• 제목/요약/키워드: LI11

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LiOH용액에서 핵연료피복관용 Zr신합금의 부식특성 연구

  • 정용환;김창호;김영석;국일현;임갑순
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1995년도 춘계학술발표회논문집(2)
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    • pp.623-628
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    • 1995
  • 여러 가지 Zr합금에 대한 부식시험을 autoclave를 이용하여 물과 여러 가지 Li 용액에서 수행하였다. 합금은 11종의 신합금을 사용하였는데 크게 나누어 Zircaloy형 합금(ZrSnFeCr), ZrNbFeCr, ZrSnNbFeCr과 ZrFeCr 합금으로 대별되며, 비교평가를 위해 표준 Zircaloy-4 합금에 대해서도 부식시험을 수행하였다. 모든 합금에서 Li을 일정농도이상 첨가할 때 부식은 가속되는데, 부식은 Li의 농도가 2.2와 30 ppm 사이일 때 가속되기 시작한다. Li은 부식거동에 있어서 천이후 영역에서의 부식속도 보다는 천이시간과 무게 증가량에 더 영향을 끼치는 것으로 나타났다. 수소흡수율은 Li 농도와 합금에 따라서 강하게 영향을 받는 것으로 나타났으며, Li 농도가 30 ppm 이상에서는 Li 가속부식과 함께 Li가속 수소흡수현상이 나타났다. ZrSnFeCr합금들은 낮은 부식속도와 늦은 천이현상을 보이며 표준 Zircaloy보다 훨씬 우수한 부식저항성을 보인 반면에, 대부분의 Nb첨가 합금은 높은 부식속도와 빠른 천이 현상을 보였다.

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Comparative Analysis of SOC Estimation using EECM and NST in Rechargeable LiCoO2/LiFePO4/LiNiMnCoO2 Cells

  • Lee, Hyun-jun;Park, Joung-hu;Kim, Jonghoon
    • Journal of Electrical Engineering and Technology
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    • 제11권6호
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    • pp.1664-1673
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    • 2016
  • Lithium rechargeable cells are used in many industrial applications, because they have high energy density and high power density. For an effective use of these lithium cells, it is essential to build a reliable battery management system (BMS). Therefore, the state of charge (SOC) estimation is one of the most important techniques used in the BMS. An appropriate modeling of the battery characteristics and an accurate algorithm to correct the modeling errors in accordance with the simplified model are required for practical SOC estimation. In order to implement these issues, this approach presents the comparative analysis of the SOC estimation performance using equivalent electrical circuit modeling (EECM) and noise suppression technique (NST) in three representative $LiCoO_2/LiFePO_4/LiNiMnCoO_2$ cells extensively applied in electric vehicles (EVs), hybrid electric vehicles (HEVs) and energy storage system (ESS) applications. Depending on the difference between some EECMs according to the number of RC-ladders and NST, the SOC estimation performances based on the extended Kalman filter (EKF) algorithm are compared. Additionally, in order to increase the accuracy of the EECM of the $LiFePO_4$ cell, a minor loop trajectory for proper OCV parameterization is applied to the SOC estimation for the comparison of the performances among the compared to SOC estimation performance.

Photoluminescence of Li-doped Y2O3:Eu3+ thin film phosphors grown by pulsed laser deposition

  • 이성수
    • 센서학회지
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    • 제11권6호
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    • pp.371-377
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    • 2002
  • $Y_2O_3:Eu^{3+}$ and Li-doped $Y_2O_3:Eu^{3+}$ thin films have been grown on sapphire substrates using a pulsed laser deposition technique. The thin film phosphors were deposited at a substrate temperature of $600^{\circ}C$ under the oxygen pressure of 100, 200 and 300 mTorr. The films grown under different deposition conditions have been characterized using microstructural and luminescent measurements. The crystallinity and photoluminescence (PL) of the films are highly dependent on the oxygen pressure. The PL brightness data obtained from $Y_2O_3:Eu^{3+}$ films grown under optimized conditions have indicated that sapphire is one of the most promising substrate for the growth of high quality $Y_2O_3:Eu^{3+}$ thin film red phosphor. In particular, the incorporation of $Li^{+}$ ions into $Y_2O_3$ lattice could induce a remarkable increase of PL. The highest emission intensity was observed with LiF-doped $Y_{1.84}Li_{0.08}Eu_{0.08}O_3(Y_2O_3LiEu)$, whose brightness was increased by a factor of 2.7 in comparison with that of $Y_2O_3:Eu^{3+}$ films. This phosphor may promise for application to the flat panel displays.

평판 유리로 봉인된 다층 무기 박막을 갖는 OLED 봉지 방법 (Encapsulation Method of OLED with Inorganic Multi-layered Thin Films Sealed with Flat Glass)

  • 박민경;주성후;양재웅;백경갑
    • 한국전기전자재료학회논문지
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    • 제24권11호
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    • pp.905-910
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    • 2011
  • To study encapsulation method for large-area organic light emitting diodes (OLEDs), red emitting OLEDs were fabricated, on which LiF and Al were deposited as inorganic protective films. And then the OLED was attached to flat glass by printing method using epoxy. In case of direct coating of epoxy onto OLED by printing method, luminance and current efficiency were remarkably decreased because of the damage to the OLED by epoxy. In case of depositing LiF and Al as inorganic protective films and then coating of epoxy onto OLED, luminance and current efficiency were not changed. OLED lifetime was more increased through inorganic protective films between OLED and flat glass than that without any encapsulation (8.8 h), i.e., 47 (LiF/Al/epoxy/glass), 62 (LiF/Al/LiF/epoxy/glass), and 84 h (LiF/Al/Al/epoxy/glass). The characteristics of OLED encapsulated with inorganic protective films (attached to flat glass) showed the possibility of application of protective films.

ZORA DFT Calculation of $^{11}$B Electric Field Gradient Tensor for Lithium Borates

  • Woo, Ae-Ja;Wasylishen, Roderick E.
    • 한국자기공명학회논문지
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    • 제8권2호
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    • pp.70-76
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    • 2004
  • ZORA-DFT calculations of $^{11}$B EFG (electric field gradient) tensors for lithium borates, LiB$_3O_5$ (LBO) and Li$_2B_4O_7$ (LTB), were performed. The calculated values of 11B quadrupole coupling constant and asymmetry parameter are in good agreement with the experimental values. The sign of the quadrupole coupling constant for the tetrahedral boron site was deduced from the distortion from the ideal tetrahedral symmetry.

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LiDAR용 엣지 컴퓨팅을 활용한 중요시설 경계 시스템 (Important Facility Guard System Using Edge Computing for LiDAR)

  • 조은경;이은석;신병석
    • 정보처리학회논문지:컴퓨터 및 통신 시스템
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    • 제11권10호
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    • pp.345-352
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    • 2022
  • 최근의 LiDAR(Light Detection And Ranging) 센서는 실시간으로 주변에 있는 물체를 스캔하는 데 사용된다. LiDAR 센서를 이용하여 주변 환경을 스캔할 경우 감지되었던 사물들에 대한 변화를 감지하고 실시간으로 움직이는 물체를 인식할 수 있다. 센서들의 제작 비용이 낮아지면서 LiDAR는 중요시설의 경계, 스마트시티, 자율주행차 등 다양한 산업 분야에서 다양하게 활용되고 있다. 이러한 LiDAR 데이터는 실시간에 사물을 스캔하는 만큼 입력 데이터의 크기가 크다. 따라서 이러한 LiDAR를 활용하는 시스템에서는 이러한 대용량 데이터의 실시간 처리가 병목이 될 수 있어서 이러한 대용량 처리에 대한 대안이 필요하다. 본 논문에서는 엣지 컴퓨팅 서버를 이용하여 방대한 포인트 클라우드를 압축하여 빠르게 처리하는 엣지 컴퓨팅 기법을 제안한다. LiDAR 센서의 레이저의 반사 범위가 제한되어 있으므로 실시간으로 넓은 영역을 스캔하기 위해서는 여러 대의 라이다를 사용해야 한다. 따라서 실시간으로 물체를 감지하거나 인식하기 위해서는 여러 개의 LiDAR 센서에 대한 데이터를 한 번에 처리해야 한다. 에지 컴퓨터는 데이터 가속을 수행하기 위해 포인트 클라우드를 효율적으로 압축하고 모든 데이터를 메인 클라우드에서 실시간에 압축해제하여 사용할 수 있도록 설계되었다. 이를 통해 사용자는 시스템을 중앙에서 병목 없이 실시간에 LiDAR 센서들을 제어할 수 있다. 실험에 사용된 시스템은 이러한 엣지 컴퓨팅 서비스를 적용함으로써 기존 클라우드 기반 방식에서 문제였던 데이터 병목 현상을 효과적으로 해결하였다.

The Sintering Temperature Effect on Electrochemical Properties of LiMn2O4

  • Hwang, Jin-Tae;Park, Sung-Bin;Park, Chang-Kyoo;Jang, Ho
    • Bulletin of the Korean Chemical Society
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    • 제32권11호
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    • pp.3952-3958
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    • 2011
  • The effect of sintering temperature on the electrochemical property of $LiMn_2O_4$ was investigated. Results showed that the particle size was increased at higher sintering temperatures while the initial capacity was decreased after high temperature sintering. Capacity fading, on the other hand, was suppressed at lower sintering temperatures since the sintering at higher temperatures (${\geq}800^{\circ}C$) increased the Mn ions with a lower oxidation state ($Mn^{+3}$), which induced structural instability during cycling due to dissolution of Mn ions into the electrolyte. In particular, $LiMn_2O_4$ sintered above $830^{\circ}C$ showed severe capacity fading (capacity loss was 38% of initial capacity) by lower coulombic efficiency due to the abnormally increased particle size.

언어발달장애 아동의 문법형태소 산출 (The Production of Grammatical Morphemes of Korean Children with Developmental Language Impairments)

  • 황민아
    • 음성과학
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    • 제10권3호
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    • pp.47-64
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    • 2003
  • In the present study, the production of grammatical morphemes of Korean-speaking children with and without developmental language impairments was investigated. Ten children with language impairments (LI) (CA: 4; 4-6; 11, LA: 3; .6-5; 10) and 10 normal children (CA: 3;1-6;3, LA: 3;5-5;11) with matched language abilities participated in the study. Sixty pairs of pictures were used to elicit 12 types of predetermined grammatical morphemes. The two pictures of a pair were designed to elicit two sentences of the same sentence structure. After the investigator described one picture of a pair, the children were asked to describe the other picture. The LI children made more errors than the normal children in the production of 6 types of grammatical morphemes including: locative case marker, dative case marker, two connective endings of predicates representing cause and goal, and suffixes for passive and causative verbs. However, the LI children produced some grammatical morphemes as accurately as. the normal children. The two groups were similar in their error patterns. Some explanations for Korean-speaking LI children's use of grammatical morphemes were suggested.

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Ordered Reverse k Nearest Neighbor Search via On-demand Broadcast

  • Li, Li;Li, Guohui;Zhou, Quan;Li, Yanhong
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제8권11호
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    • pp.3896-3915
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    • 2014
  • The Reverse k Nearest Neighbor (RkNN) query is valuable for finding objects influenced by a specific object and is widely used in both scientific and commercial systems. However, the influence level of each object is unknown, information that is critical for some applications (e.g. target marketing). In this paper, we propose a new query type, Ordered Reverse k Nearest Neighbor (ORkNN), and make efforts to adapt it in an on-demand scenario. An Order-k Voronoi diagram based approach is used to answer ORkNN queries. In particular, for different values of k, we pre-construct only one Voronoi diagram. Algorithms on both the server and the clients are presented. We also present experimental results that suggest our proposed algorithms may have practical applications.

PMMA IPN계 겔폴리머전해질을 채용한 리튬이온폴리머전지의 전기화학적 특성 (Electrochemical Properties of Lithium-Ion Polymer Battery with PMMA IPN-Based Gel Polymer Electrolyte)

  • 김현수;신정한;나성환;엄승욱;문성인;김상필
    • 한국전기전자재료학회논문지
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    • 제16권11호
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    • pp.994-1000
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    • 2003
  • In this study, gel polymer electrolytes (GPE) with semi-interpenerating network of poly (methyl methacrylate) and hexanediol dimethacrylate were synthesized and their electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing 5 vol% curable mixture had a low viscosity relatively. GPE showed good electrochemical stability up to potential of 4.8 V vs. Li/Li$\^$+/. Ionic conductivity of the gel polymer electrolyte at room temperature and -20$^{\circ}C$ was ca. 5.9 and 1.4${\times}$10$\^$-3/ Scm$\^$-1/, respectively. LiCoO$_2$/GPE/graphite cells showed good rate capability, low-temperature performance and cycleability.