• Title/Summary/Keyword: L-particles

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Application of Nano-sized Amphiphilic Polyurethane Particles for The Remediation of PAH-Contaminated Soil:Sorption to Soil and PAH Solubilization

  • Park, Heon-Sik;Ahn, Ik-Sung;Kim, Ju-Young;Park, Sung-Yong;Shin, Young-Seob
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.183-186
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    • 2002
  • Experiments in the batch soil/aqueous systems were conducted to compare the sorption onto soil and extraction efficiency of sorbed phenanthrene in the presence of the micelle-forming anionic surfactant(SDS) or the micelle-like amphiphilic nano-sized polyurethane particles. Micelle-like amphiphilic nano-sized polyurethane(APU) particles synthesized from amphiphilic urethane acrylate anionomers(UAA) could solubilize phenanthrene within their hydrophobic interiors as the same way that surfactants micelles did in aqueous phase.

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Solid-liquid two phase helica l flow in a Rotating Annulus (Slim hole 환형관내 고-액 2상 유동에 관한 연구)

  • Han, Sang-Mok;Woo, Nam-Sub;Hwang, Young-Kyu;Kim, Young-Ju
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.369-372
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    • 2008
  • An experimental study is carried out to study two-phase vertically upward hydraulic transport of solid particles by water in a vertical and inclined (0${\sim}$60 degree) concentric annulus with rotation of the inner cylinder. Rheology of particulate suspensions in shear-thinning fluids is of importance in many applications such as particle removal from surfaces, transport of proppants in fractured reservoir and cleaning of drilling holes, and so on. Annular fluid velocities varied from 0.2 m/s to 1.5 m/s for the actual drilling operational condition. Macroscopic behavior of solid particles, averaged flow rate, and particle rising velocity are observed. Main parameters considered in this study were radius ratio, inner-pipe rotary speed, fluid flow regime, and particle injection rate. For both water and CMC solutions, the higher the concentration of the solid particles is, the larger the pressure gradients become

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Critical Suspension Condition of Particles in a Shaking Vessel of Solid-Liquid System (고-액계 진동교반에서 입자의 부유화 한계조건)

  • Lee, Young-Sei;Kim, Moon-Gab;Kato, Yoshihito
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.73-81
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    • 1999
  • Shake mixing has been widely used in cell culture. The mixing performance for shake mixing, however, has not been reported quantitatively. The critical circulating frequency and the power consumption for complete suspension of particles, based on the definition of Zwietering, were measured in a shaking vessel containing a solid-liquid system. The critical suspension frequency was correlated by the equation from Baldi's particle suspension model modified with the physical properties of the particles. Critical suspension frequency was correlated as following ; $$N_{JS}={\frac{0.58\;d{_p}^{0.06}(g{\Delta}{\rho}/{\rho}_L)^{0.004}X^{0.03}}{D^{0.35}d^{0.17}{\upsilon}^{0.04}}}$$ The power consumption at the critical suspension condition in the shaking vessel was less than that in an agitated vessel with impeller.

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Suspension Polymerization of Styrene with Tricalcium Phosphate as Stabilizer

  • Hong, Soon-Gil;Park, Moonsoo
    • Macromolecular Research
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    • v.8 no.6
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    • pp.247-252
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    • 2000
  • Suspension polymerizations of styrene were conducted in the aqueous phase with tricalcium phosphate (TCP) as a stabilizer and $\alpha$, $\alpha$'-azobis(isobutyronitrile) (AIBN) as an initiator. Various amounts of initiator and stabilizer were selected and the reaction was carried out at a selected temperature between 60 to 80 $\^{C}$. It was found that the combination of 5 wt% stabilizer and 2.427$\times$10$\^$-3/ mol/L of costabilizer is the minimum amount for suspension polymerization reaction to produce particles in the aqueous phase. Particles were found to be polydisperse in diameter, regardless of reaction conditions. Class transitions were observed to be around 95$\^{C}$, nearly independent of reaction temperature and initiator. Homogenizer was found to be essential in forming particles in the proximity of tens of micrometers in diameter in suspension polymerization with TCP as stabilizer.

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A study of PM-10 and Heavy Metal characteristics in the air at the each site of a subway station. (지하철역사내 측정위치별 PM-10 및 중금속 농도특성에 관한 연구)

  • Chang Jung-Wook;Cho Jang-Je;Choi Woo-Gun;Park Duk-Sin;Jung Woo-Sung;Kim Tae-Oh
    • Proceedings of the KSR Conference
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    • 2003.10c
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    • pp.389-394
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    • 2003
  • Subway has been used one of major public transportations because of overpopulation and heavy traffic problems in the metropolitan areas. So, the air pollution has been serious. In this study, continuous date of PM-10 (particles with aerodynamic diameter < $10{\mu}m$) and heavy metal concentration measurements for winter, spring and summer. These measurements have been carried out in the outdoor, concourse, platform, tunnel. The study results showed that the average seasonally concentration of PM-10 particles were $141.57{\mu}g/m^3$ in winter. $129.34{\mu}g/m^3$ in spring and $122.73{\mu}g/m^3$. The average concentration of PM-l0 particles at indoor higher than outdoor. The concentration of Fe, Cu, showed the largest peak concentrations during the respective season.

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Texture Study in HDDR-treated Nd-Fe-B-type Particles

  • Kim, Jung-Hwan;Kwon, H.W.
    • Journal of Magnetics
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    • v.10 no.4
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    • pp.152-156
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    • 2005
  • Effects of the disproportionating hydrogen pressure and alloy composition on the texture in the HDDR-treated Nd-Fe-B particles were examined using the $Nd_{12.6}Fe_{81.4}B_6$ and $Nd_{12.6}Fe_{68.7}B_6Co_{11.0}Ga_{1.0}Zr_{0.l}$ alloys. Disproportionation kinetics of the $Nd_2Fe_{14}B$ phase in the Nd-Fe-B alloy was retarded significantly by the addition of Co, Ga and Zr. The retarded disproportionation kinetics of the $Nd_2Fe_{14}B$ phase ensured a wider processing win­dow in terms of disproportionating hydrogen pressure for achieving a texture in the HDDR-treated Nd-Fe-B alloy particles.

Thermal Radiation Pressure Force on Atmosphereless Bodies

  • Bach, Yoonsoo P.;Ishiguro, Masateru
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.64.1-64.1
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    • 2019
  • Thermal fracture and cracking near the perihelion are found to be a possible mechanism to produce the dust trail of the near-Earth asteroid, (3200) Phaethon (Jewitt and Li, 2013, ApJ 771, L36). It is, however, not well understood how the debris particles were escalated from the regolith against the asteroid's gravity. Thus, the scenario that these debris particles are responsible for the detected activities (Li and Jewitt, 2013, ApJ, 145, 154), is not complete yet. Here, we hypothesize that the thermal radiation pressure around the perihelion passage would exert substantial force outwards from the regolith on dust grains, and they can be lifted up and contributes the dust tail formation with further help of solar radiation pressure. Our modeling indicates that particles with sizes of roughly ~1-10 micron can be ejected from Phaethon by the mechanism, while a detailed model of gravitational field is required for accurate estimation of the particle size range. Our idea is not necessarily limited to Phaethon case, but is applicable to any atmosphereless bodies.

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Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(IV);Dispersiveness of ${\alpha}-sulfo$ fatty acid vinyl ester oligomers (올리고머형 음이온성계면활성제 수용액에서 안료의 분산안정성(제4보);알파 술폰 지방산 비닐에스테르 올리고머의 분산성)

  • Lee, H.W.;Park, S.Y.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.3
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    • pp.55-60
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    • 1998
  • The sodium ${\alpha}-sulfo$ fatty acid vinyl ester oligomers, which are oligomer type surfactants were prepared by polymerization with fatty acid vinyl acetate. The ${\alpha}-sulfonation$ of fatty acid vinyl ester oligomers were carried by direct addition of sulfur trioxide. The dispersing performance of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS) in the aqueous suspension of iron oxide and titanium dioxide particles was evaluated by particle size distribution and zeta-potential measurement. As results, the particles of iron oxide and titanium dioxide were flocculated by addition of small amount of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS), then the flocks redispersed by more addition of oligomer type anionic surfactants and SDS. The flocculation, redispersion process was observed in lower concentration range of oligomer type anionic surfactants than SDS. Especially, the dispersing action of sodium ${\alpha}-sulfo$ palmitic acid vinyl ester oligomer was better than sodium ${\alpha}-sulfo$ lauric acid vinyl ester oligomer.

Ring Oxpening Polymerization of D,L-Lactide on Magnetite Nanoparticles

  • Tian Jing;Feng Ya-Kai;Xu Yong-Shen
    • Macromolecular Research
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    • v.14 no.2
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    • pp.209-213
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    • 2006
  • The ring-opening polymerization of D,L-lactide initiated by tin(II) 2-ethylhexanoate $(Sn(Oct)_2)$ on the surface-initiated magnetite $(Fe_{3}O_4)$ nanoparticles was performed at $130^{\circ}C$. The effects of the polymer molar mass and concentration on the amount of surface polymer were investigated. The number average molecular weights, $M_n$, obtained by both NMR and GPC methods fit well within the accuracy of the applied methods and ranged from 1,100 to $4,040g\;mol^{-1}$. A surface functionalization density of up to 625 initiation sites per particle was obtained. The composition of various core-shell particles was determined by TGA, with results indicating magnetite $(Fe_{3}O_4)$ contents, ${\mu}m$, between 17 and 59 wt%. Under the influence of a magnetic field, the heating generated by superparamagnetic core-shell particles suspended in toluene presented guidelines for an optimization of magnetic particle systems with respect to an application for hyperthermia.

Experimental study of the heat pipe phenomenon in porous media heated from above (상부가열인 다공물질내의 열파이프 현상에 관한 실험적 연구)

  • 이진호;김홍제;함윤영;남궁규완
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.4
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    • pp.825-832
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    • 1988
  • An experiment was performed to study the heat pipe phenomenon of porous media heated above at one-dimensional steady state for the range of heat flux, 300 W/ $m^{2}$ ~ 2000w/ $m^{2}$. Glass beads, sand, and copper particles were used as porous media and distilled water was used as a working fluid. Result of experiment shows that the length of the two-phase zone increases with the decreasing particle size for the same heat flux. At relatively lower heat flux the length of the two-phase zone increases with the increasing heat flux, which contradicts the result of earlier work. However, its length remains nearly constant when the heat flux increases above a certain value. The length of the two-phase zone is proportional to the product of the heat flux by the hydrostatic capillary height under the limited value on heat flux, that is, $l_{t}$ = A(q. $l_{cap}$)+B, q.leg.1/A(C+B/ $l_{cap}$) where A is 1.7*10$^{-4}$ $m^{2}$/w, B is 1.9*10$^{-2}$ m, and C is 0.43 for copper particles and 0.31 for glass beads and sand.d.d.d.