• 제목/요약/키워드: LB (Langmuir-Blodgett)

검색결과 295건 처리시간 0.023초

Characteristics of Ultrathin Film Prepared through Nano-Sized Langmuir Blodgett Monolayer of Functionalized Polyimide

  • Park, Keun-Ho;Lee, Soo
    • 한국응용과학기술학회지
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    • 제26권2호
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    • pp.224-231
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    • 2009
  • Techniques measuring Maxwell displacement current (MDC) and LB films surface measuring technique have been applied to the study of monolayers of polyamic acid containing azobenzene. MDCs was generated from monolayers on the water surface by monolayer compression and expansion. It was generated when the area per molecule was about $103{\AA}^2\;and\;78{\AA}^2$ just before the initial rise of the surface pressure during the 1st and 2nd mixed monolayer compressions cycle, respectively. It was the maximum of MDCs appeared at the molecular area just before the initial rise of surface pressure in compression cycles, and we have found that the increase of aggregations causes the noticeable increase of the surface roughness.

$C_{22}$ Quinolium-(TCNQ) LB막 누적을 위한 $\prod$-A 특성 ($\prod$-A Characteritics of $C_{22}$ Quinolium-(TCNQ) for LB FILM Deposition)

  • 박승규;김태완;홍언식;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1991년도 추계학술대회 논문집
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    • pp.7-9
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    • 1991
  • $\prod$-A characteristics of N-docosylquinolium-TCNQ complex were investigated with the following variations. I> $\prod$-A characteristics with a variation of spreading amount. ii> $\prod$-A characteristics with a variation of barrier speed. iii> $\prod$-A characteristics with a variation of subphase temperature. An optimum surface pressure for a deposition of Langmuir-Blodgett(LB) layer was found to be a 40∼50 mN/m in pure water subphase (pH 5.4, $25^{\circ}C$).

Octa(2-ethylhexyloxy)copper-phthalocyanine LB막의 $NO_2$ 가스 탐지 특성에 관한연구 (A study on the $NO_2$ Gas Detection Characteristics of Octa(2-ethylhexyloxy)copper-phthalocyanine LB Films)

  • 임준석;김영관;김정수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1716-1718
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    • 1996
  • It is well known that the metallophthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as $NO_2$ and also chemically and thermally stable. Therefore, lots of MPcs are studied for the potential chemical sensor for $NO_2$ gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS spectrascopy and ellipsometry. Transfer condition, film characterization, and preliminary results of current-voltage(I-V) characteristics of these films exposed to $NO_2$ gas as a function of film thickness will be discussed.

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Octa(2-ethylhexyloxy)copper-phnthalocyanine LB막의 NO$_2$ 가스 탐지 특성에 관한 연구 (A study on the NO$_2$ Gas Detection Characteristics of Octa(2-ethylhexyloxy)copper-phthalocyanine LB films)

  • 임준석;김영관;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.162-165
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    • 1996
  • It is well shown that the metallophthalocyanine (MPcs) are sensitive to tonic gaseous molecules such as NO$_2$ and also chemically and thermally stable. Therefore, lots of MPcs are studied for the potential chemical sensor for NO$_2$ gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyaninc ware prepared by Langmuir-Blodgett method and characterized by using UV-VIS spectrascopy and cllipsometry. Transfer condition, film characterization, and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$ gas as a function of film thickness will be discusscd.

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금속이온 착체에 의한 IMI-O 고분잔 LB막의 전기적 특성 (Electrical Properties of IMI-O Polymer LB Films in Complexed Metal Ion)

  • 정상범;유승엽;박재철;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1519-1521
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    • 1997
  • In this paper, poly (N-(2-4-imidazolyl) ethyl) maleimide-alt-1-octadecene (IMI-O) polymer which can complex metal ion was used to confirm the possibility of molecular device made by Langmuir-Blodgett method. Metal/Insulator/Metal (MIM) device was fabricated for investigation of electric properties. In the ${\pi}$-A isotherm, surface pressure at collapse point was different as to the molecular weight of metal ion complexed respectively, In I-V characteristics, currents of MiM devices were different at the same voltage. It was thought that phenomena was occurred by interaction between function group and metal ion.

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유기박막의 전계자격에 의한 전기 특성에 관한 연구 (A study on the Electrical Properties by Electric Field Stimulus of Organic Thin Films)

  • 조수영;전동규;송진원;김해진;이우선;최영일;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.49-52
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    • 1999
  • We studied on the ultra thin DMPC by Langmuir-Blodgett(LB) method. The $\pi$ -A isotherm of the DMPC was measured at the air-water interface varying with the compressing speed and amounts of solutions for spreading. DMPC molecules have one phosphatidylcholine head group and two long alky groups with carbonyl group. Displacement currents generated during the compression of monolayers of DMPC on the surface of water were investigated. The molecular arrangement of deposited films were evaluated by measuring the absorption with the UVspectrometer. And we made structures of metal(Au)/DMPC/Metal(Au) and examined electron through DMPC LB films by means of current-voltage(I-V) measurement .

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TCNQ 유기초박막의 분자 배향 및 전기적 특성 (Molecular orientation and electrical properties of TCNQ ultrathin organic films)

  • 이용수;신동명;김태완;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.5-8
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    • 1997
  • A study on the electrical conduction characteristics of the ultrathin organic films is one of the important factors for the development of molecular electronic devices. The Langmuir- Blodgett(LB) technique has recently been attracted interest as a method of the deposition ultrathin films. We hate fabricated N-docosyl N\`-methyl viologen-diTCNQ(DMVT) anion radical LB film and investigated the molecular orientation and electrical conduction characteristics. We have measured infrared transmission-reflection spectra. The alkyl chain is found to he well-ordered with the tilt angle of 13$^{\circ}$ with respect to the substrate surface normal and the TCNQ plane is tilted at 76$^{\circ}$ the surface normal. In ESR spectrum, we confirmed that a half-amplitude linewidth is clearly dependent on the incident angle, which indicates conducting species change. The in-plane conductivity of 31 lagers is approximately 1.33$\times$10$^{-6}$ S/cm. The ohmic behaviour was observed below 0.6 V, when current-voltage(I-V) characteristics was measured verically.

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Effect of ligand orientation on hepatocyte attachment onto the poly(N-p-vinyl benzyl-o-$\beta$-D-galactopyranosyl-D-gluconamide)

  • 조종수
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1996년도 춘계학술대회
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    • pp.123-125
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    • 1996
  • The orientation effect of galactose ligand on hepatocyte attachment was investigated. Poly(N-p-vinyl benzyl-o-${\beta}$-D-galactopyranosyl-D-gluconamide) (PVLA), a ${\beta}$-galactose-carrying styrene homo-polymer, was used as a model ligand for the asialoglycoprotein receptors on hepatocytes. PYVA was transferred onto the poly(${\gamma}$-benzyl L-glutamate)(PBLG) or PBLG/ poly(ethylene glycol)(PEG)/PBLG Langmuir-Blodgett (LB) films as the monolayer level. The dichroic fluorescence values of confocal microscope indicated that the PVLA transferred onto the LB films was located with a preferential orientation of its molecular axes with regard to the direction of the a-helix of polypeptide. Hepatocyte recognized well-oriented galactose moieties of the surface of PVLA through asialoglycoprotein receptors.

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PBDG의 자격 전달에 관한 연구 (A Study on the Stimulation Transmit of PBDG)

  • 김동관;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1980-1982
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    • 1999
  • Conductive Langmuir-Blodgett(LB) films have recently attracted much interest from the viewpoint of ultrathin film conductors at the molecular level. The result shows that the Maxwell-displacement-current (MDC) measuring technique is useful in the detection of phase-transitions over the entire range of molecule areas. In this parer, electrical properties of PBDG Langmuir(L) films were investigated using a displacement current measuring technique with pressure stimulation. Displacement current was generated When the Spread volume $150{\mu}{\ell}$ and compression velocity was about 30, 40, 50 mm/min. In the result, it is known that current is generated of higher current peek as compression velocity become faster.

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Polyamic Acid 알킬아민 염의 랭뮤어-블로젯막 제작에 관한 연구 (A Study on the Preparation of Polyamic Acid Alkylamine Salt Langmuir-Biodgett Films)

  • 정순욱;임현성
    • 한국응용과학기술학회지
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    • 제17권4호
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    • pp.226-232
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    • 2000
  • Polyimide is a well-known organic dielectric material, which has not only high chemical and thermal stability but also good electrical insulating and mechanical properties. In this research, we have synthesized a polyamic acid(PAA), which is a precursor of the polyimide. To obtain the optimum conditions of polyamic acid alkylamine salt(PAAS) Langmuir-Blodgett(LB) film deposition, the ${\pi}-A$ isotherms were examined by varying subphase temperature, barrier moving speed and spreading amount of solution. Film formation was verified by measuring transfer ratio, absorption of UV/vis spectra and scanning electron microscope(SEM) images.