• 한국물환경학회지
• /
• 제21권2호
• /
• pp.176-183
• /
• 2005

Chlorination of wastewater is recently practiced in Korea. While many researchers have studied the kinetics of aqueous chlorine(HOCl) with nitrogeneous compounds and other organic/inorganic contaminants in drinking water, the researches of wastewater chlorination are relatively few. The purpose of this study was to investigate the chlorine decay kinetics and parameters on wastewater chlorination. Chlorine decay rate increased with increasing initial chlorine concentration. The parameters affecting chlorine decay rate were different in each wastewater treatment plant. One of the most important parameters affecting chlorine decay was initial chlorine concentration, and other parameters such as $NH_3-N$, total coliform, $UV_{254}$ and Fe were also affected. The decay ratio of chlorine was decreased with increasing initial chlorine concentration, and the disinfection efficiency showed good correlation with the decay ratio.

• Nuclear Engineering and Technology
• /
• 제50권8호
• /
• pp.1277-1288
• /
• 2018

In this work, the reactor kinetics capability is used to compute the design safety parameters in a PWR due to complete loss of coolant flow during protected and unprotected accidents. A thermal-hydraulic code coupled with a point reactor kinetic model are used for these calculations; where kinetics parameters have been developed from the neutronic SRAC code to provide inputs to RELAP5-3D code to calculate parameters related to safety and guarantee that they meet the regulatory requirements. In RELAP5-3D the reactivity feedback is computed by both separable and tabular models. The results show the importance of the reactivity feedback on calculating the power which is the key parameter that controls the clad and fuel temperatures to maintain them below their melting point and therefore prevent core melt. In addition, extending modeling capability from separable to tabular model has nonremarkable influence on calculated safety parameters.

• Food Science and Biotechnology
• /
• 제17권2호
• /
• pp.330-335
• /
• 2008

Water vapor adsorption kinetics of 3 different types of chitosan-based films, i.e., control chitosan, chitosan/montmorillionite (Na-MMT), and chitosan/silver-zeolite (Ag-Ion) nanocomposite films, were investigated at temperature range of $10-40^{\circ}C$. In all the films, water vapor is initially adsorbed rapidly and then it comes slowly to reach equilibrium condition. Reasonably good straight lines were obtained with plotting of 1/($m-m_0$) vs. l/t. It was found that water vapor adsorption kinetics of chitosan-based films was accurately described by a simple empirical model and the rate constant of the model followed temperature dependence according to Arrhenius equation. Arrhenius kinetic parameters ($E_a$ and $k_o$) for water vapor adsorption by chitosan-based films showed a kinetic compensation effect between the parameters with the isokinetic temperature of 315.52 K.

• 한국식품저장유통학회지
• /
• 제24권4호
• /
• pp.505-509
• /
• 2017

Water vapor adsorption kinetics of vacuum-dried jujube powder were investigated in temperature and relative humidity ranges of 10 to $40^{\circ}C$ and 32 to 75%, respectively. Water vapor was initially adsorbed rapidly and then reached equilibrium condition slowly. Reaction rate constant for water vapor adsorption of vacuum-dried jujube powder increased with an increase in temperature. The temperature dependency of water activity followed the Clausius-Clapeyron equation. The net isosteric heat of sorption increased with an increase in water activity. Good straight lines were obtained with plotting of $1/(m-m_0)$ vs. 1/t. It was found that water vapor adsorption kinetics of vacuum-dried jujube powder was accurately described by a simple empirical model, and temperature dependency of the reaction rate constant followed the Arrhenius-type equation. The activation energy ranged from 50.90 to 56.00 kJ/mol depending on relative humidity. Arrhenius kinetic parameters ($E_a$ and $k_0$) for water vapor adsorption by vacuum-dried jujube powder showed an effect between the parameters with the isokinetic temperature of 302.51 K. The information on water vapor adsorption kinetics of vacuum-dried jujube powder can be used to establish the optimum condition for storage and processing of jujube.

• 대한금속재료학회지
• /
• 제49권12호
• /
• pp.956-966
• /
• 2011

Bioleaching studies of metals from a spent catalyst were conducted using both adapted and unadapted bacterial cultures. The bacterium used in this experiment was Acidithiobacillus ferrooxidans. A comparison of the kinetics of leaching was made between the two cultures by varying the leaching parameters, including the pulp density, particle size and temperature. Both cultures showed similar effects with respect to the above parameters, but the leaching rates of all metals were higher with the adapted compared to the unadapted bacterial cultures. The leaching reactions were continued for 240 h in the case of the unadapted bacterial culture, but only for 40 h in the case of the adapted bacterial culture. The leaching reactions followed first order kinetics. In addition, the kinetics of leaching was concluded to be a diffusion control model; therefore, the product layers were impervious.

• Environmental Engineering Research
• /
• 제24권2호
• /
• pp.309-317
• /
• 2019

This study evaluated the kinetics of acrylamide (AM) biodegradation by mixed culture bacteria and Enterobacter aerogenes (E. aerogenes) in sequencing batch reactor (SBR) systems with AQUASIM and linear regression. The zero-order, first-order, and Monod kinetic models were used to evaluate the kinetic parameters of both autotrophic and heterotrophic nitrifications and both AM and chemical oxygen demand (COD) removals at different AM concentrations of 100, 200, 300, and 400 mg AM/L. The results revealed that both autotrophic and heterotrophic nitrifications and both AM and COD removals followed the Monod kinetics. High AM loadings resulted in the transformation of Monod kinetics to the first-order reaction for AM and COD removals as the results of the compositions of mixed substrates and the inhibition of the free ammonia nitrogen (FAN). The kinetic parameters indicated that E. aerogenes degraded AM and COD at higher rates than mixed culture bacteria. The FAN from the AM biodegradation increased both heterotrophic and autotrophic nitrification rates at the AM concentrations of 100-300 mg AM/L. At higher AM concentrations, the FAN accumulated in the SBR system inhibited the autotrophic nitrification of mixed culture bacteria. The accumulation of intracellular polyphosphate caused the heterotrophic nitrification of E. aerogenes to follow the first-order approximation.

• 산업식품공학
• /
• 제21권4호
• /
• pp.303-311
• /
• 2017

To automate cooking processes, quantitative descriptions are needed on how quality parameters, such as texture change during heating. Understanding mechanical property changes in foods during thermal treatment due to changes in chemical composition or physical structure is important in the context of engineering models and in precise control of quality in general. Texture degradation of food materials has been studied widely and softening kinetic parameters have been reported in many studies. For a better understanding of kinetic parameters, applied kinetic models were investigated, then rate constants at $100^{\circ}C$ and activation energy from previous kinetic studies were compared. The food materials are hardly classified into similar softening kinetics. The range of parameters is wide regardless of food types due to the complexity of food material, different testing methods, sample size, and geometry. Kinetic parameters are essential for optimal process design. For broad and reliable applications, kinetic parameters should be generated by a more consistent manner so that those of foods could be compared or grouped.

• Nuclear Engineering and Technology
• /
• 제22권4호
• /
• pp.359-370
• /
• 1990

이 논문은 원자력발전소의 안전사고해석에 흔히 이용되는 중성자 다군확산 동특성방정식의 저차원(0차원 및 1차원) 수치해를 3차원 수치해와 비교함으로써 저차원 수치해법에 요구되는 동특성해석 입력자료를 체계적으로 유도하기 위한 것이다. 이 목적으로 이 논문에서는 수정형 Borresen 소격모형에 의한 3차원 동특성 해석코드인 CMSNACK 전산코드로 LRA-BWR 경수로 동특성 시범문제의 3차원해를 구하고 이 해를 기준으로 삼아 중성자 다군확산 동특성방정식의 1차원 유한차분해와 3차 Hermit 다항식 전개해법에 의한 점운동방정식의 0차원 수치해를 비교하고자 했다. 중성자 다군확산방정식의 1차원 유한차분해와 점운동방정식의 0차원 수치해를 구하기 위해 ODTRAN 전산코드와 POTRAN 전산코드를 개발하였고 이들 코드의 입력자료는 ODTRAN 코드의 경우 중성자속 체적가중법을 POTRAN의 경우 단열근사법을 수정하여 마련하였다. 이같이 마련한 입력자료를 써서 LRA-BWR 동특성문제에 대한 1차원 및 0차원 해를 구했으며 그 결과를 CMSHACK코드에 의한 3차원 해와의 비교를 통해서 저차원 수치해의 계산효율성과 안전해석코드에 요구되는 계산결과의 보수성 등을 조사했다. 이같은 비교결과를 토대로 저차원 수치해법의 입력자료 마련에 이 논문에서 제시한 방법이 유용하게 이용될 수 있음을 보였다.

• 환경위생공학
• /
• 제16권1호
• /
• pp.66-71
• /
• 2001

The objective of this study was to depict the kinetic behavior of the platinum catalyst for the deep oxidation of aromatic solvents and their binary mixtures. The oxidation kinetics of aromatic solvents, which were benzene, toluene and m-xylene, was studied on a 0.5% $Pt/{\gamma}-Al_2O_3$ catalyst. Deep oxidation of binary mixtures, which were 1:1 in volume, was carried out and the inlet concentration was controlled in the range of 133 and 333ppmv. An approach based on the two-stage redox model was used to analysis the results. The deep oxidation conversion of aromatic solvents was inversely proportional to inlet concentration in plug flow reactor. This trend is due to the zeroth-order kinetics with respect to inlet concentration. The kinetic parameters of multicomponent model were independently evaluated from the single compound oxidation experiments. A simple multicomponent model based on two-stage redox rate model made reasonably good predictions of conversion over the range of parameters studied.

• Bulletin of the Korean Chemical Society
• /
• 제35권1호
• /
• pp.111-116
• /
• 2014

The kinetics and mechanism of oxidation of sulfanilic acid by N-chloro-p-toluene sulfonamide (chloramine-T) have been studied in acid medium. The species of chloramine-T were analysed on the basis of experimental observations and predominantly reactive species was taken into account for proposition of most plausible reaction mechanism. The derived rate law (1) conforms to such a mechanism. $$-\frac{d[CAT]}{dt}=\frac{kK_1[RNHCl][SA]}{K_1+[H^+]}$$ (1) All kinetic parameters were evaluated. Activation parameters such as energy and entropy of activation were calculated to be $(61.67{\pm}0.47)kJmol^{-1}$ and $(-62.71{\pm}2.48)kJmol^{-1}$ respectively employing Eyring equation.