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Characterization of Stormwater Pollutants Runoff in Industrial Complex (강우시 산업단지에서의 오염물질 유출특성)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Jong-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.341-353
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    • 2000
  • The purpose of this study is to investigate the characteristics of pollutants overflow on storm events and the first flush analysis in industrial complex. Eight sub-basins in the Chongju industrial complex were selected for sampling and study with different characteristics during the period from June 1997 to August 1998. Water quality parameters of stormwater runoff such as $BOD_5$, COD, SS, TKN, $NO_3-N$, $PO_4-P$, TP, n-Hexane extracts, Cr, Cu, Pb and Fe were analyzed. During the storm events, measured concentration ranges of $BOD_5$, COD, SS, $NO_3-N$, TKN, $PO_4-P$, TP, r-Hexane extracts, Cr, Cu, Pb and Fe were 2~324 mg/L, 5~810 mg/L, 1~1,110 mg/L, 0.01~10.89 mg/L, 0.1~59.8 mg/L, 0.08~7.02 mg/L, 0.1~7.8 mg/L, 0.1~1,723.6 mg/L, 0.001~0.363 mg/L, 0.001~0.488 mg/L, 0.001~1.28 mg/L, and 0.26~18.91 mg/L, respectively in the industrial complex watersheds. And a quantitative of first flush has been presented. First flush occurs more frequently as the ratio of impervious area increases.

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A Parallel Algorithm for Construting the Delaunay Triangulation in the $\textrm{L}_\infty$($\textrm{L}_{1}$) Metric (디루니 삼각분할의 병렬처리 알고리즘)

  • 위영철;황시영
    • Proceedings of the Korean Information Science Society Conference
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    • 2000.10a
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    • pp.545-547
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    • 2000
  • 본 논문은 영역별 근접 그래프(geographic nearest neighbor graph)와 레인지 트리(range tree)를 이용하여 평면 위의 n 개의 점에 대한 L$\infty$(L1) 거리(metric) 상의 디루니 삼각분할(Delaunay triangulation)을 구축하는 방법을 소개한다. 이 방법은 L$\infty$(L1) 거리상에서 디루니 삼각분할에 있는 각 삼각형의 최소한 한 선분이 영역별 근접 그래프에 포함됨을 이용하여 레인지 트리 방법으로 디루니 삼각분할을 구축한다. 본 방법은 O(nlogn)의 순차계산 시간에 L$\infty$(L1) 디루니 삼각분할을 구축하며, CREW-PRAM (Concurrent Read Exclusive Write Programmable Random Access Machine)에서 O(n)의 프로세서로 O(logn)의 병렬처리 시간에 L$\infty$(L1) 디루니 삼각분할을 구축한다. 또한, 이 방법은 직선간의 교차점 계산 대신 거리비교를 하기 때문에 수치오차가 적고 구현이 용이하다.

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Synthesis of Nucleophilic Adducts of Thiols (Ⅳ). Addition of Glutathione to $\beta$-Nitrostyrene Derivatives

  • Kim, Tae-Rin;Choi, Sung-Yong;Choi, Won-Sik
    • Bulletin of the Korean Chemical Society
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    • v.4 no.2
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    • pp.92-95
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    • 1983
  • The addition products of glutathione to ${\beta}$ -nitrostyrene derivatives were synthesized. ${\beta}$ -Nitrostyrene (1a), p-methyl-${\beta}$-nitrostyrene (1b), 3,4,5-trimethoxy-${\beta}$-nitrostyrene (1c), o-, m- and p-chloro-${\beta}$-nitrostyrene (1e, 1f, 1g) and o-, m- and p-methoxy-${\beta}$-nitrostyrene (1h, 1i, 1j) undergo addition reactions with glutathione to form S-(2-nitro-1-phenylethyl)-L-glutathione (5a), S-[2-nitro-1-(p-methyl)phenylethyl]-L-glutatione (5b), S-[2-nitro-1-(3', 4', 5'-trimethoxy)phenylethyl]-L-glutathione (5c), S-[2-nitro-1-(o-chloro)phenylethyl]-L-glutathione (5e), S-[2-nitro-1-(m-choro)phenylethyl]-L-glutathione (5f), S-[2-nitro-1-(p-chloro)phenylethyl]-L-glutathione (5g), S-[2-nitro-x-(o-methoxy)-phenylethyl]-L-glutathion e(5h), S-[2-nitro-x-(m-methoxy)phenylethyl]-L-glutathion e (5i), and S-[2-nitro-1-(p-methoxy)phenylethy])-L-glutathione (5j), respectively. The structure of adducts were identified by UV and IR-spectra, molecular weight measurement, and elemental analysis.

In Vitro Propagation of Guzmania cv. Cherry by Axillary Shoot Culture (측지배양에 의한 Guzmania cv. Cherry의 기내 대량번식)

  • 한봉희;최성렬;정향영
    • Korean Journal of Plant Tissue Culture
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    • v.25 no.1
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    • pp.33-36
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    • 1998
  • Guzmania was propagated through in vitro culture of lateral shoots. When new shoots grown in greenhouse were cut and cultured in vitro, contamination rate was very high at about 80% in the first stage of in vitro culture. Among cytokinin treatments for agar medium, 2.0 mg/L BA was most effective for shoot multiplication, and those with 0.5 mg/L kinetin and 0.5~1.0 mg/L BA were favorable for shoot multiplication. BA was more effective for shoot multiplication than kinetin, and shoot multiplication was more enhanced when 2.0 mg/L BA was combined with 0.1~0.5 mg/L IAA than 2.0 mg/L BA alone. The medium with 2.0 mg/L BA and 0.1 mg/L IAA showed the highest rate of shoot multiplication with about 8.7 in shoot number, and those with 2.0 mg/L BA and 0.5~1.0 mg/L IAA also resulted in high multiplication of shoots. Shoots were multiplicated more in liquid rotation culture(80 rpm) with the medium containing 0.5 mg/L BA and 0.1 mg/L IAA than liquid stagnating and solid cultures. Regenerated shoots formed roots very favorably in the medium supplemented with 2.0 mg/L IBA.

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IL-1 gene polymorphisms in Korean periodontitis patients (한국인 치주염 환자에서의 IL-1 유전자 다변성 연구)

  • Nam, Seung-Ji;Chung, Hyun-Ju;Kim, Ok-Su;Kim, Young-Joon;Koh, Jung-Tae
    • Journal of Periodontal and Implant Science
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    • v.34 no.3
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    • pp.623-637
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    • 2004
  • 중증 만성 치주염과 1L-1B+3954 및 1L-1A+4845 유전자의 대립유전자 2 보유 유전자 다변성이 관련된다고 보고되었다. 그러나 이러한 1L-1 복합유전자 다변성과 만성 치주염 및 급진성 치주염과의 관련성에 대해서는 상반되게 보고되고 있는데 이는 인종적 배경과 질환특성의 차이에 기인한 것으로 보인다. 이 연구는 한국인에서 경도, 중등도와 중증의 만성 치주염 그리고 급진성 치주염 환자를 대상으로 하여 1L-1A+4845, 1L-1B+3954, 1L1B-511, 1L-1 RN intron 2 (VNTR) 유전자 다변성의 분포를 평가하고, 치주질환의 심도와 유형에 관련되는지 알아보고자 시행되었다. 전남대학교 병원 치주과에서 검진과 치료를 받은 100명의 치주질환자를 대상으로 하였고 질환군은 치주낭 깊이, 부착 소실, 골 소실을 기준으로 하여 경도, 중등도, 중증의 만성 치주염, 급진성 치주염군으로 분류하였다. 대조군으로는 전남대학교 병원 소아치과에 내원한 전신적으로 건강한 92명의 아동을 포함하였다. 각 대상 환자에서 채취된 협점막상피에서 genomic DNA를 얻어 1L-1A+4845, 1L-1B+3954, 1L-1B-511 genotype은 중합효소 연쇄반응을 시행한 후 제한 효소분해과정을 거쳐 전기영동 후 분리한 결과를 해석하였으며 1L-1 RN(VNTR) 유전형은 중합효소연쇄반응 후 분리한 결과를 해석하여 다음의 결과를 얻었다. 대립유전자 2 보유자 비율은 치주질환자에서 1L-1A+4845, 1L-1B+3954, 1L-1B-511, 1L-1 RN이 각각 61%, 13%, 76.6%, 34%였으며 대조군에서는 76.9%, 7.7%, 62.2%, 19.1%였다. 1L-1B+3954과 1L-1A+4845 대립유전자 2 보유자인 양성유전자형 비율은 경도, 중등도, 중증의 만성치주염, 급진성 치주염환자에서 각각 10%, 7.9%, 22.2%, 12% 였으며 치주질환자의 13%, 대조군의 7.7%에서 양성 복합유전자형(positive genotype)을 보였다. IL-1B-511 유전자 다변성은 치주질환자에서 대조군에 비하여 높았으며 급진성 치주염환자에서 대립유전자 2 보유자율이 유의하게 높았다(p<0.01). IL-1 RN intron 2 유전자 다변성은 중등도 및 중증 만성 치주염환자에서 대립유전자 2 보유자율이 유의하게 증가하였다. 이러한 결과는 IL-1 gene cluster의 유전형이 한국인에서도 치주염의 유형과 질환 심도에 관련될 수 있음을 시사하였다.

Nematicidal Effect of Root-knot Nematode (Meloidogyne incognita) by Biological Nematicide (생물학적 선충 방제제를 이용한 고구마 뿌리혹선충 (Meloidogyne incognita)의 방제효과)

  • Park, Moon-Hyun;Kim, Jin-Kwang;Choi, Won-Ho;Yoon, Min-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.228-235
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    • 2011
  • An nematophagous fungi Arthrobotrys thaumasia Nema-1 and Pseudomonas putida C-5, which degrade the collagen and gelatin, was isolated from controlled horticultural soils in Seonnam-myun, Sungju-gun, Kyungpook and Woosung-myun, Gongju-shi, Chungnam to develop biological nematode pesticide. When $5,000mL\;L^{-1}$ of A. thaumasia Nema-1 culture was treated to Meloidogyne incognita, the nematicidal activity resulted in 55% at 72 hours after treatment. While the nematicidal activity increased to 65% by treating the culture mixture of $5,000mL\;L^{-1}$ Nema-1 and P. putida C-5 after 72 hours. Furthermore, the nematicidal activity of the mixture containing cinnamon extract $50mg\;L^{-1}$, each $5,000mL\;L^{-1}$ of Nema-1 and C-5 culture was elevated to 89% at 72 hours after treatment, comparing to the result showed 17% and 57% of the nematicidal activity, respectively by the treatment of chemical nemato pesticide Fosthiazate $50mg\;L^{-1}$ and neem oil $2,000mL\;L^{-1}$. These results suggested that the mixture of microorganisms and plant extract were more effective biological nematicide than the case of only microorganism or plant extract for nematode control.

Optimal Design of L1B4 Linear Ultrasonic Motor using Evolutionary Strategy Algorithm (진화 전략 알고리즘을 이용한 L1B4 선형 초음파 모터의 형상 최적 설계)

  • Rho, Jong-Seok;Jung, Hyun-Kyo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.619-622
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    • 2004
  • 본 논문에서는 진화 전략 알고리즘(Evolution Strategy Algorithm)를 이용한 L1B4 선형 초음파 모터(L1B4-USM)의 최적 설계 기법을 제시하고자 한다. 유한요소법(Finite Element Method)을 정식화 하였고, 2차원 유한요소법을 L1B4-USM의 임피던스와 모드의 해석을 통해 검증 하였다. 검증된 2차원 유한 요소 해석을 통한 선형 초음파 모터의 임피던스 해석, mode 해석 및 최적 모드의 탐색 프로그램, 자동 요소분할 프로그램 그리고 진화 전략 알고리즘을 수행하였다. 이를 통해 선형 초음파 모터의 L1모드, B4 모드 각각이 발생하는 공진주파수를 일치시키며, 최대 속도를 얻기 위한 최적 설계기법을 완성 하였고, 최적화된 형상의 L1B4-USM를 설계하였다.

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Synthesis of Nuclophilic Adducts of Thiols (Ⅵ). Addition of L-Cystein to $\beta,\;\beta$-Diethoxycarbonylstyrene Derivatives

  • kim, Tae-Rin;Cho, Bong-Rae;Choi, Sung-Yong;Choi, Won-Sik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.6
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    • pp.215-218
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    • 1984
  • A series of S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-cysteine derivatives (10a-e) were synthesized from the reaction of $\beta$$\beta$-diethoxycarbonylstyrene with L-cysteine in 1:1 aqueous methanol. Thus, S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-cysteine( 10a), S-[2,2-diethoxycarbonyl-1-(3',4'-methylendioxy)ph enylethyl]-L-cysteine (10b), S-[2,2-diethoxycarbonyl-1-(3',4',5'-trimethoxy)phe nylethyl]-L-cyseine (10c), S-[2,2-diethoxycarbonyl-1-(p-hydroxy)phenylethyl] -L-cysteine (10d), S-[2,2-diethoxycarbonyl-1-(p-methoxy)phenylethyl] -L-cysteine (10e) were obtained in moderate to excellent yields. The structure of the adducts was characterized by analytical and spectral data. The effects of pH upon the product yields were also briefly examined.

Formation of Cadmium(II) Nitrate Complexes with Macrocycles

  • Ho-Doo Kim;Hak-Jin Jung;Oh-Jin Jung
    • Bulletin of the Korean Chemical Society
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    • v.14 no.5
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    • pp.561-567
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    • 1993
  • The twelve macrocycle (L) complexes of cadmium(II) nitrate have been synthesized: $CdL(NO_3)_2$. All the complexes have been indentified by elemental analysis, electric conductivity measurements, IR and NMR spectroscopic techniques. The molar electric conductivities of the complexes in water and acetonitrile solvent were in the range of 236.8-296.1 $cm^2{\cdot}mol^{-1}{\cdot}ohm^{-1}$ at 25$^{\circ}$C. The characteristic peaks of macrocycles affected from Cd(II) were shifted to lower frequencies as compared with uncomplexed macrocycles. A complex with 1,4,8,11-tetrakis(methylacetato)-1,4,8,11-tetraaza cyclodecane (L4) exhibited two characteristic bands such as strong stretching (1646 $cm^{-1})$, and weaker symmetric stretching band (1384 $cm^{-1})$. NMR studies indicated that all nitrogen donor atoms of macrocycles have greater affinity to cadmium(II) metal ion than do the oxygen atoms. The $^{13}$C-resonance lines of methylene groups neighboring the donor atom such as N and S were shifted to a direction of high magnetic field and the order of chemical shifts were $L_1 < L_2 < L_3 < L_6 < L_4$. Also the chemical shifts values were larger than those of methylene groups bridgeheaded in side-armed groups. This result seems due to not only the strong interaction of Cd(Ⅱ) with nitrogen donors according to the HSAB theory, but weak interaction of Cd(Ⅱ) and COO- ions or sulfur which is enhanced by the flexible methylene spacing group in side-armed groups. Thus, each additional gem-methyl pairs of L_3, L_4\;and\; L_6$ macrocycles relative to $L_1, L_2,\;and\;L_5$ leads to an large enhancement in Cd(II) affinity. ^{13}C$-NMR spectrum of the complex with $L_{12}$ (1,5,9,13-tetracyclothiacyclohexadecane-3,11-diol) reveals the presence of two sets of three resonance lines, and intensities of the each resonance line have the ratio of 1 : 2 : 2. This molecular conformation is predicted as structure of tetragonal complex to be formed by coordinating two sulfur atoms and the other two sulfur atoms which is affected by OH-groups.

A Single Layer Multi Band Microstrip Patch Antenna for GPS L1/L2, GLONASS Receiver Applications (GPS L1/L2, GLONASS 수신기용 다중 대역 단일 패치 안테나)

  • Kim, Ji-Hae;Kim, Mi-Suk;Kim, Jong-Seong;Son, Seok-Bo;Kim, Young-Baek
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.10
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    • pp.990-998
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    • 2011
  • In this paper, we have designed a multi-band single layer microstrip patch antenna with slots for GPS L2/L1, GLONASS receivers. The antenna has dual feed structure and consists of single layer microstrip patch with slots and impedance matching circuit. The antenna specifications are a VSWR(Voltage Standing Wave Ratio) of less than 2.0, RHCP(Right-Hand Circular Polarization) characteristics over the operating frequency bands of GPS L2(1,227.6 MHz)/L1(1,575.42 MHz) and GLONASS(1,602 MHz), the maximum active antenna gain of more than 30 dB and the axial ratio of less than 3 dB. The antenna has been successfully evaluated by various tests.