• Title/Summary/Keyword: Kinetics Analysis

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Analysis on the Grain Growth of PLZT Ceramics (PLZT세라믹스에서의 입성장 분석)

  • 송병무;김도연
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.329-334
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    • 1988
  • Kinetics of grain growth in PLZT ceramics during isothermal heat treatment and hot-pressing were investigated and the published data on grain growth were reanalyzed. It was found, in many cases, that the errors were introduced by ignoring the initial grain size. The grain growth of PLZT ceramics was confirmed to follow the parabolic normal growth : D2-Do2=Kt.

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A Study on the Pit Growth Kinetics of Inconel Alloy 600 in $Cl^--Ion$ Containing Solution at Temperatures $25^{\circ}\;to\;150^{\circ}C$ by Analysis of Current Transients in View of Stochastic Theory (확률 이론의 관점에서 $25^{\circ}$ 에서 $150^{\circ}C$ 사이의 염화이온 함유수용액에서 인코넬 합금 600에서 구한 전류추이 곡선의 해석에 의한 핏트의 성장 속도론에 대한 연구)

  • 박진주;변수일
    • 한국전기화학회:학술대회논문집
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    • 2003.04a
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    • pp.44-44
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    • 2003
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A Biomechanical Analysis of Lower Extremity Kinematics and Kinetics During Level Walking (평지를 걸어갈 때 하지운동과 작용하는 하중에 대한 생체역학적 해석)

  • Son, Kwon;Choi, Gi-Yeong;Chung, Min-Keun
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.8
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    • pp.2101-2112
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    • 1994
  • A two-dimensional biomechanical model was developed in order to calculated the lower extremity kinematics and kinetics during level walking. This model consists of three segments : the thigh, calf, and foot. Each segment was assumed to be a rigid body ; its motion to be planar in the sagittal plane. Five young males were involved in the gait experiment and their anthropometric data were measured for the calculation of segmental masses and moments of inertial. Six markers were used to obtain the kinematic data of the right lower extremity for at least three trials of walking at 1.0m/s, and simultaneously a Kistler force plate was used to obtain the foot-floor reaction data. Based on the experimental data acquired for the stance phase of the right foot, calculated vertical joint forces reached up to 0.91, 1.05, and 1.11 BW(body weight) at the hip, the knee, the ankle joints, respectively. The flexion-extension moments reached up to 69.7, 52.3, and 98.8 Nm in magnitude at the corresponding three joints. It was found that the calculated joint loadings of a subject were statistically the same for all his three trials, but not the same for all five subjects involved in the gait study.

On the Reaction Kinetics of GaN Particles Formation from GaOOH (GaOOH로부터 GaN 분말 형성의 반응역학에 관하여)

  • Lee Jaebum;Kim Seontai
    • Korean Journal of Materials Research
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    • v.15 no.5
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    • pp.348-352
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    • 2005
  • Gallium oxyhydroxide (GaOOH) powders were heat-treated in a flowing ammonia gas to form GaN, and the reaction kinetics of the oxide to nitride was quantitatively determined by X-ray diffraction analysis. GaOOH turned into intermediate mixed phases of $\alpha-\;and\;\beta-Ga_2O_3$, and then single phase of GaN. The reaction time for full conversion $(t_c)$ decreased as the temperature increased. There were two-types of rapid reaction processes with the reaction temperature in the initial stage of nitridation at below $t_c$, and a relatively slow processes followed over $t_c$ does not depends on temperatures. The nitridation process was found to be limited by the rate of an interfacial reaction with the reaction order n value of 1 at $800^{\circ}C$ and by the diffusion-limited reaction with the n of 2 at above $1000^{\circ}C$, respectively, at below $t_c$. The activation energy for the reaction was calculated to be 1.84 eV in the temperature of below $830^{\circ}C$, and decreased to 0.38 eV above $830^{\circ}C$. From the comparative analysis of data, it strongly suggest the rate-controlling step changed from chemical reaction to mass transport above $830^{\circ}C$.