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Evaluation of Air Void System and Permeability of Latex-Modified Concrete by Image Analysis Method

  • Jeong, Won-Kyong;Yun, Kyong-Ku;Hong, Seung-Ho
    • International Journal of Concrete Structures and Materials
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    • v.19 no.1E
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    • pp.41-48
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    • 2007
  • Addition of latex to concrete is known to increase its durability and permeability. The purpose of this study is to analyze air void systems in latex-modified concretes using a reasonable and objective method of image analysis with such experimental variables as water-cement (w/c) ratios, latex contents (0%, 15%) and cement types (ordinary portland cement (OPC), high-early strength (HES) cement and very-early strength (VES) cement). The results are analyzed by spacing factor, air volume (content) after hardening, air void distribution and structure. Additionally, air void systems and permeability of latex-modified concrete (LMC) are compared by a correlation analysis. The results are as follows. The LMC of the same w/c ratio showed better air entraining (AE) effect than OPC with AE water reducer. The VES-LMC showed that the quantity of entrained air below $100{\mu}m$ increased more than four times. For the case of HES-LMC, microscopic entrained air between the range of 50 to $500{\mu}m$ increased greater than 7 times even in the absence of anti-foamer. Although spacing factor was measured rather low, the permeability of latex-modified concrete was good. It is construed that air void system does not have a considerable effect on the property of latex-modified concrete, but latex film (membrane) has a definite influence on the durability of LMC.

Studies on the Aging Behavior of Coated Paper(I) -Effect of latex on optical properties of coated paper during dry heat aging- (도공지 노화에 관한 연구(I) - 도공지 강제열화 시 라텍스가 도공지의 광학적 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.11-16
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    • 2011
  • This study was carried out in order to elucidate the effect of latex dosage and properties on aging behavior of coated paper. The coated paper with five different coating formulations were prepared and also four different latices were used. The coated paper were thermally aged at $105^{\circ}C$ for 14 days and the optical properties were measured. Increasing latex content increased the magnitude of reduction in brightness and whiteness. In addition, the variations in CIE a$^*b^*$ were larger with increasing latex dosage. Latex which has the lower gel content and the higher Tg showed the higher reduction in brightness and whiteness and much variation in CIE a$^*b^*$. However the particle size of latex didn't affect to thermal behavior of coated paper. These results indicate that latex which has higher Tg and lower gel content is the one of the main factors affecting aging behavior of coated paper.

Application Technology of Environmental-friendly Starch-based Biobinder and Synthesized Binder in order to Substitute SB Latex for Paper Coating (1) - Application of Substitute Binder for Pre-coating Layer - (SB latex 대체용 친환경 전분계 바이오바인더 및 합성바인더의 적용 기술 개발 (제1보) - 대체용 바인더의 Pre-coating 적용 -)

  • Lee, Yong Kyu;Kim, Sun-Goo;Won, Jong Myoung;Kim, Young-Hun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.134-140
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    • 2015
  • This study was carried out to evaluate whether EVAc, acryl latex and biobinder could substitute the part of SB latex for pre-coating color formula or not. Different coating colors prepared through the substitution of 30% SB latex with EVAc, acryl latex, and biobinder were applied for pre-coating layer. 100% SB latex is used as a binder for top coating color. The optical properties, gloss, roughness, stiffness, dry- and wet-pick strength were measured. There were no significant differences in the brightness, whiteness, opacity, roughness, ink set-off and gloss of paper coated with 5 different coating colors. However the stiffness, dry- and wet-pick strength were somewhat lower than those of conventional coating color which 100% SB latex was used as a binder. Although the part of SB latex could be substituted with EVAc, acryl latex and biobinder without sacrificing the qualities of coated paper. Further researches on the improvement of stiffness, dry- and wet-pick strength, and the optimization of rheology of coating color in order to improve the qualities of coated paper are strongly recommended.

The Surface Sizing Effect of Oxidized Starch on the Printability of Newspaper (국산 신문 용지에서 산화전분에 의한 표면 사이징 처리가 인쇄적성에 미치는 영향)

  • 하영백
    • Journal of the Korean Graphic Arts Communication Society
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    • v.15 no.2
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    • pp.25-40
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    • 1997
  • This research was carried out to investigated the effect of base paper and latex binder on printability and obtical properties of coated paper. Especially, it examined the effect of th pH of vase paper surface and functional groups of latices on the interactions between coating color components and on the structure of coated layer. It was found that the behavior of coating color containing amphoeric latex depends on the pH in the boundary region between coating color and base paper. Thus, the coating color formulated with amphoteric latex formed bulky coating layer by inducing stronger interaction between paper surface and coating components than the coating color with anionic latex. The coated paper with amphoteric latex showed better optical properties (i.e.gloss and optical) and printability (i.e. ink receptivity, wet ink receptivity, and ink set off) than the conventional anionic latex in the acidic and alkaline paper. However, dry pick strength of the coated paper was less decreased. This result indicated that amphoteric latex could also be applied practically to the alkaline paper.

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Freezing and Thawing Resistance of Latex Modified Concrete with Latex Content (라텍스 혼입에 따른 LMC의 동결융해 저항특성평가)

  • 이주형;정원경;김동호;이봉학;원치문;이정호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.497-502
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    • 2000
  • This study was performed to change the latex content for properties of freezing-thawing resistance. When styrene-butadiene latex is added to portland cement, aggregate and water, a concrete with the color, consistency and workability of ordinary conventional concrete results, but with 20% to 35% less water. When cured, the concrete consists of hydrated cement and aggregate interconnected by a film of latex particles. In general, increasing the amount of latex will produce concrete with increased tensile and flexural strength and lower modulus of elasticity. Air entrainment has been used in conventional concrete for the past 50 years to impart freeze-thaw resistance. Latex modified concrete does not need additional air entrainment for freeze-thaw resistance provided adequate cure occurs.

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Studies on the Coating Structure and Printability of Coated Paper(II) - Effect of Ionic Groups of Latices on Coating Structure - (도공층 구조 및 도공지의 인쇄적성에 관한 연구(II) - 라텍스 이온기가 도공층 구조에 미치는 영향 -)

  • Lee, Yong-Kyu;Park, Kyu-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.4
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    • pp.10-16
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    • 1997
  • This study was carried out to improve coating structure by controlling the electrostatic interaction of coating components and by changing the coating structure of coated paper prepared with amphoteric and anionic latices. The results indicated that amphoteric latex copolymerized with carboxylic and amine groups had stronger interaction with other coating components than anionic latex with branched carboxylic group by controlling pH. These properties of amphoteric latex showed positive effects on viscosity rheology, and supernatant sediment of coating color. The coated paper using amphoteric latex had also produced more porous and smoother coverage of the coating layer than that using anionic latex. This porous and smooth coating layer showed better optical properties and printability than those of anionic latex such as opacity, porosity, ink set-off, and wet ink receptivity.

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A Study on the Reduction of Combined Deterioration by Mixing Latex in Base Concrete (바탕콘크리트의 라텍스 혼입에 따른 복합열화 저감에 관한 연구)

  • Kim, Dae-Geon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.101-102
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    • 2023
  • This study aims to mix the base concrete by mixing latex to improve the durability performance to reduce the composite deterioration of the base concrete. Latex fiber has high resistance to freezing and thawing, adhesion, and deicing agent (calcium chloride), and it is used to secure long-term durability to reduce cracking and compound deterioration of concrete. In addition, through experiments, we are trying to find ways to improve the strength of concrete by studying the mixing of the appropriate mixing ratio of latex.

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Permeability and Freeze-Thaw Resistance of Latex Modified Concrete (라텍스 개질 콘크리트의 투수성 및 동결융해 저항 특성)

  • 김기헌;이종명;홍창우;윤경구
    • Journal of the Korea Concrete Institute
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    • v.13 no.5
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    • pp.484-490
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    • 2001
  • This study focused on the investigation of durability of latex modified concrete in the points of chloride ion permeability and freeze-thaw resistance as latex content variated such as 5%, 10%, 15% and 20%. When latex was mixed in concrete and cured, the concrete consisted of hydrated cement and aggregate interconnected by a film of latex particles. An increasing the amount of latex produced concrete with increased flexural strength, but with slightly lower compressive strength. The increase in flexural strength might be attributed to the latex films between the hydrated cement and aggregates, and the decrease in compressive strength to the flexibility of the latex component named by Butadiene. The rapid chloride permeability test was used to evaluate the relative permeability of latex-modified concretes and conventional concretes. The results showed that the permeability of latex-modified concretes was considerably lower than conventional concretes tested, which might be due to the latex filled in voids and interconnections of hydrated cement and aggregates by a film of latex particles. The freeze-thaw resistance of LMC was quite good comparing to conventional concrete. Air entraining agent has been used in conventional concrete to improve the freeze/thaw resistance, but latex modified concrete does not need additional air entraining agent for freeze-thaw resistance provided adequate cure occurs.

The Quantitative Analysis of SB Latex Contents in Coating Color and Coating Layer of Coated Paper Using FT/Raman Spectroscopy (FT/RAman을 이용한 도공액과 도공지의 도공층 내의 SB Latex 정량분석)

  • 이복진;정순기;윤동호;마금자
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.16-22
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    • 1999
  • The quantitative analysis of SB latex contents in coating color and coated paper was investigated with FT/Raman spectroscopy. From the measured FT/IR and FT/Ramon spectra, the peaks of coating color were compared with those of each compoents . Calibration curves were obtained by the area of latex peaks and PLS method of QuantIR program. The relation of predicted values in PLS method and actual values in coating mixtures and coating layer was examined. The components of coating layer in coated paper were investigated by EDS , X-mapping and SEM, The contents of latex in z-direction were calculated in the coating layer of unknown coated paper. The latex concentration measurements of Top layer and Pre layer in double coated paper show that each layer has different value. In single coated paper, it is clear that the latex concentration is highest at the surface and decreases with an increase of depth. From those results it is indicated that the latex migrates to the coated surface. The result of this study may be applied to the binder migration study and the quality control in paper mill.

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Comparative Analysis of Latex Plants by GC-MS using Methanol Extraction

  • J. Varshini Premakumari;M. Job Gopinath;B. Narmadha
    • Mass Spectrometry Letters
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    • v.14 no.1
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    • pp.9-23
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    • 2023
  • Plants are able to produce a large number of diverse bioactive compounds. Solvent extraction is used for isolation of plant metabolites. The extract yield for plant metabolite extraction strongly depends on the nature of solvent. A review showed the methanol can yield more bioactive compounds. Drying of the sample material is also important for the extraction of plant material. The present study was carried out to analyze the phytocomponents of 5 different latex producing plants. The plants like Calotropis gigantea, Carica papaya, Nerium oleander, Ficus benghalensis and Plumeria alba leaves and latex. The GC-MS analysis of the metabolites revealed phytocomponents. Calotropis gigantea leaves showed 14 compounds and latex produced 5 compounds out of this 4,4,6A,6B,8A,11,11,14B-Octamethyl-1,4,4A,5,6,6A,6B,7,8,8A,9,10,11,12,12A,14,14A,14B-Octadeca-hydro-2 and 2R- Acetoxymethyl-1,3,3-trimethyl-4T-(3-Methyl-2-Buten-1-Yl)-1T-Cyclohexanol compound was present in both latex and leaf extraction. Beta. -carotene compound was present in both latex and leaf of Carica papaya. It was observed that Ficus benghalensis contained 2R-Acetoxymethyl-1,3,3-trimethyl-4T-(3-Methyl-2-Buten-1-Yl)-1T-Cyclohexanol was same in latex and leaf extraction.