of $Li_3BO_3$ in the range of 2-10 wt.% by dilatometer measurements and isothermal sintering. Dilatometry analysis reveals that the sintering of $Li_7La_3Zr_2O_{12}-Li_3BO_3$ composites is characterized by two stages, resulting in two peaks, which show a significant dependence on the $Li_3BO_3$ additive content, in the shrinkage rate curves. Sintered density and total ion conductivity of the system increases with increasing $Li_3BO_3$ content. After sintering at $1100^{\circ}C$ for 8 h, the $Li_7La_3Zr_2O_{12}-8$ wt.% $Li_3BO_3$ composite shows a total ionic conductivity of $1.61{\times}10^{-5}Scm^{-1}$, while that of the pure $Li_7La_3Zr_2O_{12}$ is only $5.98{\times}10^{-6}Scm^{-1}$.

Semantic Depth Data Transmission Reduction Techniques using Frame-to-Frame Masking Method for Light-weighted LiDAR Signal Processing Platform (LiDAR 신호처리 플랫폼을 위한 프레임 간 마스킹 기법 기반 유효 데이터 전송량 경량화 기법)

  • Chong, Taewon;Park, Daejin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.25 no.12
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    • pp.1859-1867
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    • 2021
  • Multi LiDAR sensors are being mounted on autonomous vehicles, and a system to multi LiDAR sensors data is required. When sensors data is transmitted or processed to the main processor, a huge amount of data causes a load on the transport network or data processing. In order to minimize the number of load overhead into LiDAR sensor processors, only semantic data is transmitted through data comparison between frames in LiDAR data. When data from 4 LiDAR sensors are processed in a static environment without moving objects and a dynamic environment in which a person moves within sensor's field of view, in a static experiment environment, the transmitted data reduced by 89.5% from 232,104 to 26,110 bytes. In dynamic environment, it was possible to reduce the transmitted data by 88.1% to 29,179 bytes.

Analysis of Operating Time of Li-polymer Secondary Cell with or Without Flyback Converter Active Balancing BMS (Flyback Converter Active Balancing BMS 적용 유·무에 따른 리튬폴리머 이차전지 가용시간 분석)

  • Kim, Young-Pil;Choi, Chul-Hyung;Ko, Seok-Cheol;Kim, Si-Kyung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.5
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    • pp.786-791
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    • 2017
  • In this paper, the run time of Li-polymer secondary cell with and without Active Balancing BMS is analyzed. The Active Balancing System using Flyback Converter with two-way power control facility, his designed for optimal characteristics of balancing. The run time of Li-polymer secondary cell is drastically increased employing the Flyback Convert Active Balancing BMS. The run time performance of Li-polymer secondary cell with or without Flyback Converter Active Balancing BMS is analyzed with the discharging and charging experiment of Li-polymer secondary cell.

A study on the periodical domain obtained in Nd : $LiNbO_3$ sinlgle crystals grown by czochralski method (Czochralski법에 의해 성장시킨 Nd : $LiNbO_3$ 단결정의 주기적인 domain제어에 관한 연구)

  • 최종건
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.50-55
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    • 2002
  • $Nd_2O_3$0.2~0.5 wt.% doped $LiNbO_3$single crystals were grown by the Czochralski method. The ZnO doping by 2~8 mole% can improve the resistance of optical damage. In this study, Nd : LiNbO$_3$ single crystals with the periodical domain structure were obtained by CZ method.

Electrochemical Properties of Cross-linked Polyurethane Acrylate-Based Gel Polymer Electrolyte

  • Kim, Hyun-Soo;Kim, Sung-Il;Choi, Gwan-Young;Moon, Seong-In;Kim, Sang-Pil
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.197-201
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    • 2002
  • In this study, a gel polymer electrolyte was prepared from urethane acrylate and its electrochemical performances were evaluated. And, $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. Ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.7\times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed electrochemical stability up to potential of 4.5V vs. $Li/Li^+.LiCoO_2/GPE/graphite$ cell showed a good high-rate and a low-temperature performance.

Preparation and Electrochemical Properties of LiFePO4-PSS Composite Cathode for Lithium-ion Batteries

  • Nguyen, Hiep Van;Jin, En Mei;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.4
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    • pp.177-180
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    • 2012
  • In this study, we prepared $LiFePO_4$- poly (sodium 4-styrenesulfonate) (PSS) composite by the hydrothermal method and ball-milling process. Different wt% PSS were added to $LiFePO_4$. The cathode electrodes were made from mixtures of $LiFePO_4$-PSS: SP-270: PVDF in a weighting ratio of 70%: 25%: 5%. $LiFePO_4$-PSS powders were characterized by X-ray diffraction (XRD), and scanning electron microscopy (SEM). The electrochemical properties of $LiFePO_4$-PSS/Li batteries were analyzed by cyclic voltammetry, charge/discharge tests, and AC impedance spectroscopy. A Li/$LiFePO_4$-PSS battery with 4.75 wt% PSS shows the best electrochemical properties, with a discharge capacity of 128 mAh/g.

Adjustment of Exterior Orientation of the Digital Aerial Images using LiDAR Points

  • Yoon, Jong-Suk
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.26 no.5
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    • pp.485-491
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    • 2008
  • LiDAR systems are usually incorporated a laser scanner and GPS/INS modules with a digital aerial camera. LiDAR point clouds and digital aerial images acquired by the systems provide complementary spatial information on the ground. In addition, some of laser scanners provide intensity, radiometric information on the surface of the earth. Since the intensity is unnecessary of registration and provides the radiometric information at a certain wavelength on the location of LiDAR point, it can be a valuable ancillary information but it does not deliver sufficient radiometric information compared with digital images. This study utilize the LiDAR points as ground control points (GCPs) to adjust exterior orientations(EOs) of the stereo images. It is difficult to find exact point of LiDAR corresponding to conjugate points in stereo images, but this study used intensity of LiDAR as an ancillary data to find the GCPs. The LiDAR points were successfully used to adjust EOs of stereo aerial images, therefore, successfully provided the prerequisite for the precise registration of the two data sets from the LiDAR systems.

Corrosion Characteristics of Zr Alloys in LiOH Solution (LiOH 용액에서 Zr합금의 부식특성연구)

  • Jeong, Yong-Hwan;Kim, Yeong-Seok
    • Korean Journal of Materials Research
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    • v.5 no.4
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    • pp.458-467
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    • 1995
  • 여러가지 Zr합금에 대한 부식시험을 autoclave를 이용하여 물과 여러가지 Li 용액에서 수행하였다. 합금은 11종의 신합금을 사용하였는데 크게 나누어 Zircaly형 합금(ZrSnFeCr), ZnNbFeCr, ZrSnNbFeCr과 ZrFeCr 합금으로 대별되며, 비교평가를 위해 표준 Zircaloy-4 합금에 대해서도 부식시험을 수행하였다.모든 합금에서 Li을 일정농도이상 첨가할 때 부식은 가속되는데, 부식은 Li의 농도가 2.2와 30ppm 사이일 때 가속되기 시작한다. Li은 부식거동에 있어서 천이후 영역에서의 부식속도보다는 천이시간과 무게 증가량에 더 영향을 끼치는 것으로 나타났다. 수소 흡수율은 Li 농도와 합금에 따라서 강하게 영향을 받는것으로 나타났으며, Li 농도가 30ppm이상에서는 Li 가속부식과 함께 Li가속 수소흡수현상이 나타났다. ZrSnFeCr합금들은 낮은 부식속도와 늦은 천이현상을 보이며 표준 Zircaloy보다 훨씬 우수한 부식저항성을 보인 반면에 대부분의 Nb첨가 합금은 높은 부식속도와 빠른 천이 현상을 보였다.

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Electrochemical Characteristics of $LiFePO_4$ with Conductivity Materials for Lithium Polymer Batteries

  • Jin, En Mei;Wang, Jiao;Zhao, Xing Guan;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.132-132
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    • 2009
  • Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. In this study, Multi-walled carbon nanotube (MWCNT) and Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. $LiFePO_4$, $LiFePO_4$-MWCNT and $LiFePO_4$-C particles were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) transmission electron microscope (TEM). $LiFePO_4/SPE/Li$, $LiFePO_4$-MWCMT/SPE/Li and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments at a constant current density of $0.1mA\;cm^{-2}$ in a range between 2.5 and 4.3 V vs. $Li/Li^+$ and cyclic voltammetry (CV).

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Synthesis LiFePO4- poly(sodium 4-styrenesulfonate) composite cathode material for rechargeable lithium battery by hydrothermal method

  • Hiep, Nguyen Van;Wang, Wan Lin;Jin, En Mei;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.137.2-137.2
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    • 2011
  • Poly (sodium 4-styrenesulfonate) (PSS) is ionomer based on polystyrene that is electrical conductivity and isoviscosity. LiFePO4 has been a promising electrode material however its poor conductivity limits practical application. To enhance the electronic conductivity of LiFePO4, in this study we prepared LiFePO4- PSS composite by the hydrothermal method. LiFePO4 was heated at $170^{\circ}C$ for 12h and then different wt% PSS (0%, 2.91%, 4.75%, 7.36%, 10%) are added to LiFePO4 and milled at 300rpm for 10h. And then the obtained powders were subsequently heated at $500^{\circ}C$ for 1h under argon flow. The cathode electrode were made from mixtures of LiFePO4-PSS: SP-270- PVDF in a weighting ratio 75%: 25%:5%. The electrochemical properties of LiFePO4- PSS/Li batteries were analyzed by cyclic voltammetry and charge/discharge tests. LiFePO4-C/Li battery with 4.75 wt% PSS displays discharge capacity of 128 mAh g-1 at room temperature that is considerably higher than pure LiFePO4/Li battery ( 113.48 mAhg-1).

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