• Title/Summary/Keyword: LDPE-EVA

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Study on Halogen Free Low Smoke Polyolefin (할로겐이 없는 저연성 폴리올레핀에 관한 연구)

  • Kim, Young-Doo;Chung, Kwang-Soo;Kim, Tae-Ho
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.177-182
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    • 2002
  • For low-smoke-type polyolefin compound, LDPE, EVA, and EEA as base resin, magnesium trihydrate, alumina trihydrate, and red phosphorous as flame retardant and MAH type compatibilizer were applied. The amount of each component was changed to find out optimum composition. Mechanical properties were obtained by tensile test and residual stress after aging and flame retardancy was evaluated by smoke density, LOI(Limit Oxygen Index), and UL-94 test. SEM was used for the investigation or morphology and halogen contents were obtained by measuring the amount of HCI. Two kinds of halogen free compositions for flame retardant and low smote resin were found and it is expected to be applied for various purposes.

Study on the Physical Property of Soft Film for Greenhouse (시설하우스용 연질필름의 물리적 특성에 관한 연구)

  • 장유섭;한길수;김승희;정두호;김기철
    • Journal of Bio-Environment Control
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    • v.5 no.1
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    • pp.23-33
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    • 1996
  • This study was performed to induce a quality improvement and standardization of materials used for greenhouse. For this purpose, physical and mechanical properties of agricultural films for greenhouse were measured by kinds and thickness of the films. The properties are composed of impact, tensile, tear propagation strength and light transmittance. The results were summarized as follows. 1. At the impact test result of the falling dart, the thicker the film, the greater the impact strength of soft film. The impact weight at 50 percents is from 158g to 213g and the strength of low density polyethylene(LDPE) film is higher than the rest of any other films. 2. Seeing the leveling of the impact rupture, maximum impact weight which was ruptured very little ranges from 62g to 192g. The impact strength of 0.1mm films was higher than that of 0.05mm as from 1.8 to 3.2 times. 3. Tensile weight covers from 0.95kg to 2.22kg in the test materials, and the weight of lengthwise film is larger than that of width. LDPE film has high value of tensile weight. Elongation range is from 345 to 102 percent and lengthwise elongation is greater than width as much as from 1.4 to 2.7 times. 4. Tea. propagation strength ranges from 80.5kg/cm to 121.7kg/cm, and unlike which of LDPE film has high value, EVA film has low value in the films tested. The width strength is higher than the lengthwise. 5. The light transmittance of the soft film is about 78-92 percent in the range of ultraviolet ray, but has high value in the visible ray range.

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Comparison of Magnesium Hydroxide Particles by Precipitation and Hydrothermal Treatment for Flame Retardant Application to Low Density Polyethylene and Ethylene-Co-Vinyl Acetate Resin (침전법과 수열처리로 제조된 수산화마그네슘 비교와 이의 저밀도 폴리에틸렌-에틸렌 비닐 아세테이트 수지 난연제 적용)

  • Hyun, Mi Kyung;Lim, Hyung Mi;Yoon, Joonho;Lee, Dong Jin;Lee, Seung-Ho;Whang, Chin Myung;Jeong, Sang Ok
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.234-240
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    • 2009
  • $Mg(OH)_2$ particles were prepared by precipitation and a hydrothermal treatment to examine the effect of $MgCl_2$ concentration, alkali type and concentration, temperature, hydrothermal treatment on the formation of $Mg(OH)_2$ particles using full factorial design, as one of DOE (Design of experiment) methods. The primary particle size is similar to the secondary particle size for the samples after the hydrothermal treatment, where the average particle size of $Mg(OH)_2$ increased with increasing the concentration of $MgCl_2$ and hydrothermal temperature and decreasing alkali/Mg molar ratio. On the other hand, for the samples prepared from precipitation, the secondary particle size is larger than the primary particles due to aggregation. The difference in alkaline source is that the particles prepared from $NH_4OH$ exhibit the larger size with better dispersion than those from NaOH. Low density polyethylene and ethylene-co-vinyl acetate (LDPE-EVA) resin composed of the smaller secondary particle size of $Mg(OH)_2$ shows a higher limited oxygen index (LOI) at 50 and 55% loading, but the smaller primary particle size may result in a better grade in UL-94 tests. At the high loading of 60%, all samples with any preparation methods exhibit V-0 grade but the LOI value depends on not only primary particle size but also dispersion state.

A Study on the Recycling of Agricultural Films by Air Washing (공기세척에 의한 농업용 폐필름의 재활용 연구)

  • Kim, R. K.;Kang, M.;Lee, J. M.;Yoon, T. H.
    • Resources Recycling
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    • v.8 no.3
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    • pp.3-8
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    • 1999
  • An air-washer was developed in order to remove the soil on the films collected from agricultural use, The washed films were subjected to TGA analysis to measure the residual soil content and DSC analysis to evaluate composition as well as compositional ratro, Mechanical properties of washed films were measured via tensile test ,md the properties of washed films were compared with those of neat resin blend. Major component of air washed films was polyethylene, and compositional ratio was 10:6:3:1 (HDPE:LLDPE:LDPE:EVA). 30 min air-washed films showed 2.1 % of residual soil content, while the water washed films had 1.5%. Tensile properties of washed (air and water) films were almost same as those of neat resin mixture.

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Insect Repellency and Crop Productivity of Essential Oil Films

  • KIM, Jin Gu;KANG, Seok Gyu;MOSTAFIZ, Md Munir;LEE, Jeong Min;LEE, Kyeong-Yeoll;HWANG, Tae Kyung;LIM, Jin Taeg;KIM, Soo Yeon;LEE, Won Hee
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.1
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    • pp.95-106
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    • 2020
  • The purpose of this study was to determine the effects of coniferous essential oils (EOs) blended films on insect repellence and crop productivity. Low-density polyethylene (LDPE) film is widely used, especially in agriculture and for food packaging. Ethylene vinyl acetate was blended with LDPE to reduce volatilization of EOs. An EO from Japanese cypress (Chamaecyparis obtusa) was incorporated into the blend film to conduct field research on antimicrobial and insect repellent properties. Among the various concentrations of EO, the highest concentration (2.5%) showed the highest efficiency in terms of pesticidal activity. The ability to inhibit microbial growth can be explained by the lipophilic properties of the EO component, and many studies have already demonstrated this. Agricultural films containing all types of EO have been tested on various crops such as chili, cucumber, Korean melon and have been able to verify their effectiveness in avoiding pests and increasing yields. From these results, it was found that it is reasonable to use a modified film such as a composite film containing an EO for agriculture. Thus, the modified film containing EO has undoubtedly shown impressive potential for reducing the use of pesticides in a variety of ways, not only for agricultural mulching film but also for food and agricultural product packaging. This product is an environmentally friendly chemical and is safe for agricultural and industrial and food packaging applications, among others. In particular, the use of agricultural films significantly reduces the use of pesticides, suggesting that farmers can increase their incomes by reducing working hours and costs, and increasing production.

Influence of Surface Free Energy of Carbon Black/Thermoplastic Resin Composites on PTC Characteristics

  • Park, Soo-Jin;Kim, Hyun-Chel;Lee, Jae-Rock
    • Carbon letters
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    • v.1 no.1
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    • pp.1-5
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    • 2000
  • The effect of surface free energy on the positive temperature coefficient (PTC) of carbon black/thermoplastic resin composites was investigated. The thermoplastic resins such as EVA, LDPE, LLDPE and HDPE were used with the addition of 30 wt.% of the carbon black. The surface free energy of the composites was studied in the context of two-liquid contact angle measurements, i.e., deionized water and diiodomethane. It was observed that the resistivity on PTC composites Was greatly increased near the crystalline melting temperature, due to the thermal expansion of polymeric matrix. From the experimental results, it was proposed that the decrease of surface free energy induced by interactions between carbon black surfaces and polymer chains is an important factor to the fabrication of a PTC composite made of carbon black and polymeric matrix.

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Development of self-sealing waterproof materials using GRT powder (폐타이어 분말을 이용한 자체보수성 방수재 개발)

  • Lee Dong-Min;Choi Joong-So
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.22-33
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    • 2005
  • Four sheet-shaped and one soft-shaped self-sealing waterproof materials were prepared to recycle some GRT(Ground Rubber Tires). Their physical properties were tested to consider characteristics of them. The self-sealing waterproof materials were consisted of GRT/super absorbent polymer(SAP)/binder and mold by a hot press after mixing with a batch-typed internal mixer. The average size of GRT particles was -40 mesh, SAPs were commercial GE-500F and poly(AM-SAS-AA) prepared in this work. Binders were PU. EVA, LDPE, SBR, and poly(2-EHA). And PU film was attached to improve the properties of waterproof materials. Characteristics of self-sealing waterproof materials consisted of by GRT/GE-500F/EV-600/PU film and GRT/GE-500F/SBR(vulcanization)/PU film among the developed self-sealing waterproof materials were similar to the commercial products. And properties of the soft-shaped self-sealing waterproof materials consisted of by GRT/GE-500F/Po1y(2-EHA) and CRT/Poly(AM-SAS-AA)/poly(2-EHA) were improved within from four times to twenty times compared to the one oi the commercial products.

Physicochemical Characteristics and Efficacy of Controlled-release Insecticide Formulation (방출조절형(放出調節型) 살충성(殺蟲性) 농약제제(農藥製劑)의 특성(特性)과 약효(藥效)에 관한 연구(硏究))

  • Kim, Jin-Hwa;Oh, Byung-Youl;Oh, Kyeong-Seok;Kim, Sung-Kee;Kim, Mee-Hea;Kim, Young-Koo
    • Korean Journal of Environmental Agriculture
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    • v.14 no.3
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    • pp.289-295
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    • 1995
  • This study was carried out to develop a controlled-release insecticide formulation for the control of rose aphid (Macrosiphum ibarae) in rose and cotton aphid (Myzus persicae) in chrysanthemum (Dendranthema grandiflorum var. Meibung) in greenhouse. Imidacloprid[1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine] was chosen as a toxicant. Two synthetic polymers, low density polyethylene(LDPE) and ethylene vinyl acetate(EVA), were used as polymer matrices. The tested plastic sheet formulations were prepared by heat-aided extrusion procedures after mixing imidacloprid technical and the polymers of three different combinations, and physicochemical properties as well as efficacy of the formulations were investigated. The amounts of imidacloprid recovered and incorporated in the formulations were recorded over 90% and 80%, respectively. Release of the active ingredient from the formulations was remarkably affected by mixing rates of polymers. The active ingredient in the formulations was chemically unstable with over 10% degradation rates after 90 day storage at $50{\pm}2^{\circ}C$. The residual amounts of imidacloprid in the soil treated with the formulations were paralleled with the release pattern of the formulations. Efficacy of the formulations on rose and cotton aphid was maintained over 90% even 120days after treatment under greenhouse.

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Effect of the Slow-releasing Fertilizer Applied Directly to Rice Seedling Tray Before Transplanting and Practical Test at Field (이앙직전 벼 육묘상자 살포용 완효성 비료의 처리 효과)

  • Chi, Jeong-Hyun;Choi, Byoung-Rourl;Jo, Gwang-Lae;Kim, Soon-Jae;Park, Kyeong-Yeol;Kwon, O-Youn
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.1
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    • pp.8-14
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    • 2013
  • The newly developed fertilizer is the slow-releasing fertilizer which can be used as a basal fertilizer without no additional fertilization at tillering stage. It has 30-4-6% of $N-P_2O_5-K_2O$ and was coated with mixture of LDPE (Low density polyethylene), EVA (Ethylene vinyl acetate), BDP (Bio degraded polymer), TALC and nonionic surfactant for the controlled release up to 50 days after application. Coating materials were designed to be decomposed naturally. This fertilizer can be applied directly to the seedling tray mechanically just before transplanting, resulting in significant labor saving effect. The developed slow-release fertilizer, which can replace both basal fertilization and top dressing at tillering stage by single application directly to seedling tray, showed the highest release at 14~21 days after transplanting. Considering the plant growth at different growth stages and yield, the optimal application rate of developed slow-release fertilizer was 300 g per rice nursery tray and the yield of rice at this application rate was 5.25 MT/ha. Rice quality in terms of head rice grain ratio, amylose content, whiteness, and taste value decreased as fertilization rate increased from 200 g to 500 g per nursery tray. Fertilization rate based on quantity of fertilizer ingredients (N, P, K) was reduced by 49.3% compared to the standard application rate and there was 49.2% reduction in labor input for fertilization.