In this paper, a total stress analysis method for gravity quay walls is suggested. The method can evaluate the displacement of the quay walls considering the effect of excess pore pressure developed in backfill soils. This method changes the stiffness of backfill soils according to the expected magnitude of the excess pore pressure. For practical application, evaluation methods are suggested for determining the excess pore pressure ratio developed in the backfill soils and the backfill stiffness that corresponds to the excess pore pressure ratio. This method is important in practical applications because the displacement of the quay walls can be evaluated by using only the basic input properties in the total stress analysis. The applicability of the suggested method was verified by comparing the results of the analysis with the results of 1-g shaking table tests. From the comparison, it was found that the calculated displacements from the suggested method showed good agreement with the measured displacements of the quay walls. It was also found that the excess pore pressure in backfill soils is a governing influence on the dynamic behavior of quay walls.
Mining activity in the Gubong gold mine started in 1908 and lasted up to recent days. Heavy metals derived from the activity may be porentially toxic to human life and envirinment of this area. Because metal toxicity depends on chemical associations into five operationally defined groups: exchangeable, carbonate, reducible, oxidizable, and residual fractions, and the Most of heavy metals have significant little significance (alomost<1%). And Cu is mainly associated with the oxidizable from. Total concentration of heavy metals, pH, and mineralogy affect the chemical forms of the metals. Heavy metal concentrations. Significant amounts of metal elements (5∼65.1% in Pb, 6.2∼39.7% in Zn, 8.7∼54.7% in Cd, and 3.6∼24.7% in Cu) were present in carbonate form from mine wastes, contaminated soils and sediments. High pH value and cerussite (Pb bearing carbonate mineral) in mine wastes, contaminated soils and sediments. High pH value and cerussite (Pb beraring varbonate mineral) in mine waste support this result. Areas with high corbonate bound from would have higher potentoal conamination, however, because elements of carbonate bound forms are easily mobilized under lower pH conditions in the surface envionments due to acid to rain soil acidification.
The aqueous carbonation efficiencies of basic oxygen furnace (BOF) and ladle slags at various pressures, temperatures, and liquid-to-solid (L/S) ratios were investigated to determine optimum conditions. The maximum CO2 carbonated concentrations in slag (0.584 mmol/g for BOF slag and 1.038 mmol/g for ladle slag) was obtained at 10 bars, 40℃, and L/S = 5 mL/g-dry. The L/S ratio was the most critical parameter for carbonation. The effect of carbonated slag amendment on the immobilization of heavy metals in two field-contaminated soils was also investigated. The immobilization efficiencies evaluated by using the toxicity characteristic leaching procedure (TCLP) and the Standards, Measurements and Testing Programme (SM&T) were above 90% for both raw and carbonated slags for all soils. The TCLP-extractable heavy metals concentrations were below the criteria (5.0, 1.0 and 5.0 g/L for Pb, Cd, and Cr, respectively) after immobilizations with both slags except for Pb in soil B. The SM&T analysis showed the decrease in the exchangeable phase but the increase in residual phase after immobilization with raw and carbonated slags. The results of this study imply the promising potential of the carbonated slags on the immobilization of heavy metals in the field-contaminated soils.
In this study, the treatability of two target contaminants during the Fenton reaction, n-hexadecane and 1-methylnaphthalene, was evaluated as a function of the amounts of $FeCl_2$ and $H_2O_2$ injected into open and closed reaction systems. In the Fenton reaction of n-hexadecane and 1-methylnaphthalene, the mass recovery of the target contaminants was above 95% in the closed system. However, when the Fenton reaction was performed with high amounts of $H_2O_2$ and $FeCl_2$ injected in the open system, a reduction of approximately 40% of the initial mass of 1-methylnaphthalene was observed. This trend may be explained by the unique physical properties of 1-methylnaphthalene, which has higher volatility than n-hexadecane. Further, this trend was well correlated with the rise in high temperature at the initial reaction stage. Considering the mass recovery of the two target contaminants, the reaction temperature, and the residual concentration of $H_2O_2$ at different amounts of $FeCl_2$ and $H_2O_2$ injected, it can be suggested that the Fenton reaction should be performed with controlled conditions that can provide a suitable reaction environment between oxidant and contaminants.
For investigating whether the MARSSIM nonparametric test has sufficient statistical power when a site has a specific contamination distribution before conducting a final status survey (FSS), a novel approach was proposed to predict the release probability of the site. Five distributions were assumed: lognormal distribution, normal distribution, maximum extreme value distribution, minimum extreme value distribution, and uniform distribution. Hypothetical radioactivity populations were generated for each distribution, and Sign tests were performed to predict the release probabilities after extracting samples using Monte Carlo simulations. The designed Type I error (0.01, 0.05, and 0.1) was always satisfied for all distributions, while the designed Type II error (0.01, 0.05, and 0.1) was not always met for the uniform, maximum extreme value, and lognormal distributions. Through detailed analyses for lognormal and normal distributions which are often found for contaminants in actual environmental or soil samples, it was found that a greater statistical power was obtained from survey units with normal distribution than with lognormal distribution. This study is expected to contribute to achieving the designed decision error when the contamination distribution of a survey unit is identified, by predicting whether the survey unit passes the statistical test before undertaking the FSS according to MARSSIM.
Kim, Tae-Seob;Sim, Bo-Kyoung;Lee, Kou-Sang;Lee, In-Mo
Journal of the Korean Geotechnical Society
/
v.26
no.6
/
pp.5-19
/
2010
The purpose of this study is to figure out the effect of pressurized grouting on the pullout resistance and the group effect of the compression ground anchor by performing pilot-scale chamber tests and field tests. The laboratory tests are carried out for 3-types of soils which are abundant in the Korean peninsular. Experimental results showed that the enlargement of anchor diameters estimated from the cavity expansion theory matches reasonable well with that obtained from experiments. Moreover, the required injection time as a function of the coefficient of permeability of each soil type was proposed. A series of in-situ anchor pullout tests were also performed to experimentally figure out the effect of pressurized grouting on the pullout resistance. Experimental results also showed that the effect of the pressurized grouting is more prominent in a softer ground with smaller SPT-N value in all of the following three aspects: increase in anchor diameter; pullout resistance; and surface roughness. The pressurized grouting effect in comparison with gravitational grouting was found to be almost nil if the SPT-N value is more than 50. Based on experimental results, a new equation to estimate the pullout resistance as a function of the SPT-N value was proposed. And based on in-situ group anchor pullout tests results, a new group effect equation was proposed which might be applicable to decomposed residual soils which are abundant in the Korean peninsular.
Antifungal substances against three plant pathogenic fungi, Phytophthora capsici, Phytophthora nicotianae var. parasitica and Rhizoctionaia solani were fractionated cultures of Streptomyces sp. A-2 strain isolated in Korean soils. Characterizations of active substances related with antagonistic effects were follows : 1. The excellent media which showed the transfer efficiency of antagonistic substances from Streptomyces sp. A-2 strain G.Y.B and B.H.I. among four that are glucose yeast broth (G.Y.B), $M\ddot{u}eller$, brain heart infusion(B.H.I.) and Czapek media. Active substances which were transfered into ethylacetate or left in residual aqueous phase did not lose antagonistic activity in spite of autoclavation. This indicated that bonds of these compounds were rigid enough to keep activity under such conditions. 2. Antagonistic substances were extracted according to adjustment of pH 3 or pH12 to 5 day-old B.H.I. broth cultures of Streptomyces sp. A-2 strain. Comparative analysis fluorescent bands on HPTLC to antagonsitic spectra against three phytopathogenic fungi indicated that major substances with antagonistic activity were extracted regardless of different pH adjustment to broth cultures. Since UV spectrum of these fractions scanned from 500nm to 200nm was similiar to that of polyene macrolide, major substances related with antagonistic activities were assumed to be polyene derivatives antibiotics.
The cadmium (Cd) and zinc (Zn) contamination of soils and cultivated crop plants by zinc smelting activities was studied. In the study area of the vicinity of ${\triangle}{\triangle}$ zinc smelting factory in Korea, soils and corn plants were sampled at corn harvesting stage and analyzed Cd and Zn concentration as well as Cd and Zn fraction and chemical properties in soils. At 600 m radius of studied area, Cd and Zn were highly accumulated in the surface soils (0 - 20 cm) showed greater than the Korean warning criteria (Cd 1.5, Zn 300 mg $kg^{-1}$) with corresponding values 1.7 and 407 mg $kg^{-1}$, respectively. The leaf part gave higher Cd concentration with the corresponding value of 9.5 mg $kg^{-1}$ as compared to the stem and grains pare (1.6 and 0.18 mg $kg^{-1}$), respectively. Higher Zn concentration was also obtained from the leaf part of the corn plant which gave the value of 1,733 mg $kg^{-1}$. The stem and grain part gave corresponding values of 547 and 61 mg $kg^{-1}$. The order of the mean Cd concentration in fractions is F3 (oxidizable fraction) > F2 (reducible fraction) > F4 (residual fraction) > F1 (exchangeable + acidic fraction). A highly positive correlation is observed between F2 and concentration of Cd and Zn in both plant pare, leaf and grain. Highly positive correlations are shown in the pH exchangeable Ca and Mg, and CEC when correlated with Cd and Zn bound to F4 fractions. To reduce Cd and Zn uptake by corn plant in an arable land heavily contaminated with Cd and Zn as affected by smelting factory, an efficient and effective soil management to increase soil pH and CEC is thus recommended.
Some physical and chemical properties of forest soils in Korea were analyzed for providing the reasonable management methods of forest lands, Among 375 soil series surveyed until 1979, 93 soil series of forest soils were classified and analyzed according to their characteristics. Firstly soil data were classified into 5 categories by weathered products and secondly were classified and analyzed by parent rocks. The results are as follows: 1) In forest soils characterized by weathered products volcanic ash soils were proved to be the most fertile and alluvial soils were turned out to be the most infertile soils. Residual soils on mountain and hill were mostly on the average in all kinds of soil properties analyzed except total soil depth. 2) Igneous rocks developed rather infertile soils containing large amount of organic matter and available $P_2O_5$ with relatively deep soil depth and strong acidity. On the other hand sedimentary rocks produced rather shallow soils containing small amount of organic matter and available $P_2O_5$ but they were relatively fertile with weak acidity. 3) Among igneous rocks basalt and trachyte produced very fertile soils and granite and andesite produced slightly infertile soils. 4) Among sedimentary rocks limestone soils had high fertility neutral in acidity but low amount of available $P_2O_5$ 6) Alluvial sand produced generally very infertile soils with great soil depth comparing with the arable alluvial land with high fertility.
Because of the continuing rapid increase in pesticide usage in Taiwan, much attention has been focus on pesticide contamination of food and effect of pesticides on human and environmental health. The Plant Protection Center (PPC) conducts safety evaluation of pesticides usee! in Taiwan. The pesticides are classified into different groups based on their acute toxicities. Pesticides which are classified into extremely toxic group are not allow to used on short term crops or the continuously harvest crops. The acute toxicity of pesticides to the beneficial insects are also studied, special attention has been paid to the two predators of rice brown planthopper. 60% of cultivated land in Taiwan are paddy field; therefore, acute fish toxicity was taken into consideration when a pesticide was applied for registration to be used in the paddy. Fish toxicities were evaluated by the dangerous rating value which is the amount of pesticide residue in the field water over the TLM value. Mutagenicity of pesticides was continuously evaluated by using Arne's microbial testing method. Island wide survey of residual levels of pesticides of known pollutants such as chlorinated hydrocarbon . insecticides, mercurial compounds in soil, water and biological samples were carried out constantly. The potential of a new1y Imported esticides to pollute the environment were studied by using model ecosystem. Ecological magnification (EM) of a chemical was calculated from model ecosystem. A chemical was considered as a pollutant when its EM value over 5000. In order to ensure the levels of pesticides residue of the crop within the safety limit. The 'tolerance' of pesticides on different crop groupings were established base on 1) acceptable daily intake value of individual pesticides, 2) average daily consumption of each crop groupings by Chinese person, 3) Actual residues of pesticides. on different crops obtained from supervised trials. Total about 79 pesticides for which the tolerances have been established on different crop groupings. Because the intensive agricultural system was adopted in Taiwan. The phytotoxicity of pesticides to the non-target crops was therefore become one of the important factor in the safety evaluation of pesticide usage. These will include 1) direct injury, 2) injury caused by pesticide polluted irrigation water, 3) injury caused by the pesticide polluted soil, 4) reduction of growth caused by the effect of pesticide on the soil microorganisms. This paper will reviewed all the aspects mentioned in the previous .paragraphs. Most the works have done in Taiwan by the PPC.y the PPC.
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