• Title/Summary/Keyword: LAS-Na

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Acute Toxicity of Surfactants LAS-Na and MES in Mice (마우스에서 계면활성제 LAS-Na와 MES의 급성 경구독성)

  • 김효정;이호;서경원;오미현;선우유신
    • Journal of Food Hygiene and Safety
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    • v.8 no.3
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    • pp.163-169
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    • 1993
  • The acute toxicity of lAS-Na(Linear Alkylbenzene Sulfonate-Na) and MES (ASME, Alpha-Sulfo fatty acid Methyl Ester), surfactans, was eyaluated in ICR mice for 14 days. Mice aging 6 weeks were administered orally with 0, 1,000, 1,320, 1,780, 2,280, 3,000 mg/kg of lASNa or 0, 1,000, 1,560, 2,450, 3,830, 6,000 mg/kg of MES in saline. The body weight of the treated animals was not significantly different from the controls. The main clinical signs of animals treated with lAS-Na or MES were diarrhea, decreased motor acthity and piloerection. The congestion in small intestine was only gross finding in dead animals treated with two sulfactants. In this study, $LD_{50}$ values of lAS-Na and MES were eyaluated 1,319 mg/kg in male and 1,402 mg/kg in female mice, 2,040 mg/kg in male and 2,548 mg in female mice, respectiyely.

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The Surface Activities of Surfactant Mixtures (혼합 개면활성제의 개면활성에 관한 연구)

  • 정혜원
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.3
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    • pp.348-354
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    • 1994
  • The changes of surface activities in the aquaous solutions of mixed surfactants composed of linear sodium dodecylbenznesulfoate (LAS), polyoxyethylene nonyl phenylether (PE, EO=10) and polyethylene glycol monolauryl ether (LE, EO=25) have been studied. Addition of nonionic surfactants to LAS reduces the surface tension, especially at the lower concentration than cmc. The interfacial tension of olive oil/LAS was lower than the other surfactant solutions. The removal of triolein from cotton fabrics by nonionic surfactants and mixtures is higher than by LAS. The addition of NaCI to surfactant solutions even though reduces surface tension smaller but enthances oil removal more than that of $CaCl_2$.

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Studies on the Dynamic Surface Tension of GL12 and Anionic Mixtures (N-Dodecanoyl, N-Methyl Glucamine(GL 12)과 음이온 계면활성제 혼합물의 Dynamic Surface Tension에 관한 연구)

  • Ahn, Ho-Jeong;Choi, Kyu-Suk
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.101-108
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    • 1996
  • The dynamic surface tension of GL12 (easily biodegradable nonionic surfactant and mild to skin), LAS and SLES aqueous solutions and that of mixed surfactant systems were measured by the maximum bubble pressure method at different mixing ratios. The effects of various salt such as NaCl, CsCl and urea on the dynamic surface tension of mixed surfactant systems were also studied. The dynamic surface tension of GL12 was not influenced by the presence of salts. On the contrary, the dynamic surface tensions of anionic surfactants (LAS and SLES) were significantly affected by the salts. In the mixed surfactant systems, the effect of salt increased as the composition of anionic LAS or SLES increased in the GL12/LAS and GL12/SLES mixtures.

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Studies on the Solubilizing Capacity of GL-12 and Anionic Surfactant Mixtures (N-Dodecanoyl, N-Methyl Glucamine (GL-12)과 음이온 계면활성제 혼합물의 가용화력에 관한 연구)

  • Ahn, Ho-Jeong;Oh, Seong-Geun;Choi, Kyu-Suk
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.881-885
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    • 1997
  • The solubilizing capacity of GL-12, LAS, SLES aqueous solutions and that of mixed surfactant systems were studied using sudan III, which is oil-siluble dye. The solubilizing capacity of mixed surfactant systems was greatly influenced by the mixing ratios. Generally, the solubilizing capacity increased as the composition of GL-12 in the mixed systems increased. From the effect of NaCl on the solubilizing capacity, it was found that the solubilizate is located near the palisade layer in the GL-12/LAS system, and the solubilizate is located inside the micellar core in the GL-12/SLES mixed system. These differences in the location of slubilizate inside micelles result from the difference of molecular structure between LAS and SLES.

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Extraction of Cd and Pb from Soil by Anionic Surfactant and Ligand NaI (NaI 리간드화 계면활성제에 의한 토양내 Cd과 Pb 추출 연구)

  • Heo, Jung-Hyun;Jeong, Seung-Woo
    • Journal of Soil and Groundwater Environment
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    • v.13 no.5
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    • pp.74-80
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    • 2008
  • Heavy metals, Cd and Pb, in soil were extracted by using anionic surfactants such as AOS (alpha olefin sulfonate), SDS (sodium dodecyl sulfate), and LAS (linear alkyl benzene sulfonic acid). Metal extractability from soil was affected by the carbon number and solution pH of surfactants. LAS showed higher metal extractability due to the acidic solution condition. Although SDS has a fewer carbon number than AOS, it would produce smaller micelles and resulted in more efficient extraction of metals by increased soil contact. Cd extractability of surfactant was twice enhanced by adding NaI as a ligand. However, Pb extractability of surfactant was sometimes reduced by adding NaI. Those ligand effects were dependent on solubility of metal-ligand. The column experiment also showed that SDS having smaller micelles resulted in higher metal extractability than AOS.

Detergency of Soluble Sodium Silicate (수용성 규산나트륨의 세정성)

  • Ha, Youn-Shick;Park, Kyeong-Il;Seo, Moo-Lyong
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.13-21
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    • 1999
  • Silicate used as laundry detergent builder was good for pH buffering capacity and solubility but calcium-ion binding capacity and surfactant adsorption ability were lower. As $SiO_2/Na_2O$ molar ratio became higher, pH buffering capacity and ion exchange ability were lower and surfactant adsorption ability was little higher. Anionic surfactant LAS (linear alkylbenzene sulphonate), nonionic surfactant LA-9 (lauryl alcohol EO-9) were used to investigate the detergency performance. Zeolite was better than sodium silicate in detergency performance. In case of LAS, detergency performance was good when $SiO_2/Na_2O$ molar ratio was lower. In case of LA-9, detergency performance was similar without discrimination of molar ratio of $SiO_2/Na_2O$.

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Library Anxiety and library Anxiety Scale in the Digital Library Environment (디지털 도서관에서의 도서관불안과 측정도구 분석)

  • Kwon, Na-Hyun
    • Journal of the Korean Society for Library and Information Science
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    • v.38 no.2
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    • pp.29-47
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    • 2004
  • As affective barriers to library and information use, library anxiety(Mellon, 1986) has been studied in reference/information services and bibliographic instructions. The paper revisits Mellon's theory of library anxiety and Bostick's(1992) Library Anxiety Scale(LAS) in the digital library environment. In particular, this study attempts to address the inadequacy of the continued applications of LAS in the digital library environment, although the scale has been used unquestionably as the instrument measuring library anxiety. This contention was substantiated by three service trends in digital libraries(i.e., digital reference services, remote access, and transition from bibliographic instructions to information literacy) and by re-analyses of published library anxiety research papers in recent years. This study addresses the need for scale development that could measure anxieties of digital library users. It also suggests Information Literacy Anxiety Scale(ILAS) as a direction for the new scale.

Properties of Microbial Surfactant S-acid (미생물 계면활성제(S-acid)의 특성조사에 관한 연구)

  • 정해권;이정복임건빈김은기
    • KSBB Journal
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    • v.10 no.1
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    • pp.71-77
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    • 1995
  • Characteristics of S-acid and its derivatives, as biosurfactants, were investigated. Sodium salt of S-acid(S-lNa) effectively decreased the surface tension to near 30 dyne/cm and showed superior dispersing ability than commercial surfactants such as SDS and Tween 80. The emulsion made by S-lNa could be maintained even with increased concentration of calcium ion. Also the penetratlng ability of S-lNa was observed as effective as that of LAS. All derivatives of S-acid were degraded by microorganisms much faster than conventional surfactants. Among the derivatives, S-3Na prevented rust formation as effectively as commercial anti-rust agents did.

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Adsorption Characteristics of Cu(II) in the Presence of Surfactants on Natural Zeolites Treated Chemically and Thermally (가열 및 화학처리된 천연 제올라이트의 계면활성제 수용액 내에서 Cu(II)흡착특성)

  • Sun, Y.S.;Kim, P.K.
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.849-860
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    • 1996
  • Natural zeolites which were known to occur in sedimentary clinoptilolite, were treated by thermal and chemical methods, and their adsorption characteristics of Cu(II) were studied. Analyses by FT-IR, S. E. M, TGA/DSC, and XRD showed that the adsorption capacity of Cu(II) on the zeolite decreased gradually at the temperatures of above $400^{\circ}C$. The zeolites, which treated with NaOH and NaCl, show higher absorbility in acid solution. The adsorption rate of Cu(II) in the presence of surfactants(LAS, POE AE) on the thermally or chemically treated zeolites varied depending on pH, anion or nonion surfactants.

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Effect of $Na^+$ Removal on the Action of Ethanol in Cat Ileal Longitudinal Muscle (장관 평활근에서 Na-free용액이 Ethanol의 효과에 미치는 영향)

  • Suh, Duk-Jun;Kim, So-Sun;Woo, Jae-Suk;Kim, Young-Keun
    • The Korean Journal of Physiology
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    • v.20 no.1
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    • pp.125-133
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    • 1986
  • The effect of ethanol on the contraction of intestinal smooth muscle in Na-free solution was studied using cat ileal longitudinal muscle strips. Ethanol $(0.5{\pm}4%)$ inhibited both the spontaneous mechanical activity and base-line tension in normal physiological salt solution. However, in Na-free solution it induced a reversible contraction. The excitatory effect by ethanol in Na-free solution was increased with increasing the concentrations of ethanol and the time incubated in Na-free solution. The excitatory response by ethanol was reduced by increasing the concentrations of Na in incubated medium . Ethanol-induced contractile response was not affected by $Ca^{2+}$ removal in bathing medium. In Na-free solution, the contraction by ethanol was inhibited by Las. but was not affected by verapamil. The contraction induced by Na removal in solution was inhibited by the pretreatment of ethanol. These results suggest that ethanol may induce the contraction by increasing the release of superficially membrane-bound $Ca^{2+}$ and/or intracellular $Ca^{2+}$ in Na-free physiological salt solution.

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