• The Journal of the Petrological Society of Korea
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• v.13 no.4
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• pp.238-243
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• 2004

Duwon meteorite was fallen on 23 November 1943 in Duwonmyeon, Goheung, Jeolanam-Do. We measured rare earth element abundance of Duwon meteorite by isotope dilution thermal ion mass spectrometry (ID-TIMS) and ICP-MS. As a result, except La and Ce, abundance of other rare earth element show a correspondence within 10％ of error range. However, La and Ce show more than 70％ in abundance, which is considered due to 1) experimental procedure or 2) inhomogeneity of sample. Leedey meteorite was fallen on 25 November 1943 in Dewey County, Oklahoma, USA. which suggested that fallen difference between Leedey and Duwon meteorites is only 2 days. Leedey and Duwon meteorites are classified as ordinary chondrite of L6 type. In Leedey chondrite-normalized REE pattern, Duwon meteorite shows nearly flattened, which suggests close relationship between Leedey and Duwon meteorites meteoritically or cosmochemically.

• Journal of the Korean earth science society
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• v.43 no.3
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• pp.405-429
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• 2022

Detrital zircon LA-MC-ICP-MS U-Pb dating of the Cretaceous Gurye Group, Gurye Basin, was carried out. Gurye Group consists of Supyeongri, Geumjeongri, Togeum, and Obongsan formations in ascending order, and five samples were collected for age dating. Based on the dating results, the lowermost Supyeongri and the uppermost Obongsan formations show narrow age ranges. Only Precambrian and Late Cretaceous zircons were found in the Supyeongri and Obongsan formations, respectively. However, the upper and lower Geumjeongri, and Togeum formations show wide age ranges from the Precambrian to Cretaceous. The youngest detrital zircon U-Pb ages of each formation except the Supyeongri Formation, which lacks Cretaceous zircon, were calculated to be ca. 107.4 Ma in the lower Geumjeongri Formation, ca. 104.6 Ma in the upper Geumjeongri Formation, ca. 97.7 Ma in the Togeum Formation, and ca. 88.5 Ma in the Obongsan Formation. Such results indicate that the depositional age of the Gurye Group can be constrained from the Lower Cretaceous Albian to the Upper Cretaceous Coniacian. Based on the distribution of the detrital zircon ages from each formation, the source area of the Gurye Group is interpreted to have been extended from the adjacent Youngnam Massif to the Okcheon Belt throughout the basin evolution. The increase of the Cretaceous zircon with time is thought to reflect the slab roll-back of the proto-Pacific plate during the Cretaceous.

• Nuclear Engineering and Technology
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• v.43 no.3
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• pp.309-316
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• 2011

Molybdenum is the most abundant fission product since its fission yield is equivalent to that of xenon, and it has a very special role in the chemistry of nuclear fuel because it influences the oxygen potential of $UO_2$ fuel. In this study, the distribution of molybdenum in spent $UO_2$ fuel specimens with 33.3, 41.0 and 57.6 GWd/tU burnup was measured by a LA-ICP-MS system and the reproducibility of the measured data was obtained. The Mo distribution was almost constant along the radius of a fuel except an increase at the periphery of the fuel. It showed a drop in reproducibility with relatively high deviation of measured values for the highest burnup fuel. To explain this, the state of molybdenum in a $UO_2$ matrix and its effect on the oxidation behavior of $UO_2$ were investigated. The low reproducibility was explained by the segregation of molybdenum, and the inhibition of oxidation by the molybdenum was also observed.

• Economic and Environmental Geology
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• v.54 no.2
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• pp.213-232
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• 2021

Ore criteria at the Sheba Deposit indicate orogenic mineralization type. Rocks and mineral assemblages suggest low formation-temperature of green-schist facies. Pyrite found in two generations; Type1 is irregular grains, contains higher arsenic and gold contents, compared to the relatively younger phase Type2 pyrite, which is composed of euhedral grains, found adjacent to late quartz-carbonate veins or at rims of type1 pyrite. Two gold generations were identified; type1 found included in sulphides (mainly pyrite). The second gold type was remobilized (secondary) into free-lodes within silicates (mainly quartz). Gold fineness is high, as gold contains up to 95 wt. % Au, Ag up to 3.5 wt. %, and traces of Cu, Ni, and Fe. Pyrite type2 contains tiny mineral domains (rich in Al, Mn, Hg, Se, Ti, V, and Cr). Zoning, and replacement textures are common, suggesting multiple mineralization stages. The distribution and relationships of trace elements in pyrite type2 indicate three formation patterns: (1) Al, Mn, Hg, Se, Ti, V, Cr, and Sn are homogeneously distributed in pyrite, reflecting a synchronous formation. (2) As, Ni, Co, Zn, and Sb display heterogeneous distribution pattern in pyrite, which may indicate post-formation existence due to other activities. (3) Au and Ag show both distribution patterns within pyrite, suggesting that gold is found both in microscopic phases and as chemically bounded phase.

• Journal of the Korean earth science society
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• v.41 no.4
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• pp.367-380
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• 2020

LA-MC-ICP-MS zircon U-Pb dating was conducted to constrain the timing of fossil formation and the depositional age of the uppermost Jinju Formation located in Natural Monument No. 534 (Tracksite of Pterosaurs, Birds, and Dinosaurs in Hotandong, Jinju), and 87 Cretaceous, 1 Precambrian, and 2 Jurassic zircons were obtained from 90 valid analytical points. Most Cretaceous zircons were found to have a youngest graphical peak age of ca. 106.5 Ma, suggesting the depositional age of the uppermost Jinju Formation. Based on this study and previous works, the average sedimentation rate of the Jinju Formation was calculated to be approximately 0.17-0.31 mm/year in the Milyang Subbasin, and the Cretaceous zircons of the uppermost Jinju Formation seem to have originated mainly from the western or northwestern parts of the Gyeonggi Massif. Unlike the Nakdong and Hasandong formations of the Sindong Group, most zircons analyzed in the uppermost Jinju Formation were Cretaceous. This suggests that volcanic activity occurred in the area closer to the Gyeongsang Basin due to the roll-back of subducting paleo-Pacific Plates during the Jinju period.

• Economic and Environmental Geology
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• v.51 no.4
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• pp.323-343
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• 2018

This study defines the mineralogical, micro-textural and geochemical characteristics for the carbonate rocks and discusses the fluids that have affected the depositional environment of the Lower Makgol Formation in Seokgaejae section. Based on analysis of X-ray Diffraction (XRD), Scanning Electron Microscope-Energy Dispersive X-ray Spectrometry (SEM-EDS), Electron Probe Micro Analyzer-Wavelength Dispersive X-ray Spectrometry (EPMA-WDS) and Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS), carbonate miorofacies in the basal and the lower members of the Makgol Formation are distinguished and classified into four types. Type 1 dolomite (xenotopic interlocking texture) and Type 2 dolomite (idiotopic interlocking texture) have relatively high Mg/Ca ratio, flat REE pattern, low Fe and Mn. Extensively interlocking textures in these dolomites indicate constant supply of Mg ion from hypersaline brine. Type 3 and Type 4 dolomite (scattered and loosely-aggregated texture) have relatively moderate Mg/Ca ratio, MREE enriched pattern, low to high Fe and Mn. These partial dolomitization indicate limited supply of Mg ion under the influx of meteoric water with seawater. Also, the evidence of Fe-bearing minerals, recrystallization and relatively high Fe and Mn in Type 4 indicates the influence of secondary diagenetic fluids under suboxic conditions. Integrating geochemical data with mineralogical and micro-textural evidence, the discrepancy between the basal and the lower members of the Makgol Formation indicates different sedimentary environment. It suggest that hypersaline brine have an influence on the basal member, while mixing meteoric water with seawater have an effect on the lower member of the Makgol Formation.

• Economic and Environmental Geology
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• v.53 no.4
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• pp.397-411
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• 2020

The Cretaceous Yucheon Group is volcano-sedimentary successions that are formed by volcanic activities of the Gyeongsang Volcanic Arc. Lack of the detailed field researches on the Yucheon Group results in poor understanding of the formation time and the tempo-spatial development of the volcanic arc. Also, this causes difficulties to reconstruct the depositional history from the Sindong and Hayang groups to the Yucheon Group. In this study, we conducted field research targeting to the interface between topmost part of the Hayang Group and the lowermost part of the Yucheon Group from Hyeonpoong to Bugok areas. We also identified depositional timing of the lowermost part of the Yucheon Group using SHRIMP U-Pb zircon age dating. This Yucheon Group is composed of tuff and lapilli tuff, conformably overlying the Jindong Formation. The results of SHRIMP U-Pb zircon age are 97 to 96 Ma, indicating cessation of deposition of the Hayang Group at 97 to 96 Ma by input of pyroclastic materials into the Jinju Subbasin during the explosive volcanic eruptions from the Gyeongsang Volcanic Arc. In comparison with field researches and results of LA-ICP-MS zircon U-Pb age dating (88-85 Ma) of the lowermost part of the Yucheon Group in Gyeongju areas, the volcanic activities that formed Yucheon Group and their influence ranges varied tempo-spatially. This is probably due to distance difference from the volcanic arc or establishment of the paleo-drainage system from the Gyeongsang Volcanic Arc to nearby lowlands.