• Korean Journal of Environmental Agriculture
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• v.5 no.1
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• pp.35-42
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• 1986

This study was carried out to investigate the distribution of arsenic (As) fractions in paddy soils in relation to some soil characteristics and to find out the relationship between As fractions in soil and As content in brown rice. Soils and rice samples were collected from paddy field adjacent to arsenic mining and refinery sites. Sequential extraction procedures were used to fractionate As in soils into the designated forms of water soluble-As, Al-As, Fe-As, Ca-As, and residual-As. The results obtained were as follows: 1. The percent distribution of As fractions in soil showed a wide difference depending on some soil properties. The relative abundance of the extractable inorganic As fractions was in the order of Fe-As>Al-As>Ca-As>Water soluble-As regardless of mining and refinery sites. Residual-As fraction was more abundant in mining site than in refinery site. 2. With increasing soil pH, the percent distribution of Fe-As and Al-As fractions were decreased, but that of Ca-As and Residual-As fractions increased. The percent distribution of Al-As fraction in soil was negatively correlated with soil CEC, but others showed positive relationships. 3. Active Al and Fe content, and exchangeable Ca content in soil were positively correlated with the percent distribution of Al-As, Fe-As, and Ca-As fractions in soil respectively, and higher correlation between them was shown in mining site than in refinery site. 4. Soil As fractions, except for water soluble-As, showed significant correlation with among each others and also with 1N HCl extration method using as the common soil As extractant in Korea. 5. Arsenic content in brown rice had highly significant correlation with Al-As fraction in soil and it also showed significant correlation with Fe-As and Ca-As fractions, Total-As, and 1N-HCl extractable As.

• Analytical Science and Technology
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• v.15 no.1
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• pp.67-71
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• 2002

The residual analysis and half-life time of imidazole fungicide prochloraz in soils (silty clay) were investigated by gas chromatography equipped electron capture detector (GC-ECD). The soil samples were extracted acetone/hexane(1:1) solvent and analyzed after separated by $LC-NH_2$ Sep-Pak solid column. Linear sensitivity of standard calibration curve was Y = 268.8600X + 0.0664, $R^2=0.9998$ between 0.05~1.00 ng. The detection limit was 0.02 mg/L and the average recoveries were 94.5~97.3% from the standard additional experiments with 0.10 and 0.40 mg/L. The half-life time was 24.4 days in room laboratory and 7.6 days in the field test soil.

• Journal of Soil and Groundwater Environment
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• v.29 no.5
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• pp.1-13
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• 2024

Repeated tracer tests are often conducted to improve the accuracy of parameter estimation or are sometimes inevitably performed due to mechanical issues or human errors occurred during initial tracer tests. However, residual concentrations from preceding tracer tests can interfere with the injection concentrations of subsequent tests, potentially compromising accuracy of parameter estimation in those later tests. Additionally, repeated injections and interruptions can create transient flow conditions, which have not been adequately considered to date. In this study, a new analytical solution was developed to generate a type curve for repeated tracer tests under transient flow conditions. The solution was validated through numerical simulations. By using the proposed analytical solution, the residual concentration from preceding tracer tests can be effectively accounted for, enabling more accurate parameter estimation for subsequent tracer tests under transient flow conditions.

• Journal of The Korean Society of Grassland and Forage Science
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• v.16 no.4
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• pp.260-266
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• 1996

To find out the residual effect of phosphate fertilization level on the dry matter yield and nutrient plloductivity of pasture plants, this experiment was arranged as a randomized complete block design with six treatments(0-0, 50-50, 100-65, 150-65, 200-65 and 250-65kg $P_2O_5$), those were composed of three $P_2O_5$ fertilization level(0,50 and 65kg $P_2O_5$ after phosphate fertilization trial with six treatments(0, 50, 100, 150, 200 and 250kg $P_2O_5$/ha) from 1989 to 1992, and conducted at hilly land in Kwangju, Kyonggi Province from 1993 to 1994. The results obtained are summarized as follows : As the available phosphate of soil increase, the early growth and cover degree of pasture plants wintered were more favorable. With 150-65kg $P_2O_5$ application for two years, the average dry matter yield of grasses, 9,862kglha was similared to that of 200-65kg $P_2O_5$/ha. The crude protein and energy productivity of pasture plants tended to increase as available phosphate of soil was increased, but those were not different between 150-65 and 250-65kg P 2 0 4 a Efficiency of $P_2O_5$ was highest at $P_2O_5$ 150-65kg/ha fertilization, wHich produced dry matter 11 1.8kg. net energy lactation(NEL) 67 1.2M.f per I kg P205. Therefore, phosphate fertilization is recommended strongly application with 150kg/ha for three years after pasture establishment, and then 65kg/ha for two years a reasonabl management in hilly grassland.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.09a
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• pp.1190-1200
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• 2010

A method was developed to determine resilient modulus for crushed rock-soil mixtures whose usage has been increased recently without engineering specifications. The method is based on the subtle different modulus called nonlinear dynamic modulus and was lately implemented in residual soils and engineered crushed-stones. Hereby. the same method was expanded to crushed rock-soil mixtures containing as large grain diameter as 300mm. The method utilize field direct-arival tests for the determination of maximum Young's modulus, and a large scale free-free resonant column test, which is recently developed to is capable to test as large grain diameter as 25mm, for modulus reduction curves. The prediction model of resilient modulus was evaluated for crushed rock-soil mixtures of a highway construction site at Gimcheon, Korea.

• Journal of The Korean Society of Agricultural Engineers
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• v.59 no.5
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• pp.41-49
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• 2017

This study was aimed to investigate the influence of cation exchange capacity (CEC) and application amounts of zeolite on the stabilization of heavy metals (As, Ni, Pb, and Zn) in upland soils. The upland soils were sampled from field near mines located in Gyeonggi Province. The CEC of zeolite was treated at three different levels, ie, low, medium, and high, while zeolite was amended with soils at the ratio of 0.1 % and 0.5 % as to soil weight. A sequential extraction was performed for the soil sampled at 1, 2 4, and 8 week after zeolite was added to the soil. The concentrations of Pb and Zn appeared to be high in the sampled soils. The mobility of heavy metals obtained from sequential experiments was as follows: Pb > Zn > Ni >As. Addition of zeolite to contaminated soils effectively reduced exchangeable and carbonate fractions but increased organic and residual fraction, indicating that zeolite is effective for immobilizing heavy metals in soils. The influence of incubation time on the metal stabilization was rather pronounced as compared to the application amount and CEC of zeolite.

• Korean Journal of Environmental Agriculture
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• v.42 no.1
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• pp.8-13
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• 2023

Biodegradation of antibiotics in soil can be affected by various environmental factors. This study was set to investigate the effect of environmental conditions such as soil pH and temperature on the degradation of oxolinic acid (OA), one of the agricultural antibiotics used in South Korea, in soil. Rice paddy soil (RS) and field soil (FS) were contaminated with OA and the soil pH was adjusted to 5.7±0.2, 6.8±0.2, and 7.6±0.1. The soil samples were kept at different temperatures (2.3±0.2, 23.0±0.6, 30.5± 0.3℃) for 30 d. The changes in the OA concentrations were determined at selected times. With the RS and FS, the OA removal was not affected by the soil pH used in this study; however, at pH 7.6, the OA removal in the RS was greater than that in the FS, which can be attributed to the different soil properties. The OA removal was similar at 23.0 and 30.5℃ in both soils, but was lower at 2.3℃. The information on the effect of different environmental conditions on the degradation of antibiotics in soil is very limited. Therefore, further studies are needed to better manage the residual antibiotics in the agricultural environment.

• Journal of the Korean Society for Railway
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• v.20 no.1
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• pp.64-75
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• 2017

The role of a track subgrade is to provide bearing capacity and distribute load transferred to lower foundation soils. Track subgrade soils are usually compacted by heavy mechanical machines in the field, such that sometimes they are attributed to progressive residual settlement during the service after construction completion of the railway track. The progressive residual settlement generated in the upper part of a track subgrade is mostly non-recoverable plastic deformation, which causes unstable conditions such as track irregularity. Nonetheless, up to now no design code for allowable residual settlement of subgrade in a railway trackbed has been proposed based on mechanical testing, such as repetitive triaxial testing. At this time, to check the DOC or stiffness of the soil, field test criteria for compacted track subgrade are composed of data from RPBT and field compaction testing. However, the field test criteria do not provide critical design values obtained from mechanical test results that can offer correct information about allowable permanent deformation. In this study, a test procedure is proposed for permanent deformation of compacted subgrade soil that is used usually in railway trackbed in the laboratory using repetitive triaxial testing. To develop the test procedure, an FEA was performed to obtain the shear stress ratio (${\tau}/{\tau}_f$) and the confining stress (${\sigma}_3$) on the top of the subgrade. Comprehensive repetitive triaxial tests were performed using the proposed test procedure on several field subgrade soils obtained in construction sites of railway trackbeds. A permanent deformation model was proposed using the test results for the railway track.

• Journal of the Korean Geotechnical Society
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• v.33 no.12
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• pp.7-20
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• 2017

In this study, effects of grain size distribution on the shear strength and rheological properties are investigated for coarse- and fine-grained soils by using direct shear apparatus. Shear strengths are estimated for fine-grained soils with the maximum particle size of 0.075 mm and coarse-grained soils with the maximum particle size of 0.425 mm and fine contents of 17% prepared at dry and liquid limit states. The direct shear tests are conducted under the relatively slow shear velocity, which corresponds to the reactivated landslide or debris flow after collapse according to the landslide classification. In addition, for the evaluation of rheological properties, residual shear strengths for both fine- and coarsegrained soils prepared under liquid limit states are obtained by multiple reversal shear tests under three shear velocities. From the relationship between residual shear strengths and shear rates, Bingham plastic viscosity and yield stress are estimated. The direct shear tests show that cohesions of fine-grained soil are greater than those of coarse-grained soil at both dry and liquid limit states. However, internal friction angles of fine-grained soil are smaller than those of coarse-grained soil. In case of rheological parameters, the plastic viscosity and yield stress of fine-grained soils are greater than those of coarse-grained soils. This study may be effectively used for the prediction of the reactivated landslide or debris flow after collapse.

• Journal of the Korean Geotechnical Society
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• v.20 no.9
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• pp.47-56
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• 2004

A new fragmentation model, called the GRS (the generation model of weathered residual soils) model, was proposed in this study, This model could identify the formation of a residual soil. This model is based on the phenomena that as the soil was weathered more highly, soil particles were smaller and pores were more expanded simultaneously. The possibility of fragmentation, $P_F,$ which was based on the fractal theory, was introduced in this model. There were some fundamental notions in the GRS model that soil particles were generated as the rock is fragmented, and the fragmentation of the rock was performed step by step. The $P_F,$ of the rock was not constant at each fragmentation steps. As a result of application on the GRS model, there were more residue where $P_{Fi}s$ were small at any particle size. There was a S-shape of PSD curve at the concave shape of $P_{Fi},$ and the PSD curve goes to a gaped graded curve at the convex shape of $P_{Fi}.$ The shape of PSD curve was concave in the case of small $P_{Fi}s.$ The value of $P_{Fi}$ increased with the coefficient of uniformity $(C_u)$ and the fragmentation fractal dimension $(D_r),$ but had no relation with the coefficient of gradation $(C_C)$.